US4351876A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Laminate films and sheets of crosslinked polyethylene resins
Assignee: Mitsubishi Chemical Corp
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Filing: 1980-12-17
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Granted: 1982-09-28
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Expires: 2000-12-17
Abstract
Abstract A laminate film or sheet of crosslinked polyethylene resin has as an outer layer a resin layer comprising a copolymer of ethylene and an ethylenically unsaturated silane compound which has been crosslinked by the contact thereof with moisture and has a gel content of 5 percent or more, and possesses excellent processing stability during its lamination, almost no odor, and, simultaneously, heat resistance and heat sealability.
Inventors
- 👤 Shuhei Doi
- 👤 Tsutomu Isaka
- 👤 Shinichiro Iida
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 23:41
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/32; B32B15/00; B32B15/04; B32B15/08; B32B15/085; B32B23/00; B32B23/04; B32B23/08; B32B27/06; B32B27/08; B32B27/10; B32B2305/00; B32B2305/72; B32B2307/00; B32B2307/30; B32B2307/306; B32B2307/31; B32B2311/00; B32B2317/00; B32B2317/12; B32B2317/18; B32B2323/00; B32B2323/04; B32B2439/00; B32B2439/70; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/31504; Y10T428/31551; Y10T428/31609; Y10T428/31612; Y10T428/31652; Y10T428/31663; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/3188; Y10T428/31884; Y10T428/31888; Y10T428/31895; Y10T428/31899; Y10T428/31902; Y10T442/00; Y10T442/30; Y10T442/3472; Y10T442/3528; Y10T442/60; Y10T442/674; Y10T442/678
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
112 words
A laminate film or sheet comprising a plurality of laminate layers selected from films or sheets of resins, foils or sheets of metals, paper, cellophane, fabric, glass in sheet or fibrous form and asbestos, in which at least one surface layer among said plurality of laminate layers comprises a heat sealable crosslinked polyethylene copolymer formed by copolymerizing ethylene monomer and an ethylenically unsaturated silane compound so that said copolymer contains about 0.001 to 5 percent by weight of said silane compound and then crosslinking the resultant copolymer by contact with moisture in the presence of a silanol condensation catalyst, whereby the crosslinked copolymer has a gel content of 5 percent or more.
Claim 2
Dependent Claim
112 words
A laminate film or sheet comprising a plurality of laminate layers selected from films or sheets of resins, foils or sheets of metals, paper, cellophane, fabric, glass in sheet or fibrous form and asbestos, in which at least one surface layer among said plurality of laminate layers comprises a heat sealable crosslinked polyethylene copolymer formed by copolymerizing ethylene monomer and an ethylenically unsaturated silane compound so that said copolymer contains about 0.001 to 5 percent by weight of said silane compound and then crosslinking the resultant copolymer by contact with moisture in the presence of a silanol condensation catalyst, whereby the crosslinked copolymer has a gel content of 5 percent or more.
Claim 3
Dependent Claim
43 words
The laminate film or sheet as claimed in claim 1 in which the ethylenically unsaturated silane compound is selected from the group consisting of: CH.sub.2 ═CHSi(OA).sub.3 and CH.sub.2 ═C(CH.sub.3)COOC.sub.3 H.sub.6 Si(OA).sub.3 wherein A is a hydrocarbyl group having 1 to 8 carbon atoms.
Claim 4
Dependent Claim
35 words
The laminate film or sheet as claimed in claim 1 or 2 in which the laminate comprises a film or sheet of a material selected from the group consisting of resins, metals, papers, and cellophane.
Claim 5
Dependent Claim
34 words
A laminate film according to claim 1 in which the ethylenically unsaturated silane compound has the formula CH 2 ═CHSi(OA) 3 , wherein A is a hydrocarbyl group having 1 to 8 carbon atoms.
Claim 6
Dependent Claim
40 words
A laminate film according to claim 1 in which the ethylenically unsaturated silane compound has the formula CH 2 ═C(CH 3 )COOC 3 H 6 Si(OA) 3 , wherein A is a hydrocarbyl group having 1 to 8 carbon atoms.
Claim 7
Dependent Claim
26 words
A laminate film according to claim 1 or 2 in which said copolymer contains about 0.05 to 2 percent by weight of said ethylenically unsaturated compound.
Claim 8
Dependent Claim
111 words
In a laminate film or sheet composed of a plurality of laminate layers selected from films or sheets of resin, foils or sheets of metal, paper, cellophane, fabric, glass in sheet or fibrous form and asbestos, the improvement wherein at least one outer layer of said laminate comprises a heat sealable crosslinked ethylene copolymer formed by copolymerizing ethylene monomer and an ethylenically unsaturated silane compound so that said copolymer contains about 0.001 to 5 percent by weight of said silane compound and then crosslinking the resultant copolymer by contact with moisture in the presence of a silanol condensation catalyst, whereby the crosslinked copolymer has a gel content of 5% or more.
Claim 9
Dependent Claim
111 words
In a laminate film or sheet composed of a plurality of laminate layers selected from films or sheets of resin, foils or sheets of metal, paper, cellophane, fabric, glass in sheet or fibrous form and asbestos, the improvement wherein at least one outer layer of said laminate comprises a heat sealable crosslinked ethylene copolymer formed by copolymerizing ethylene monomer and an ethylenically unsaturated silane compound so that said copolymer contains about 0.001 to 5 percent by weight of said silane compound and then crosslinking the resultant copolymer by contact with moisture in the presence of a silanol condensation catalyst, whereby the crosslinked copolymer has a gel content of 5% or more.
Claim 10
Dependent Claim
25 words
A laminate film or sheet according to claim 1 or 7 in which said crosslinked copolymer has a gel content of about 15 to 85%.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-27 | 1986-03-29 | 1986-09-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-27 | 1990-03-29 | 1990-09-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-27 | 1994-03-29 | 1994-09-28 | $7700.00 | Window Closed / Lapsed |