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US4351754A Expired / Lapsed US ⏱️ 0.0 years remaining

Thickening agent for aqueous compositions

Assignee: Rohm and Haas Co
•
Filing: 1980-04-10
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Granted: 1982-09-28
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Expires: 2000-04-10
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Abstract

Abstract A mixture of a water swellable clay mineral and an alkali soluble and thickenable (meth)acrylic acid emulsion copolymer provides a highly effective thickening and gelling agent for aqueous systems at low concentrations. The gels are self-supporting and have high strength and thus are particularly useful as air fresheners and other applications where firm gels are desirable. A synergistic thickening effect between the (meth)acrylic acid copolymer and the clay mineral is observed.

Inventors

  • 👤 Jean Dupre

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 05:08
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/02; C11D3/12; C11D3/124; C11D3/1246; C11D3/1253; C11D3/1266; A; A01; A01N; A01N25/00; A01N25/02; A01N25/04; A61; A61K; A61K8/00; A61K8/02; A61K8/04; A61K8/042; A61K8/18; A61K8/19; A61K8/26; A61K8/72; A61K8/81; A61K8/8141; A61K8/8152; A61L; A61L15/00; A61L15/16; A61L15/18; A61L15/42; A61L15/60; A61L9/00; A61L9/015; A61L9/04; A61L9/048; A61Q; A61Q19/00; C08; C08K; C08K3/00; C08K3/34; C08K3/346; C09; C09K; C09K8/00; C09K8/02; C09K8/04; C09K8/14; C09K8/18; C09K8/22; C09K8/24; C11D3/16; C11D3/37; C11D3/3746; C11D3/3757; C11D3/3765; Y; Y10; Y10S; Y10S526/00; Y10S526/932

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 162 words
As a thickening agent for aqueous systems, a composition comprising a mixture of: (A) a water swellable clay mineral, and (B) a water insoluble emulsion polymer, an aqueous dispersion of which will thicken upon addition of a neutralization agent, of (1) 20-50 wt. % of (meth)acrylic acid, (2) 0.5-25 wt. % of at least one monomer of the formula (I): H.sub.2 C═C(R)--C(O)--O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.o wherein R is H or CH 3 , n is at least 2 and has an average value up to 60 or more, and R o is a group having at least 8 carbon atoms selected from alkyl, alkaryl and polycyclic hydrocarbyl, (3) at least 30 wt. % of an alkyl (meth)acrylate wherein the alkyl group has 1 to 4 carbon atoms, and (4) zero to 1.0 wt. % of a polyethylenically unsaturated monomer; the proportions of (A) and (B) being effective, upon addition of a neutralizing agent for (B), for thickening an aqueous dispersion formed therewith.
Claim 2
Dependent Claim 162 words
As a thickening agent for aqueous systems, a composition comprising a mixture of: (A) a water swellable clay mineral, and (B) a water insoluble emulsion polymer, an aqueous dispersion of which will thicken upon addition of a neutralization agent, of (1) 20-50 wt. % of (meth)acrylic acid, (2) 0.5-25 wt. % of at least one monomer of the formula (I): H.sub.2 C═C(R)--C(O)--O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.o wherein R is H or CH 3 , n is at least 2 and has an average value up to 60 or more, and R o is a group having at least 8 carbon atoms selected from alkyl, alkaryl and polycyclic hydrocarbyl, (3) at least 30 wt. % of an alkyl (meth)acrylate wherein the alkyl group has 1 to 4 carbon atoms, and (4) zero to 1.0 wt. % of a polyethylenically unsaturated monomer; the proportions of (A) and (B) being effective, upon addition of a neutralizing agent for (B), for thickening an aqueous dispersion formed therewith.
Claim 3
Dependent Claim 29 words
A composition as in claim 1 wherein the proportions of (A) and (B) are effective for forming a firm gel upon at least partial neutralization and admixture with water.
Claim 4
Dependent Claim 13 words
A composition as in claim 1 wherein (A) is a montmorillonite clay mineral.
Claim 5
Dependent Claim 49 words
A composition as in claim 1 wherein (B) is a copolymer of (1) 30-45 wt. % of (meth)acrylic acid, (2) 1-15 wt. % of said monomer of formula (I), wherein R o contains about 8 to 24 carbon atoms, and (3) about 40-60 wt. % of said alkyl (meth)acrylate.
Claim 6
Dependent Claim 36 words
A composition as in claim 1 or 4 wherein said monomer (2) is ##STR1## wherein R o is an alkyl group having 12-18 carbon atoms, and n has an average value of at least about 10.
Claim 7
Dependent Claim 55 words
A composition as in claim 1 wherein (B) is a copolymer of (1) 30-45 wt. % of methacrylic acid, (2) 1-15 wt. % of said monomer of formula (I) wherein n has an average value of about 10-60 and R o is alkyl having 12-18 carbon atoms, and (3) 40-60 wt. % of ethyl acrylate.
Claim 8
Dependent Claim 35 words
A composition as in claim 1 wherein the amount of (A) is about 0.1-10 parts by weight and the amount of (B) is about 0.1-5 parts by weight, and (A) is a montmorillonite clay mineral.
Claim 9
Dependent Claim 24 words
A composition comprising an aqueous dispersion thickened with effective amounts of an at least partially neutralized composition of claim 1, 4, 6 or 7.
Claim 10
Dependent Claim 21 words
A composition comprising an aqueous gel prepared by dispersing in water and at least partially neutralizing the composition of claim 2.
Claim 11
Dependent Claim 34 words
A method of thickening an aqueous dispersion, comprising blending therewith a composition as in claim 1, 4, 6 or 7, and at least partially neutralizing said composition before, after or simultaneously with said blending.
Claim 12
Dependent Claim 29 words
A method of forming an aqueous gel, comprising dispersing in water the composition of claim 7 and at least partially neutralizing said composition before, after or during said dispersing.

References Cited (Backward Citations)

US3657175A Cited
US3652497A Cited
US3779970A Cited
US3960935A Cited
US3894980A Cited
US3891591A Cited
US4138381A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-27 1986-03-29 1986-09-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-27 1990-03-29 1990-09-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-27 1994-03-29 1994-09-28 $7700.00 Window Closed / Lapsed

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