US4351754A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Thickening agent for aqueous compositions
Assignee: Rohm and Haas Co
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Filing: 1980-04-10
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Granted: 1982-09-28
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Expires: 2000-04-10
Abstract
Abstract A mixture of a water swellable clay mineral and an alkali soluble and thickenable (meth)acrylic acid emulsion copolymer provides a highly effective thickening and gelling agent for aqueous systems at low concentrations. The gels are self-supporting and have high strength and thus are particularly useful as air fresheners and other applications where firm gels are desirable. A synergistic thickening effect between the (meth)acrylic acid copolymer and the clay mineral is observed.
Inventors
- 👤 Jean Dupre
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 05:08
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/02; C11D3/12; C11D3/124; C11D3/1246; C11D3/1253; C11D3/1266; A; A01; A01N; A01N25/00; A01N25/02; A01N25/04; A61; A61K; A61K8/00; A61K8/02; A61K8/04; A61K8/042; A61K8/18; A61K8/19; A61K8/26; A61K8/72; A61K8/81; A61K8/8141; A61K8/8152; A61L; A61L15/00; A61L15/16; A61L15/18; A61L15/42; A61L15/60; A61L9/00; A61L9/015; A61L9/04; A61L9/048; A61Q; A61Q19/00; C08; C08K; C08K3/00; C08K3/34; C08K3/346; C09; C09K; C09K8/00; C09K8/02; C09K8/04; C09K8/14; C09K8/18; C09K8/22; C09K8/24; C11D3/16; C11D3/37; C11D3/3746; C11D3/3757; C11D3/3765; Y; Y10; Y10S; Y10S526/00; Y10S526/932
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
162 words
As a thickening agent for aqueous systems, a composition comprising a mixture of: (A) a water swellable clay mineral, and (B) a water insoluble emulsion polymer, an aqueous dispersion of which will thicken upon addition of a neutralization agent, of (1) 20-50 wt. % of (meth)acrylic acid, (2) 0.5-25 wt. % of at least one monomer of the formula (I): H.sub.2 C═C(R)--C(O)--O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.o wherein R is H or CH 3 , n is at least 2 and has an average value up to 60 or more, and R o is a group having at least 8 carbon atoms selected from alkyl, alkaryl and polycyclic hydrocarbyl, (3) at least 30 wt. % of an alkyl (meth)acrylate wherein the alkyl group has 1 to 4 carbon atoms, and (4) zero to 1.0 wt. % of a polyethylenically unsaturated monomer; the proportions of (A) and (B) being effective, upon addition of a neutralizing agent for (B), for thickening an aqueous dispersion formed therewith.
Claim 2
Dependent Claim
162 words
As a thickening agent for aqueous systems, a composition comprising a mixture of: (A) a water swellable clay mineral, and (B) a water insoluble emulsion polymer, an aqueous dispersion of which will thicken upon addition of a neutralization agent, of (1) 20-50 wt. % of (meth)acrylic acid, (2) 0.5-25 wt. % of at least one monomer of the formula (I): H.sub.2 C═C(R)--C(O)--O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.o wherein R is H or CH 3 , n is at least 2 and has an average value up to 60 or more, and R o is a group having at least 8 carbon atoms selected from alkyl, alkaryl and polycyclic hydrocarbyl, (3) at least 30 wt. % of an alkyl (meth)acrylate wherein the alkyl group has 1 to 4 carbon atoms, and (4) zero to 1.0 wt. % of a polyethylenically unsaturated monomer; the proportions of (A) and (B) being effective, upon addition of a neutralizing agent for (B), for thickening an aqueous dispersion formed therewith.
Claim 3
Dependent Claim
29 words
A composition as in claim 1 wherein the proportions of (A) and (B) are effective for forming a firm gel upon at least partial neutralization and admixture with water.
Claim 4
Dependent Claim
13 words
A composition as in claim 1 wherein (A) is a montmorillonite clay mineral.
Claim 5
Dependent Claim
49 words
A composition as in claim 1 wherein (B) is a copolymer of (1) 30-45 wt. % of (meth)acrylic acid, (2) 1-15 wt. % of said monomer of formula (I), wherein R o contains about 8 to 24 carbon atoms, and (3) about 40-60 wt. % of said alkyl (meth)acrylate.
Claim 6
Dependent Claim
36 words
A composition as in claim 1 or 4 wherein said monomer (2) is ##STR1## wherein R o is an alkyl group having 12-18 carbon atoms, and n has an average value of at least about 10.
Claim 7
Dependent Claim
55 words
A composition as in claim 1 wherein (B) is a copolymer of (1) 30-45 wt. % of methacrylic acid, (2) 1-15 wt. % of said monomer of formula (I) wherein n has an average value of about 10-60 and R o is alkyl having 12-18 carbon atoms, and (3) 40-60 wt. % of ethyl acrylate.
Claim 8
Dependent Claim
35 words
A composition as in claim 1 wherein the amount of (A) is about 0.1-10 parts by weight and the amount of (B) is about 0.1-5 parts by weight, and (A) is a montmorillonite clay mineral.
Claim 9
Dependent Claim
24 words
A composition comprising an aqueous dispersion thickened with effective amounts of an at least partially neutralized composition of claim 1, 4, 6 or 7.
Claim 10
Dependent Claim
21 words
A composition comprising an aqueous gel prepared by dispersing in water and at least partially neutralizing the composition of claim 2.
Claim 11
Dependent Claim
34 words
A method of thickening an aqueous dispersion, comprising blending therewith a composition as in claim 1, 4, 6 or 7, and at least partially neutralizing said composition before, after or simultaneously with said blending.
Claim 12
Dependent Claim
29 words
A method of forming an aqueous gel, comprising dispersing in water the composition of claim 7 and at least partially neutralizing said composition before, after or during said dispersing.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-27 | 1986-03-29 | 1986-09-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-27 | 1990-03-29 | 1990-09-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-27 | 1994-03-29 | 1994-09-28 | $7700.00 | Window Closed / Lapsed |