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US4351745A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrically conductive polyetherester elastomers

Assignee: EIDP Inc
•
Filing: 1980-01-09
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Granted: 1982-09-28
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Expires: 2000-01-09
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Abstract

Abstract Conductive elastomeric compositions consisting essentially of a blend of a copolyetherester having 45-85 weight percent of long chains and 15-55 weight percent of short chains and melting at at least 90° C. with a conductive filler consisting of carbon black or a mixture of carbon black with graphite, the resistivity of such compositions being less than about 2 ohm.cm can be fabricated or cast into thin, self-supporting films or sheets. Articles made from these compositions find utility in electrical and electronic equipment, business machines, and in applications where good aging properties are important.

Inventors

  • 👤 Henry J. Stinger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 22:36
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/20; H01B1/24; C; C08; C08K; C08K3/00; C08K3/02; C08K3/04; C08L; C08L67/00; C08L67/02; C08L67/025; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2918; Y10T428/30

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 224 words
An electrically conductive composition, capable of forming self-supporting films, consisting essentially of a uniform mixture of: (A) 100 parts of a copolyetherester having a melting point of at least about 90° C. and containing 45-85 weight percent of long-chain ester units represented by the following formula (1) ##STR3## and 15-55 weight percent of short-chain ester units represented by the following formula (2) ##STR4## wherein R is a divalent radical remaining after removal of carboxyl groups from an aromatic or aliphatic dicarboxylic acid having a molecular weight of less than 300; G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol HO-G-OH having a number average molecular weight of about 600-3500 and a carbon/oxygen atomic ratio of at least 2.5; and D is a divalent radical remaining after removal of hydroxyl groups from a diol HO-D-OH having a molecular weight of less than about 250; and (B) 60-110 parts of a conductive filler selected from the group consisting of carbon black and a mixture of carbon black and graphite, the proportion of carbon black in such a mixture being no less than about 20 weight percent; the resistivity of said electrically conductive composition being less than about 2 ohm.cm, its tensile strength at break at least about 10 MPa, and its extension at break at least 20%.
Claim 2
Dependent Claim 224 words
An electrically conductive composition, capable of forming self-supporting films, consisting essentially of a uniform mixture of: (A) 100 parts of a copolyetherester having a melting point of at least about 90° C. and containing 45-85 weight percent of long-chain ester units represented by the following formula (1) ##STR3## and 15-55 weight percent of short-chain ester units represented by the following formula (2) ##STR4## wherein R is a divalent radical remaining after removal of carboxyl groups from an aromatic or aliphatic dicarboxylic acid having a molecular weight of less than 300; G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol HO-G-OH having a number average molecular weight of about 600-3500 and a carbon/oxygen atomic ratio of at least 2.5; and D is a divalent radical remaining after removal of hydroxyl groups from a diol HO-D-OH having a molecular weight of less than about 250; and (B) 60-110 parts of a conductive filler selected from the group consisting of carbon black and a mixture of carbon black and graphite, the proportion of carbon black in such a mixture being no less than about 20 weight percent; the resistivity of said electrically conductive composition being less than about 2 ohm.cm, its tensile strength at break at least about 10 MPa, and its extension at break at least 20%.
Claim 3
Dependent Claim 43 words
A compostion of claim 1 wherein the polymeric glycol HO-G-OH is selected from the group consisting of poly(tetramethylene oxide) glycol, random copolymers of ethylene oxide and 1,2-propylene oxide, block copolymers of ethylene oxide and 1,2-propylene oxide, and copolymers of tetrahydrofuran with ethylene oxide.
Claim 4
Dependent Claim 11 words
A composition of claim 2 wherein the diol HO-D-OH is 1,4-butanediol.
Claim 5
Dependent Claim 16 words
A composition of claim 1 wherein R is selected from the group 1,2-phenylene, 1,3-phenylene, and 1,4-phenylene.
Claim 6
Dependent Claim 55 words
A composition of claim 1 wherein the conductive filler is a carbon black having a surface area of more than 30 m 2 /g, as determined by nitrogen absorption; a particle size of less than 70 μm, determined by electron microscopy; and dibutyl phthalate absorption value of more than 50 cm 3 per 100 g.
Claim 7
Dependent Claim 9 words
A composition of claim 1 also containing a plasticizer.
Claim 8
Dependent Claim 39 words
Composition of claim 6 wherein the plasticizer is selected from the group consisting of: chlorinated paraffin, dioctyl phthalate, butyl stearyl butyl glycolate, N-ethyl o- and p-toluenesulfonamide, 2-ethylhexyl diphenyl phosphate, polymeric polyester plasticizers, and substantially noncrystalline or low melting copolyetheresters.
Claim 9
Dependent Claim 25 words
A composition of claim 7 wherein the plasticizer is a low-melting copolyetherester of a chemical structure similar to the copolyetheresters of formulas (1) and (2).
Claim 10
Dependent Claim 13 words
A dispersion of a conductive composition of claim 1 in an organic solvent.
Claim 11
Dependent Claim 13 words
A conductive film or sheet cast from a wet dispersion of claim 9.

References Cited (Backward Citations)

US3510448A Cited
US3639121A Cited
US3783021A Cited
US4035265A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-27 1986-03-29 1986-09-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-27 1990-03-29 1990-09-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-27 1994-03-29 1994-09-28 $7700.00 Window Closed / Lapsed

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