US4351707A
Expired / Lapsed
US
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Methods employing magnetic isotope effect
Assignee: Alpine Kinetics Inc
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Filing: 1979-11-08
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Granted: 1982-09-28
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Expires: 1999-11-08
Abstract
Abstract Separation and enrichment of isotopes are effected and rates and products of reactions are controlled by methods employing magnetic isotope effect. By virtue of the invention, when dibenzyl ketone was photolyzed to partial conversion in a dimensionally restricted environment (micelles in soap solution) 13 C enrichment of over 100% was achieved. The 13 C enrichment was found to occur specifically at the carbonyl carbon and to be magnetic field dependent.
Inventors
- 👤 Nicholas J. Turro
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 10:17
CPC Classifications
B; B01; B01D; B01D59/00
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
81 words
In a chemical reaction system having radical pairs in the triplet state, some of which have magnetic nuclei and others of which have non-magnetic nuclei, a method of controlling reactions in said system involving the conversion of said radical pairs from the triplet state to the singlet state comprising providing an environment of restricted dimensionality for said radical pairs wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 2
Dependent Claim
81 words
In a chemical reaction system having radical pairs in the triplet state, some of which have magnetic nuclei and others of which have non-magnetic nuclei, a method of controlling reactions in said system involving the conversion of said radical pairs from the triplet state to the singlet state comprising providing an environment of restricted dimensionality for said radical pairs wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 3
Dependent Claim
18 words
A method in accordance with claim 1, further comprising applying an external magnetic field to the reaction system.
Claim 4
Dependent Claim
92 words
In a chemical reaction system involving molecules of a substance which produce radical pairs in the triplet state, some of which have magnetic nuclei and others of which have non-magnetic nuclei, a method of enhancing the reformation of molecules from radical pairs containing magnetic nuclei by the conversion of radical pairs from the triplet state to the singlet state, comprising providing an environment of restricted dimensionality for the radical pairs wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 5
Dependent Claim
92 words
In a chemical reaction system involving molecules of a substance which produce radical pairs in the triplet state, some of which have magnetic nuclei and others of which have non-magnetic nuclei, a method of enhancing the reformation of molecules from radical pairs containing magnetic nuclei by the conversion of radical pairs from the triplet state to the singlet state, comprising providing an environment of restricted dimensionality for the radical pairs wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 6
Dependent Claim
39 words
A method in accordance with claim 1 or 3, wherein the chemical reaction system involves a process whose rate does not depend on magnetic effects and that competes with intersystem crossing or touching for destruction of a radical pair.
Claim 7
Dependent Claim
18 words
A method in accordance with claim 1 or 3, wherein the method produces enrichment of an atomic species.
Claim 8
Dependent Claim
17 words
A method in accordance with claim 1 or 3, wherein the method produces separation of atomic species.
Claim 9
Dependent Claim
37 words
A method in accordance with claim 1 or 3, wherein the chemical reaction system includes a photochemical or thermal reaction that proceeds along one pathway in the triplet state and along another pathway in the singlet state.
Claim 10
Dependent Claim
32 words
A method in accordance with claim 1 or 3, wherein the method involves the enrichment of 13 C via the photolysis of ketones in soap solution providing the environment of restricted dimensionality.
Claim 11
Dependent Claim
57 words
A method in accordance with claim 1 or 3, wherein the chemical reaction system involves free radical formation via photolysis of ketones in soap solution providing the environment of restricted dimensionality and wherein at least one of the rate of reaction, the rate of free radical formation, and the reaction products are affected by the restricted dimensionality.
Claim 12
Dependent Claim
103 words
In a chemical reaction system involving the conversion of radical pairs from the triplet state to the singlet state, some radical pairs having magnetic nuclei and others having non-magnetic nuclei, and involving a process that competes with said conversion, a method of enhancing the conversion of radical pairs having magnetic nuclei relative to the conversion of radical pairs that do not have magnetic nuclei and relative to the competing process, comprising providing an environment of restricted dimensionality for said radical pairs wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 13
Dependent Claim
103 words
In a chemical reaction system involving the conversion of radical pairs from the triplet state to the singlet state, some radical pairs having magnetic nuclei and others having non-magnetic nuclei, and involving a process that competes with said conversion, a method of enhancing the conversion of radical pairs having magnetic nuclei relative to the conversion of radical pairs that do not have magnetic nuclei and relative to the competing process, comprising providing an environment of restricted dimensionality for said radical pairs wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 14
Dependent Claim
34 words
A method in accordance with claim 10, wherein said competing process competes with intersystem crossing or touching for destruction of a radical pair and has a rate which does not depend on magnetic effects.
Claim 15
Dependent Claim
13 words
A method in accordance with claim 11, wherein said competing process comprises diffusion.
Claim 16
Independent Claim
106 words
A method of isotope enrichment of a chemical compound having both magnetic and non-magnetic isotopes of a chemical element, comprising forming radical pairs in the triplet state from molecules of the compound, some of said radical pairs including a magnetic isotope of the chemical element and other radical pairs including a non-magnetic isotope of the chemical element, and providing for said radical pairs an environment of restricted dimensionality such that the radical pairs containing said magnetic isotope are preferentially converted to the singlet state wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 17
Independent Claim
106 words
A method of isotope enrichment of a chemical compound having both magnetic and non-magnetic isotopes of a chemical element, comprising forming radical pairs in the triplet state from molecules of the compound, some of said radical pairs including a magnetic isotope of the chemical element and other radical pairs including a non-magnetic isotope of the chemical element, and providing for said radical pairs an environment of restricted dimensionality such that the radical pairs containing said magnetic isotope are preferentially converted to the singlet state wherein the environment of restricted dimensionality is selected from the group consisting of micelles, gels, molecular sieves, vesicles, liquid crystals, and clathrates.
Claim 18
Dependent Claim
30 words
A method in accordance with claim 13, wherein said method involves the enrichment of 13 C via the photolysis of ketones in soap solution providing the environment of restricted dimensionality.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-27 | 1986-03-29 | 1986-09-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-27 | 1990-03-29 | 1990-09-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-27 | 1994-03-29 | 1994-09-28 | $7700.00 | Window Closed / Lapsed |