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US4350804A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable compositions comprising an azole-functional resin and a metal-ligand complex

Assignee: PPG Industries Ohio Inc
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Filing: 1980-11-21
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Granted: 1982-09-21
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Expires: 2000-11-21
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Abstract

Abstract The invention is directed to curable compositions comprising an azole-functional resin and a labile metal-ligand complex. The azole-functional resin is the reaction product of a monomeric or polymeric resin and a reactive N-heterocyclic compound containing at least two nuclear nitrogen atoms in a 5-membered ring structure capable of forming stable metal-ligand complexes. Mixtures of azole-functional resins also may be used with the labile-metal ligand complexes in the compositions of the invention.

Inventors

  • 👤 John S. Ostrowski
  • 👤 John F. Grunewalder
  • 👤 Nicholas T. Castellucci

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 14:51
CPC Classifications
C; C08; C08G; C08G85/00; C08G85/004; C08G59/00; C08G59/14; C08G59/1433; C08G79/00

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 27 words
A curable composition comprising: (A) an azole-functional resin; and (B) a labile metal-ligand complex; wherein said labile metal-ligand complex is capable of reacting with said azole-functional resin.
Claim 2
Dependent Claim 27 words
A curable composition comprising: (A) an azole-functional resin; and (B) a labile metal-ligand complex; wherein said labile metal-ligand complex is capable of reacting with said azole-functional resin.
Claim 3
Dependent Claim 31 words
The composition of claim 1 wherein the azole of said azole-functional resin is selected from the group consisting of an imidazole, a triazole, a tetrazole, a thiadiazole and a mixture thereof.
Claim 4
Dependent Claim 26 words
The composition of claim 1 wherein the ratio of equivalents of said labile metal-ligand complex to said azole-functional resin is from about 0.5:1.0 to about 2.0:1.0.
Claim 5
Dependent Claim 45 words
The composition of claim 1 wherein said azole-functional resin comprises the reaction product of (i) a compound selected from the group consisting of a triazole, a thiadiazole, a tetrazole, an imidazole, and a mixture thereof; and (ii) a resin capable of reacting with said compound.
Claim 6
Dependent Claim 28 words
The composition of claim 4 wherein said compound is a triazole substituted by a primary amino, secondary amino or mercapto group on at least one nuclear carbon atom.
Claim 7
Dependent Claim 28 words
The composition of claim 4 wherein said compound is a thiadiazole substituted by a primary amino, secondary amino or mercapto group on at least one nuclear carbon atom.
Claim 8
Dependent Claim 26 words
The composition of claim 4 wherein said compound is a tetrazole substituted by a primary amino, secondary amino or mercapto group on the nuclear carbon atom.
Claim 9
Dependent Claim 28 words
The composition of claim 4 wherein said compound is an imidazole substituted by a primary amino, secondary amino or mercapto group on at least one nuclear carbon atom.
Claim 10
Dependent Claim 19 words
The composition of claims 4, 5, 6, 7, or 8 wherein said resin of component (ii) comprises a polyepoxide.
Claim 11
Dependent Claim 15 words
The composition of claim 9 wherein said polyepoxide is a polyglycidyl ether of a polyphenol.
Claim 12
Dependent Claim 15 words
The composition of claim 10 wherein said polyglycidyl ether is a polyglycidyl ether of bis(4-hydroxyphenol)dimethylmethane.
Claim 13
Dependent Claim 15 words
The composition of claim 9 wherein said polyepoxide is an acrylic resin containing epoxy groups.
Claim 14
Dependent Claim 25 words
The composition of claim 9 wherein the ratio of equivalents of said metal-ligand complex to said azole-functional resin is from about 0.5:1.0 to about 2.0:1.0.
Claim 15
Dependent Claim 15 words
The composition of claim 1 further comprising a pigment, an additive or a mixture thereof.
Claim 16
Dependent Claim 15 words
The composition of claim 4 further comprising a pigment, an additive or a mixture thereof.

References Cited (Backward Citations)

GB836695A Cited
US2878233A Cited
US2878234A Cited
US3324050A Cited
US3308078A Cited
US3700636A Cited
US3677978A Cited
US3730915A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-20 1986-03-22 1986-09-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-20 1990-03-22 1990-09-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-20 1994-03-22 1994-09-21 $7700.00 Window Closed / Lapsed

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