US4349650A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
Assignee: BIOTECHNOLOGY Inc
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Filing: 1980-05-01
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Granted: 1982-09-14
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Expires: 2000-05-01
Abstract
Abstract The reaction of a polyfluorocarbonyl compound such as a polyfluoroketone or polyfluorocarboxylic acid fluoride with fluoride ion and a polyfluoroallyl chloride, bromide or fluorosulfate produces a polyfluoroallyloxy compound, e.g., CF2=CFCF2OCF2CF2SO2F. The polyfluoroallyloxy compounds copolymerize with ethylenically unsaturated monomers such as tetrafluoroethylene, chlorotrifluoroethylene or vinylidene fluoride to form polymers which are moldable, and in some cases electrically conducting or are water-wettable and dyeable.
Inventors
- 👤 Carl G. Krespan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 06:06
CPC Classifications
C; C08; C08F; C08F16/00; C08F16/12; C08F16/14; C08F16/30; C07; C07C; C07C43/00; C07C43/02; C07C43/20; C07C43/225; C07C51/00; C07C51/58; C07C51/62
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
175 words
A copolymer of a polyfluoroallyloxy compound having the formula CF.sub.2 ═CFCF.sub.2 OR.sub.F wherein R F is ##STR69## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Q is --SO 2 F, --COF, --CN or --CO 2 R 4 where R 4 is --CH 3 or --C 2 H 5 ; Y and Y', independently, are --F or --CF 3 and only Y and Y' can be --CF 3 ; or (ii) --CF(R 2 ) 2 wherein R 2 is --CF 2 COF, --CF 2 CN, or --CF 2 CO 2 R 4 where R 4 is defined as above; or ##STR70## wherein R 3 is a linear perfluoroalkylene group of carbon content such that the moiety ##STR71## does not exceed 15 carbon atoms; Y is --F, or --CF 3 ; n is 1 to 4; and Q' is defined as for Q above; and at least one ethylenically unsaturated monomer; said copolymer having a molecular weight sufficient to be molded into a shaped article.
Claim 2
Dependent Claim
175 words
A copolymer of a polyfluoroallyloxy compound having the formula CF.sub.2 ═CFCF.sub.2 OR.sub.F wherein R F is ##STR69## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Q is --SO 2 F, --COF, --CN or --CO 2 R 4 where R 4 is --CH 3 or --C 2 H 5 ; Y and Y', independently, are --F or --CF 3 and only Y and Y' can be --CF 3 ; or (ii) --CF(R 2 ) 2 wherein R 2 is --CF 2 COF, --CF 2 CN, or --CF 2 CO 2 R 4 where R 4 is defined as above; or ##STR70## wherein R 3 is a linear perfluoroalkylene group of carbon content such that the moiety ##STR71## does not exceed 15 carbon atoms; Y is --F, or --CF 3 ; n is 1 to 4; and Q' is defined as for Q above; and at least one ethylenically unsaturated monomer; said copolymer having a molecular weight sufficient to be molded into a shaped article.
Claim 3
Dependent Claim
114 words
A copolymer of a polyfluoroallyloxy compound having the formula CF.sub.2 ═CFCF.sub.2 OR.sub.F wherein R F is: ##STR72## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Y and Y', independently, are --F or --CF 3 and only Y or Y' can be --CF 3 ; or ##STR73## wherein R 3 is a linear perfluoroalkylene group of carbon content such that the moiety ##STR74## does not exceed 15 carbon atoms; Y is --F or --CF 3 ; and n is 1 to 4; and at least one ethylenically unsaturated monomer; said copolymer having a molecular weight sufficient to be molded into a shaped article.
Claim 4
Dependent Claim
114 words
A copolymer of a polyfluoroallyloxy compound having the formula CF.sub.2 ═CFCF.sub.2 OR.sub.F wherein R F is: ##STR72## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Y and Y', independently, are --F or --CF 3 and only Y or Y' can be --CF 3 ; or ##STR73## wherein R 3 is a linear perfluoroalkylene group of carbon content such that the moiety ##STR74## does not exceed 15 carbon atoms; Y is --F or --CF 3 ; and n is 1 to 4; and at least one ethylenically unsaturated monomer; said copolymer having a molecular weight sufficient to be molded into a shaped article.
Claim 5
Dependent Claim
40 words
The copolymer of claim 1 wherein the ethylenically unsaturated monomer is selected from the class consisting of ethylene, tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, trifluoroethylene and provided tetrafluoroethylene or vinylidene fluoride is also present perfluoro(methyl vinyl ether), perfluoro(propyl vinyl ether) and hexafluoropropylene.
Claim 6
Dependent Claim
26 words
The copolymer of claim 1 wherein (i) R 1 contains up to 8 carbon atoms and (iii) the moiety ##STR75## contains up to 8 carbon atoms.
Claim 7
Dependent Claim
19 words
The copolymer of claim 3 wherein the polyfluoroallyloxy compound content is about 0.1-55 percent by weight of the copolymer.
Claim 8
Dependent Claim
19 words
The copolymer of claim 4 wherein the polyfluoroallyloxy compound content is about 0.1-55 percent by weight of the copolymer.
Claim 9
Dependent Claim
38 words
The copolymer of claim 5 wherein the ethylenically unsaturated monomer is selected from the class consisting of tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, and provided tetrafluoroethylene or vinylidene fluoride is also present hexafluoropropylene, perfluoro(methyl vinyl ether) and perfluoro(propyl vinyl ether).
Claim 10
Dependent Claim
22 words
The copolymer of claim 7 wherein the ethylenically unsaturated monomer is selected from the class consisting of vinylidene fluoride, chlorotrifluoroethylene and tetrafluoroethylene.
Claim 11
Dependent Claim
19 words
The copolymer of claim 6 wherein the polyfluoroallyloxy compound content is about 1-10 percent by weight of the copolymer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-13 | 1986-03-15 | 1986-09-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-13 | 1990-03-15 | 1990-09-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-13 | 1994-03-15 | 1994-09-14 | $7700.00 | Window Closed / Lapsed |