US4348456A
Expired / Lapsed
US
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Abrasion-resistant laminated film
Assignee: Teijin Ltd
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Filing: 1979-04-17
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Granted: 1982-09-07
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Expires: 1999-04-17
Abstract
Abstract A thermoplastic resin film laminate. A thermoplastic film is made abrasion-resistant by coating or laminating (A) one or both sides of a thermoplastic resin film with (B) a vinyl polymer composed mainly of a cyanurate ring-containing (meth)cyanurate having a structure corresponding to the condensation product of 1 mole of cyanuric acid with 3 moles, on the average, of a hydroxyl group-containing (meth)acrylate represented by the formula C H 2 ═CR--COO--R 10 --OH (wherein R is hydrogen atom or methyl group; and R 10 is an alkylene group having a carbon number of 2 to 4), or a cyanurate ring-containing (meth)acrylate having a structure corresponding to the condensation product of 1 mole of cyanuric acid with 2 moles or more and less than 3 moles, on the average, of the above hydroxyl group-containing (meth)acrylate and not more than 0.5 mole, on the average, of a polyhydric alcohol of the formula R 20 --(--OH) y (wherein R 20 is a 2-4 valent saturated hydrocarbon group having a carbon number of 2 to 6, wherein a part of said carbon atoms may be replaced by oxygen atoms forming ether linkages; y is an integer of 2 to 4). The vinyl polymer layer has excellent abrasion resistance and flexibility. The thermoplastic resin film laminate can be used, for example, as a shatter-proof film for window glass, a sunlight-controlling film, a heat radiation reflective film, a plastic mirror, a label, an agricultural film, etc.
Inventors
- 👤 Yoshihiko Imanaka
- 👤 Yoichi Saito
- 👤 Akihiro Horike
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 04:56
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B27/30; B32B27/308; B32B27/28; B32B27/281; B32B27/285; B32B27/32; B32B27/34; B32B27/36; B32B27/365; C; C08; C08F; C08F26/00; C08F26/06; C08J; C08J7/00; C08J7/04; C08J7/0427; C08J7/043; C08J7/046; C08J7/05; C08J2433/00; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/265; Y10T428/31504; Y10T428/31507; Y10T428/31547; Y10T428/31721; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/3188; Y10T428/31884; Y10T428/31891; Y10T428/31909; Y10T428/31913; Y10T428/3192; Y10T428/31928; Y10T428/31935
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
283 words
A thermoplastic resin film laminate composed of a flexible thermoplastic resin film having a thickness of not more than 500 microns coated or laminated, on one or both sides thereof, with a high elongation and abrasion resistant vinyl polymer layer, which layer has a thickness of 0.5 to 1.5 microns and is composed mainly of a polymerized cyanurate ring-containing (meth)acrylate represented by the general formula (I) wherein the cyanurate ring-containing (meth) acrylate contains essentially not more than 1 weight percent of chlorine atoms ##STR11## wherein R 1 , R 2 , R 3 , R 4 , and R 5 each represents a hydrogen atom or a methyl group; R 11 , R 12 , R 13 , R 14 , and R 15 each represents an alkylene group having a carbon number of 2 to 4; R 21 and R 22 each represents a 2-4 valent saturated hydrocarbon group having a carbon number of 2 to 6, wherein a part of the carbon atoms may be replaced by oxygen atoms forming ether linkages; M is --OH and/or a group ##STR12## (wherein R is hydrogen atom or methyl group; R 10 is an alkylene group having a carbon number of 2 to 4); l is 0, 1 or 2; (l+2) is equal to the valence of R 21 and is an integer of 2 to 4; n is 0 or an integer of 1 to 3; p is 0, 1, or 2; (p+2) is equal to the valence of R 22 and is an integer of 2 to 4; when l or p is 2, both Ms may be the same or different; r is 0 or an integer of 1 to 3.
Claim 2
Dependent Claim
283 words
A thermoplastic resin film laminate composed of a flexible thermoplastic resin film having a thickness of not more than 500 microns coated or laminated, on one or both sides thereof, with a high elongation and abrasion resistant vinyl polymer layer, which layer has a thickness of 0.5 to 1.5 microns and is composed mainly of a polymerized cyanurate ring-containing (meth)acrylate represented by the general formula (I) wherein the cyanurate ring-containing (meth) acrylate contains essentially not more than 1 weight percent of chlorine atoms ##STR11## wherein R 1 , R 2 , R 3 , R 4 , and R 5 each represents a hydrogen atom or a methyl group; R 11 , R 12 , R 13 , R 14 , and R 15 each represents an alkylene group having a carbon number of 2 to 4; R 21 and R 22 each represents a 2-4 valent saturated hydrocarbon group having a carbon number of 2 to 6, wherein a part of the carbon atoms may be replaced by oxygen atoms forming ether linkages; M is --OH and/or a group ##STR12## (wherein R is hydrogen atom or methyl group; R 10 is an alkylene group having a carbon number of 2 to 4); l is 0, 1 or 2; (l+2) is equal to the valence of R 21 and is an integer of 2 to 4; n is 0 or an integer of 1 to 3; p is 0, 1, or 2; (p+2) is equal to the valence of R 22 and is an integer of 2 to 4; when l or p is 2, both Ms may be the same or different; r is 0 or an integer of 1 to 3.
Claim 3
Dependent Claim
62 words
A thermoplastic resin film laminate of claim 1, wherein the cyanurate ring-containing (meth)acrylate is a compound of the formula (II) ##STR13## wherein R 1 , R 3 , and R 5 each represents a hydrogen atom or a methyl group; R 11 , R 13 , and R 15 each represents an alkylene group having a carbon number of 2 to 4.
Claim 4
Dependent Claim
141 words
A thermoplastic resin film laminate of claim 1, wherein the cyanurate ring-containing (meth)acrylate is a compound of the formula (III) ##STR14## wherein R 1 -R 5 each represents a hydrogen atom or a methyl group; R 11 -R 15 each represents an alkylene group having a carbon number of 2 to 4; R 21 and R 22 each represents a 2-4 valent saturated hydrocarbon group having a carbon number of 2 to 6, wherein a part of the carbon atoms may be replaced by oxygen atoms forming ether linkages; M is a group ##STR15## (wherein R is hydrogen atom or methyl group; R 10 is an alkylene group having a carbon number of 2 to 4); l and p are 0 or 1; n and r each represents 0 or an integer of 1-3, and (n+r) is an integer of 1-3.
Claim 5
Dependent Claim
27 words
A thermoplastic resin film laminate as claimed in any one of claims 1, 2 or 3, wherein the thermoplastic resin is an aromatic polyester or a polycarbonate.
Claim 6
Dependent Claim
49 words
A thermoplastic resin film laminate of claim 1, wherein said thermoplastic film is formed of a member selected from the group consisting of aromatic polyesters, polyolefins, polyamides, polyimides, cellulose derivatives, polycarbonates, polyvinylchloride, polystyrene, acrylic ester copolymers, methacrylic ester copolymers, polyethers, polyester ether resins, copolymers thereof and poly blends thereof.
Claim 7
Dependent Claim
21 words
A thermoplastic resin film laminate of claim 1, wherein said vinyl polymer layer has a thickness of 1.0 to 10 microns.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-06 | 1986-03-08 | 1986-09-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-06 | 1990-03-08 | 1990-09-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-06 | 1994-03-08 | 1994-09-07 | $7700.00 | Window Closed / Lapsed |