US4348202A
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Hair dye or bleach supports
Assignee: L'Oréal SA
•
Filing: 1980-06-10
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Granted: 1982-09-07
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Expires: 2000-06-10
Abstract
Abstract This invention has for its object the use of certain quaternized polymers as cosmetic agents in certain particular cosmetic compositions.
Inventors
- 👤 Jean-Francois Grollier
- 👤 Chantal Fourcadier
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 04:11
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61Q; A61Q5/00; A61Q5/08; A61Q5/10; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5426; Y; Y10; Y10S; Y10S424/00; Y10S424/02; Y10S424/03
Claims Analysis
Total Claims: 51
Claim 1
Independent Claim
236 words
A hair dye composition free of an anionic polymer comprising an oxidation hair dye present in an amount effective to dye hair and a dye support therefor, said dye support comprising at least one polymer having units of the formula ##STR9## wherein R 1 , R 2 , R 3 and R 4 , each independently represent alkyl having 1-20 carbon atoms, hydroxyalkyl having 1-20 carbon atoms, cycloalkyl having 5 or 6 carbon atoms in the ring, alkyl substituted cycloalkyl having 5 or 6 carbon atoms in the ring and wherein the total number of carbon atoms is less than 20 and phenylalkyl wherein the alkyl moiety has 1-3 carbon atoms, or one or both of the pairs R 1 and R 2 , and R 3 and R 4 , together with the nitrogen atom to which each of said respective pairs is attached, form a ring having 2-6 carbon atoms or a ring having 2-6 carbon atoms and a heteroatom other than nitrogen; X.sup.⊖ is an inorganic or organic acid anion; m is 2 or 3; and A represents linear or branched alkylene or alkenylene having 2-18 carbon atoms, linear or branched alkylene or alkenylene having 2-18 carbon atoms and substituted by one or more of --OH or ═O groups, or linear or branched alkylene or alkenylene having 2-18 carbon atoms and interrupted by one or more of oxygen, sulfur, nitrogen or phenylene groups.
Claim 2
Dependent Claim
236 words
A hair dye composition free of an anionic polymer comprising an oxidation hair dye present in an amount effective to dye hair and a dye support therefor, said dye support comprising at least one polymer having units of the formula ##STR9## wherein R 1 , R 2 , R 3 and R 4 , each independently represent alkyl having 1-20 carbon atoms, hydroxyalkyl having 1-20 carbon atoms, cycloalkyl having 5 or 6 carbon atoms in the ring, alkyl substituted cycloalkyl having 5 or 6 carbon atoms in the ring and wherein the total number of carbon atoms is less than 20 and phenylalkyl wherein the alkyl moiety has 1-3 carbon atoms, or one or both of the pairs R 1 and R 2 , and R 3 and R 4 , together with the nitrogen atom to which each of said respective pairs is attached, form a ring having 2-6 carbon atoms or a ring having 2-6 carbon atoms and a heteroatom other than nitrogen; X.sup.⊖ is an inorganic or organic acid anion; m is 2 or 3; and A represents linear or branched alkylene or alkenylene having 2-18 carbon atoms, linear or branched alkylene or alkenylene having 2-18 carbon atoms and substituted by one or more of --OH or ═O groups, or linear or branched alkylene or alkenylene having 2-18 carbon atoms and interrupted by one or more of oxygen, sulfur, nitrogen or phenylene groups.
Claim 3
Dependent Claim
50 words
The hair dye composition of claim 1 wherein the heteroatom in the ring formed by one or both pairs of R 1 and R 2 , and R 3 and R 4 together with the nitrogen atom to which each of said respective pairs is attached is oxygen or sulfur.
Claim 4
Dependent Claim
225 words
The hair dye composition of claim 1 wherein A represents ortho xylylene, metal xylylene, para xylylene, --(CH 2 ) n --S--(CH 2 ) n --, --(CH 2 ) n --O--(CH 2 ) n --, --(CH 2 ) n --S--S--(CH 2 ) n --, --(CH 2 ) n --SO--(CH 2 ) n --, --(CH 2 ) n --SO 2 --(CH 2 ) n --, --CH 2 --CO--CH 2 --, --CH 2 --C 6 H 4 --C 6 H 4 --CH 2 --, --CH 2 --C 6 H 4 --O--C 6 H 4 --CH 2 --, --CH 2 --C 4 H 4 --SO 2 --C 6 H 4 --CH 2 --, --C 6 H 4 --CH 2 --C 6 H 4 --, --C 6 H 4 --C(CH 3 ) 2 --C 6 H 4 --, --C 6 H 4 --CHOH--C 6 H 4 , --C 6 H.sub. 4 --CO--C 6 H 4 --, --alkylene--N(R 5 )--alkylene--, or arylene--X 1 --arylene--, wherein X 1 represents --O--, --S--, --S--S--, --SO--, --SO 2 -- or --N(R 5 )--, R 5 represents alkyl, cycloalkyl or aralkyl, having up to 20 carbon atoms, said alkylene and arylene groups having up to 20 carbon atoms and n is 2 or 3, and X.sup.⊖ is a halide or an anion derived from a phosphoric acid, sulfuric acid, paratoluene sulfonic acid or a carboxylic acid.
Claim 5
Dependent Claim
18 words
The hair dye composition of claim 1 wherein said polymer has a molecular weight between 1,500 and 50,000.
Claim 6
Dependent Claim
84 words
The hair dye composition of claim 1 wherein A represents --(CH 2 ) n --O--(CH 2 ) n -- wherein n is 2 or 3, --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --CHOH--CH 2 --, --(CH 2 ) p -- wherein p is 2 to 18 or --(CH 2 ) n .sbsb. --CH═CH--(CH 2 ) n .sbsb.2 -- wherein n 1 and n 2 are integers including zero, the sum of n 1 and n 2 being at most 16.
Claim 7
Dependent Claim
55 words
The hair dye composition of claim 1 which also includes an effective amount of an adjuvant to provide said composition in the form of a cream, said adjuvant being a C 12 -C 20 fatty acid soap or a natural or synthetic C 12 -C 20 fatty alcohol in the presence of a nonionic emulsifier.
Claim 8
Dependent Claim
65 words
The hair dye composition of claim 1 which also includes an effective amount of an adjuvant to provide said composition in the form of a gelable liquid which on admixture with hydrogen peroxide gives a gel, said adjuvant being (a) a mixture of an oxyethylenated or polyglycerolated nonionic compound and a solvent or (b) a mixture of a liquid fatty acid soap and a solvent.
Claim 9
Dependent Claim
39 words
The hair dye composition of claim 7 which also includes one or more of a fatty amide, a natural or synthetic fatty alcohol, a natural or synthetic oxyethylenated fatty alcohol, a preservative agent, a sequestering agent or a perfume.
Claim 10
Dependent Claim
23 words
The composition of claim 6 or claim 7 wherein said polymer is present in an amount from 0.5 to 10 percent by weight.
Claim 11
Dependent Claim
23 words
The composition of claim 6 or claim 7 wherein said polymer is present in an amount from 1 to 3 percent by weight.
Claim 12
Dependent Claim
35 words
A two-part hair dye composition, said two parts to be mixed together at the time of use, one part comprising the composition of claim 6 or claim 7, the other part being an oxidizing agent.
Claim 13
Dependent Claim
15 words
The two-part hair dye composition of claim 11 wherein said oxidizing agent is hydrogen peroxide.
Claim 14
Dependent Claim
135 words
A hair dye composition free of an anionic polymer comprising an oxidation hair dye present in an amount effective to dye hair and a dye support therefor, said dye support comprising at least one polymer having the units of the formula ##STR10## wherein R 1 ═R 2 ═R 3 ═R 4 ═CH 3 or C 2 H 5 ; X═Cl m═3; and when R 1 -R 4 ═CH 3 , A represents --CH 2 CH 2 O--CH 2 CH 2 --, --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --CHOH--CH 2 --, --(CH 2 ) 6 -- or --CH 2 --CH═CH--CH 2 --, and when R 1 -R 4 ═C 2 H 5 , A represents --(CH 2 ) 6 --, --CH 2 --CHOH--CH 2 -- or --CH 2 --CH═CH--CH 2 --.
Claim 15
Dependent Claim
135 words
A hair dye composition free of an anionic polymer comprising an oxidation hair dye present in an amount effective to dye hair and a dye support therefor, said dye support comprising at least one polymer having the units of the formula ##STR10## wherein R 1 ═R 2 ═R 3 ═R 4 ═CH 3 or C 2 H 5 ; X═Cl m═3; and when R 1 -R 4 ═CH 3 , A represents --CH 2 CH 2 O--CH 2 CH 2 --, --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --CHOH--CH 2 --, --(CH 2 ) 6 -- or --CH 2 --CH═CH--CH 2 --, and when R 1 -R 4 ═C 2 H 5 , A represents --(CH 2 ) 6 --, --CH 2 --CHOH--CH 2 -- or --CH 2 --CH═CH--CH 2 --.
Claim 16
Dependent Claim
33 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =CH 3 , m=3, X=Cl and A represents --CH 2 CH 2 --O--CH 2 --CH 2 --.
Claim 17
Dependent Claim
29 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =CH 3 , m=3, X=Cl and A represents --CH 2 --CHOH--CH 2 --.
Claim 18
Dependent Claim
33 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =CH 3 , m=3, X=Cl and A represents --CH 2 --C 6 H 4 --CH 2 --.
Claim 19
Dependent Claim
29 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =CH 3 , m=3, X=Cl and A represents --CH 2 --CH═CH--CH 2 --.
Claim 20
Dependent Claim
29 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =CH 3 , m=3, X=Cl and A represents --(CH 2 ) 6 --.
Claim 21
Dependent Claim
31 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =C 2 H 5 , m=3, X=Cl and A represents --(CH 2 ) 6 --.
Claim 22
Dependent Claim
31 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =C 2 H 5 , m=3, X=Cl and A represents --CH 2 --CHOH--CH 2 --.
Claim 23
Dependent Claim
31 words
The hair dye composition of claim 13 wherein R 1 =R 2 =R 3 =R 4 =C 2 H 5 , m=3, X=Cl and A represents --CH 2 --CH═CH--CH 2 --.
Claim 24
Dependent Claim
162 words
A hair dye composition free from an anionic polymer in cream form comprising an oxidation hair dye present in an amount effective to dye hair, at least one polymer having units of the formula ##STR11## wherein R 1 =R 2 =R 3 =R 4 =CH 3 or C 2 H 5 ; X is Cl; m is 3; wherein when R 1 --R 4 ═CH 3 , A represents --CH 2 --CH 2 --O--CH 2 --CH 2 --, --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --CHOH--CH 2 --, --(CH 2 ) 6 -- or --CH 2 --CH═CH--CH 2 -- and when R 1 --R 4 ═C 2 H 5 , A represents --(CH 2 ) 6 --, --CH 2 --CHOH--CH 2 -- or --CH 2 --CH═CH--CH 2 --; and at least one of a C 12 to C 20 fatty acid soap or a C 12 to C 20 fatty alcohol in the presence of a nonionic emulsifier.
Claim 25
Dependent Claim
162 words
A hair dye composition free from an anionic polymer in cream form comprising an oxidation hair dye present in an amount effective to dye hair, at least one polymer having units of the formula ##STR11## wherein R 1 =R 2 =R 3 =R 4 =CH 3 or C 2 H 5 ; X is Cl; m is 3; wherein when R 1 --R 4 ═CH 3 , A represents --CH 2 --CH 2 --O--CH 2 --CH 2 --, --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --CHOH--CH 2 --, --(CH 2 ) 6 -- or --CH 2 --CH═CH--CH 2 -- and when R 1 --R 4 ═C 2 H 5 , A represents --(CH 2 ) 6 --, --CH 2 --CHOH--CH 2 -- or --CH 2 --CH═CH--CH 2 --; and at least one of a C 12 to C 20 fatty acid soap or a C 12 to C 20 fatty alcohol in the presence of a nonionic emulsifier.
Claim 26
Dependent Claim
45 words
The hair dye composition of claim 22 wherein the fatty acid of said soap is selected from the group consisting of lauric acid, myristic acid, palmitic acid, oleic acid stearic acid, hydroxy stearic acid, arachic acid, ricinoleic acid, lanolinic acid, phenylstearic acid, and linoleic acid.
Claim 27
Dependent Claim
36 words
The hair dye composition of claim 22 wherein said soap is made using an alkalizing agent selected from the group consisting of soda, potash, ammonia, monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N-ethylmorpholine, 2-amino-1-butanol, 2-amino-2-methyl-1-propanol and mixtures thereof.
Claim 28
Dependent Claim
26 words
The hair dye composition of claim 22 wherein said soap is present in an amount between 1 and 60 percent by weight of said composition .
Claim 29
Dependent Claim
25 words
The hair dye composition of claim 22 wherein said soap is present in an amount between 5 and 30 percent by weight of said composition.
Claim 30
Dependent Claim
43 words
The hair dye composition of claim 22 wherein said C 12 to C 20 fatty alcohol is selected from the alcohols derived from copra fatty acids, myristic alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, isostearyl alcohol, hydroxystearyl alcohol, oleic alcohol and ricinoleic alcohol.
Claim 31
Dependent Claim
31 words
The hair dye composition of claim 22 wherein said C 12 to C 20 fatty alcohol is present in an amount between 1 and 60 percent by weight of said composition.
Claim 32
Dependent Claim
31 words
The hair dye composition of claim 22 wherein said C 12 to C 20 fatty alcohol is present in an amount between 5 and 30 percent by weight of said composition.
Claim 33
Dependent Claim
39 words
The hair dye composition of claim 22 wherein said nonionic emulsifier is an oxyethylenated or polyglycerolated natural or synthetic C 10 -C 20 fatty alcohol present in an amount between 1 and 60 percent by weight of said composition.
Claim 34
Dependent Claim
95 words
The hair dye composition of claim 22 wherein said nonionic emulsifier is selected from the group consisting of oleic alcohol oxyethylenated with 10-30 moles of ethylene oxide, cetyl alcohol oxyethylenated with 6 to 10 moles of ethylene oxide, cetylstearyl alcohol oxyethylenated with 10 moles of ethylene oxide, oleocetyl alcohol oxyethylenated with 30 moles of ethylene oxide, stearyl alcohol oxyethylenated with 10, 15 or 20 moles of ethylene oxide, oleic alcohol polyglycerolated with 4 moles of glycerol and a C 9 to C 20 synthetic fatty alcohol oxyethylenated with 5 to 30 moles of ethylene oxide.
Claim 35
Dependent Claim
26 words
The hair dye composition of claim 30 wherein said nonionic emulsifier is present in an amount between 5 and 30 percent by weight of said composition.
Claim 36
Dependent Claim
160 words
A hair dye composition free from an anionic polymer in gelable liquid form comprising an oxidation hair dye present in an amount effective to dye hair, at least one polymer having units of the formula ##STR12## wherein R 1 =R 2 =R 3 =R 4 =CH 3 or C 2 H 5 ; X is Cl; m is 3; wherein when R 1 --R 4 =CH 3 , A represents --CH 2 --CH 2 --O--CH 2 --CH 2 --, --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --CHOH--CH 2 --, --(CH 2 ) 6 -- or --CH 2 --CH═CH--CH 2 --, and when R 1 --R 4 ═C 2 H 5 , A represents --(CH 2 ) 6 --, --CH 2 --CHOH--CH 2 -- or --CH 2 --CH═CH--CH 2 --; and (a) a mixture of an oxyethylenated or polyglycerolated nonionic compound and a solvent or (b) a mixture of a liquid fatty acid soap and a solvent.
Claim 37
Dependent Claim
160 words
A hair dye composition free from an anionic polymer in gelable liquid form comprising an oxidation hair dye present in an amount effective to dye hair, at least one polymer having units of the formula ##STR12## wherein R 1 =R 2 =R 3 =R 4 =CH 3 or C 2 H 5 ; X is Cl; m is 3; wherein when R 1 --R 4 =CH 3 , A represents --CH 2 --CH 2 --O--CH 2 --CH 2 --, --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --CHOH--CH 2 --, --(CH 2 ) 6 -- or --CH 2 --CH═CH--CH 2 --, and when R 1 --R 4 ═C 2 H 5 , A represents --(CH 2 ) 6 --, --CH 2 --CHOH--CH 2 -- or --CH 2 --CH═CH--CH 2 --; and (a) a mixture of an oxyethylenated or polyglycerolated nonionic compound and a solvent or (b) a mixture of a liquid fatty acid soap and a solvent.
Claim 38
Dependent Claim
62 words
The hair dye composition of claim 33 wherein said mixture (a) the nonionic compound is oleic alcohol oxyethylenated with 4 or 10 moles of ethylene oxide, a C 10 -C 20 synthetic fatty alcohol oxyethylenated with 4 or 6 moles of ethylene oxide and a C 9 -C 15 synthetic fatty alcohol oxyethylenated with 2, 6 or 9 moles of ethylene oxide.
Claim 39
Dependent Claim
27 words
The hair dye composition of claim 33 where in said mixture (a) the nonionic compound is nonylphenol polyether oxyethylenated with 4 or 9 moles of ethylene oxide.
Claim 40
Dependent Claim
26 words
The hair dye composition of claim 33 where said nonionic compound is present in an amount between 5 and 60 percent by weight of said composition.
Claim 41
Dependent Claim
26 words
The hair dye composition of claim 33 where said nonionic compound is present in an amount between 5 and 40 percent by weight of said composition.
Claim 42
Dependent Claim
32 words
The hair dye composition of claim 33 where in said mixture (a) the nonionic compound is selected from the group consisting of oleic alcohol polyglycerolated with 2 or 4 moles of glycerol.
Claim 43
Dependent Claim
62 words
The hair dye composition of claim 33 where in said mixture (b) the fatty acid soap is derived from (1) an acid selected from the group consisting of oleic acid, linoleic aicd, ricinoleic acid and isostearic acid and (2) an alkalizing agent selected from the group consisting of soda, potash, ammonia, monoethanolamine, diethanolamine, triethanolamine, mono-isopropanolamine, di-isopropanolamine, N-ethylmorpholine, 2-amino-1-butanol, 2-amino-2-methyl-1-propanol and mixtures thereof.
Claim 44
Dependent Claim
27 words
The hair dye composition of claim 33 wherein said fatty acid soap is present in an amount between 5 and 60 percent by weight of said composition.
Claim 45
Dependent Claim
27 words
The hair dye composition of claim 33 wherein said fatty acid soap is present in an amount between 5 and 40 percent by weight of said composition.
Claim 46
Dependent Claim
45 words
The composition of claim 33 where in mixture (a) or mixture (b) the solvent is selected from the group consisting of ethyl alcohol, propylalcohol, isopropyl alcohol, propylene glycol, methyl glycol, ethyl glycol, butyl glycol, diethylene glycol, dipropylene glycol, hexylene glycol and diethylene glycol monoethyl ether.
Claim 47
Dependent Claim
19 words
The composition of claim 42 wherein said solvent is present in an amount between 2 and 20 weight percent.
Claim 48
Dependent Claim
19 words
The composition of claim 42 wherein said solvent is present in an amount between 5 and 15 weight percent.
Claim 49
Dependent Claim
37 words
The composition of claim 33 which also includes a fatty amide selected from the group consisting of oleic diethanolamide, lauric diethanolamide, copra monoethanolamide and copra diethanolamide present in an amount between 0.5 and 15 percent by weight.
Claim 50
Dependent Claim
45 words
The composition of claim 33 which also includes a natural or synthetic alcohol selected from the group consisting of oleic alcohol, lauric alcohol, octyldodecyl alcohol, hexyldodecyl alcohol, isostearyl alcohol, ricinoleyl alcohol and linoleyl alcohol present in an amount of 1 to 25 percent by weight.
Claim 51
Dependent Claim
49 words
A process for dyeing hair comprising applying to said hair an effective amount of the composition of claim 6 or 7 to dye said hair, permitting said composition to remain in contact with the hair for a time sufficient to obtain the desired dyeing effect and rinsing said hair.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-06 | 1986-03-08 | 1986-09-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-06 | 1990-03-08 | 1990-09-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-06 | 1994-03-08 | 1994-09-07 | $7700.00 | Window Closed / Lapsed |