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US4344862A Expired / Lapsed US ⏱️ 0.0 years remaining

Reaction products of sulfonamido-carboxylic acids or carboxamido-carboxylic acids with alkanolamines, and their use as low-foaming corrosion inhibitors

Assignee: BASF SE
•
Filing: 1980-10-20
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Granted: 1982-08-17
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Expires: 2000-10-20
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Abstract

Abstract Products which have been obtained by reacting an acid of the formula I ##STR1## where R 1 and R 2 are hydrogen, fluorine, chlorine, bromine or alkyl or alkoxy of 1 to 4 carbon atoms, but the sum of the carbon atoms of R 1 and R 2 is not greater than 7 and preferably not greater than 3, A is a benzene, naphthalene or anthracene radical or a biphenyl structure, such as a diphenyl, diphenylmethane, diphenyl ether, diphenyl sulfide, diphenyl sulfoxide or diphenyl sulfone radical, R 3 is hydrogen, alkyl of not more than 4 carbon atoms, β-cyanoethyl or hydroxyalkyl of 2 to 4 carbon atoms, R 4 is hydrogen, fluorine, chlorine, bromine, alkyl or alkoxy of 1 to 4 carbon atoms, hydroxyl or carboxyl and X is --SO 2 -- or --CO--, with an amine of the formula II ##STR2## where R 5 and R 6 are hydrogen, C 1 -C 4 -alkyl, C 2 -C 4 -hydroxyalkyl and/or ##STR3## R 7 and R 8 being hydrogen, C 1 -C 4 -alkyl or C 2 -C 4 -hydroxyalkyl and n being an integer from 2 to 4, in the ratio, expressed in terms of equivalents, of from 1:1 to 1:4, and corrosion inhibitors which contain these products, with or without the admixture of an alkanolamine/boric acid reaction product.

Inventors

  • 👤 Rudi Widder
  • 👤 Elmar Getto
  • 👤 Albert Hettche

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 14:04
CPC Classifications
C; C23; C23F; C23F11/00; C23F11/08; C23F11/10; C23F11/16; C23F11/164; C23F11/14; C23F11/145; Y; Y10; Y10S; Y10S507/00; Y10S507/939

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 187 words
A product which is obtained by reacting an acid of the formula I ##STR9## where R 1 and R 2 are hydrogen, fluorine, chlorine, bromine or alkyl or alkoxy of 1 to 4 carbon atoms, but the sum of the carbon atoms of R 1 and R 2 is not greater than 7 and preferably not greater than 3, A is a benzene, naphthalene or anthracene radical or a biphenyl structure, R 3 is hydrogen, alkyl of not more than 4 carbon atoms, β-cyanoethyl or hydroxyalkyl of 2 to 4 carbon atoms, R 4 is hydrogen, fluorine, chlorine, bromine, alkyl or alkoxy of 1 to 4 carbon atoms, hydroxyl or carboxyl and X is --SO 2 -- or --CO--, with an amine of the formula II ##STR10## where R 5 and R 6 are hydrogen, C 1 -C 4 -alkyl, C 2 -C 4 -hydroxyalkyl and/or ##STR11## R 7 and R 8 being hydrogen, C 1 -C 4 -alkyl or C 2 -C 4 -hydroxyalkyl and n being an integer from 2 to 4, in the ratio, expressed in terms of equivalents, of from 1:1 to 1:4.
Claim 2
Dependent Claim 187 words
A product which is obtained by reacting an acid of the formula I ##STR9## where R 1 and R 2 are hydrogen, fluorine, chlorine, bromine or alkyl or alkoxy of 1 to 4 carbon atoms, but the sum of the carbon atoms of R 1 and R 2 is not greater than 7 and preferably not greater than 3, A is a benzene, naphthalene or anthracene radical or a biphenyl structure, R 3 is hydrogen, alkyl of not more than 4 carbon atoms, β-cyanoethyl or hydroxyalkyl of 2 to 4 carbon atoms, R 4 is hydrogen, fluorine, chlorine, bromine, alkyl or alkoxy of 1 to 4 carbon atoms, hydroxyl or carboxyl and X is --SO 2 -- or --CO--, with an amine of the formula II ##STR10## where R 5 and R 6 are hydrogen, C 1 -C 4 -alkyl, C 2 -C 4 -hydroxyalkyl and/or ##STR11## R 7 and R 8 being hydrogen, C 1 -C 4 -alkyl or C 2 -C 4 -hydroxyalkyl and n being an integer from 2 to 4, in the ratio, expressed in terms of equivalents, of from 1:1 to 1:4.
Claim 3
Dependent Claim 27 words
A low-foaming corrosion inhibitor for iron, ferrous metals, aluminum, copper, zinc or alloys comprising any of these metals, which contains a product as claimed in claim 1.
Claim 4
Dependent Claim 66 words
A corrosion inhibitor as claimed in claim 2, which additionally contains up to 85% by weight, based on the reaction product defined in claim 1, of one or more reaction products obtained from orthoboric acid and one or more alkanolamines of 2 or 3 carbon atoms per alkanol group, the orthoboric acid and alkanolamine having been used in a molar ratio of from 1:1 to 1:4.
Claim 5
Dependent Claim 27 words
The product of claim 1 wherein said biphenyl is selected from the group consisting of diphenyl, diphenylmethane, diphenyl ether, diphenyl sulfide diphenyl sulfoxide, and diphenyl sulfone radical.

References Cited (Backward Citations)

DE900041C Cited
US2578725A Cited
US2908648A Cited
US3556994A Cited
US4060522A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-08-16 1986-02-15 1986-08-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-08-16 1990-02-15 1990-08-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-08-16 1994-02-15 1994-08-17 $7700.00 Window Closed / Lapsed

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