Optical waveguide soot preform with reduced inner layer stress and method of making

Claim 2

In the process for forming a substantially cylindrical optical waveguide preform having a radially varying composition and refractive index which comprises the step of successively applying to the exterior peripheral surface of a substantially cylindrical starting member first and subsequently applied core layers of vitreous soot of varying composition and refractive index, the layers proximate to the starting member containing higher concentrations of refractive-index-increasing dopants than the layers more distant therefrom and being in a state of tensile stress at ambient temperatures, the improvement wherein: the tensile stress in the first-applied layer is reduced by modifying the composition of said layer during application to reduce the thermal expansion coefficient thereof to a value below that of at least one subsequently applied layer.

Claim 3

A process in accordance with claim 1 wherein the refractive-index-increasing dopant is selected from the group consisting of GeO 2 , P 2 O 5 and combinations thereof.

Claim 4

A process in accordance with claim 1 wherein the composition of the first-applied layer is modified by reducing the concentration of refractive-index-increasing dopants therein.

Claim 5

A process in accordance with claim 1 wherein the thermal expansion coefficient of the first applied layer is reduced to a value at which that layer is in a state of compression at ambient temperatures.

Claim 6

A process in accordance with claim 1 wherein the thickness of the first applied layer does not exceed about 3% of the total thickness of the core layers.

Claim 7

A cylindrical optical waveguide soot preform comprising a longitudinal center hole and a surrounding preform body comprising a core portion have a radially varying composition, the core portion being composed of a plurality of concentric core layers of vitreous soot including an inner layer defining the cylindrical surface of the longitudinal center hole and outer layers making up the remainder of the core portion, the soot layers proximate to the inner layer containing higher concentrations of refractive-index-increasing dopants than soot layers positioned exteriorly thereof, and being in a state of tensile stress at ambient temperatures, wherein, following soot deposition but prior to any treatment to remove residual water or consolidated the preform to clear glass, the inner layer defining the center hole of the preform has a thermal expansion coefficient lower than that of at least one of the layers proximate thereto, so as to exhibit a reduced level of tensile stress with respect to said proximate layer at ambient temperatures.

Claim 8

A cylindrical optical waveguide soot preform comprising a longitudinal center hole and a surrounding preform body comprising a core portion have a radially varying composition, the core portion being composed of a plurality of concentric core layers of vitreous soot including an inner layer defining the cylindrical surface of the longitudinal center hole and outer layers making up the remainder of the core portion, the soot layers proximate to the inner layer containing higher concentrations of refractive-index-increasing dopants than soot layers positioned exteriorly thereof, and being in a state of tensile stress at ambient temperatures, wherein, following soot deposition but prior to any treatment to remove residual water or consolidated the preform to clear glass, the inner layer defining the center hole of the preform has a thermal expansion coefficient lower than that of at least one of the layers proximate thereto, so as to exhibit a reduced level of tensile stress with respect to said proximate layer at ambient temperatures.

Claim 9

An optical waveguide preform in accordance with claim 6 wherein the refractive-index-increasing dopant is selected from the group consisting of GeO 2 , P 2 O 5 and combinations thereof.

Claim 10

An optical waveguide preform in accordance with claim 6 wherein the inner layer contains a lower concentration of refractive-index-increasing dopants than at least one of the layers proximate thereto.

Claim 11

An optical waveguide preform in accordance with claim 6 wherein the inner layer is in a state of compression at ambient temperatures.

Claim 12

An optical waveguide preform in accordance with claim 6 wherein the thickness of the first applied layer does not exceed about 3% of the total thickness of the core layers.