US4343772A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Thermal reactor
Assignee: National Aeronautics and Space Administration
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Filing: 1980-02-29
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Granted: 1982-08-10
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Expires: 2000-02-29
Abstract
Abstract A thermal reactor apparatus and method of pyrolyticaly decomposing silane gas into liquid silicon product and hydrogen by-product gas is disclosed. The thermal reactor (1) has a reaction chamber (21) which is heated well above the decomposition temperature of silane. An injecter probe (100) introduces the silane gas tangentially into the reaction chamber (21) to form a first, outer, forwardly moving vortex (22) containing the liquid silicon product and a second, inner, rearwardly moving vortex (23) containing the by-product hydrogen gas. The liquid silicon in the first outer vortex (22) deposits onto the interior walls (28) of the reaction chamber (21) to form an equilibrium skull layer (26) which flows to the forward or bottom end of the reaction chamber where it is removed. The by-product hydrogen gas in the second inner vortex (23) is removed from the top or rear of the reaction chamber by a vortex finder (30). The injecter probe (100) which introduces the silane gas into the reaction chamber (21) is continually cooled by a cooling jacket (110) having water circulating therethrough to keep the temperature of the silane gas well below its decomposition temperature prior to being introduced into the reaction zone.
Inventors
- 👤 with respect to an invention of Frosch Robert A. Administrator of the National Aeronautics and Space Administation
- 👤 Harry Levin
- 👤 Larry B. Ford
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 09:18
CPC Classifications
B; B01; B01J; B01J19/00; B01J19/24; B01J19/2405; B01J6/00; B01J6/008; C; C01; C01B; C01B33/00; C01B33/02; C01B33/021; C01B33/027; C01B33/029; B01J2219/00; B01J2219/00049; B01J2219/00051; B01J2219/00074; B01J2219/00076; B01J2219/00085; B01J2219/00087; B01J2219/00094; B01J2219/02; B01J2219/0204; F; F28; F28D; F28D7/00; F28D7/10; F28D7/103
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
182 words
A thermal reactor apparatus for pyrolytically decomposing a precursor gas containing a single decomposable compound into a liquid product and a by-product gas comprising: a reactor having walls defining a reaction chamber; means for heating said reaction chamber to a temperature above the melting point of said liquid product and for heating chamber to a temperature above the decomposition temperature of the precursor gas; injector means disposed within the interior of said reaction chamber for vortically introducing said precursor gas into said reaction chamber to form a first outer, forwardly moving vortex containing said precursor gas and said liquid product and a second inner, rearwardly moving vortex containing said by-product gas; cooling means for cooling said injector portion within the interior of said chamber to a temperature substantially below the decomposition temperature of the precursor gas; first means associated with the forward end of said reaction chamber for removing said liquid product from said reaction chamber; and second means associated with the rearward end of said reaction chamber in communication with said second vortex for removing by-product gas from said reaction chamber.
Claim 2
Dependent Claim
182 words
A thermal reactor apparatus for pyrolytically decomposing a precursor gas containing a single decomposable compound into a liquid product and a by-product gas comprising: a reactor having walls defining a reaction chamber; means for heating said reaction chamber to a temperature above the melting point of said liquid product and for heating chamber to a temperature above the decomposition temperature of the precursor gas; injector means disposed within the interior of said reaction chamber for vortically introducing said precursor gas into said reaction chamber to form a first outer, forwardly moving vortex containing said precursor gas and said liquid product and a second inner, rearwardly moving vortex containing said by-product gas; cooling means for cooling said injector portion within the interior of said chamber to a temperature substantially below the decomposition temperature of the precursor gas; first means associated with the forward end of said reaction chamber for removing said liquid product from said reaction chamber; and second means associated with the rearward end of said reaction chamber in communication with said second vortex for removing by-product gas from said reaction chamber.
Claim 3
Dependent Claim
29 words
The thermal reactor of claim 1 wherein said jacket for cooling said injector extends along the entire length of the portion of said injector disposed within said reaction chamber.
Claim 4
Dependent Claim
40 words
The thermal reactor of claim 1 wherein said injector means introduces said precursor gas into a hot zone within said reaction chamber which is maintained at a temperature at least 300° C. above the decomposition temperature of said precursor gas.
Claim 5
Dependent Claim
38 words
The thermal reactor of claim 1 wherein said injector means includes a terminal orifice disposed in a plane normal to the axis of the first and second vortexes to introduce said precursor gas tangentially into said reaction chamber.
Claim 6
Dependent Claim
24 words
The thermal reactor apparatus of claim 1 wherein said second means for removing by-product gas comprises a vortex finder extending into said reaction chamber.
Claim 7
Dependent Claim
25 words
The thermal reactor apparatus of claim 5 wherein the terminal orifice of said injector means is disposed rearward of the inlet to said vortex finder.
Claim 8
Dependent Claim
26 words
The thermal reactor apparatus of claim 1 wherein said cooling means comprises a jacket for said injector for receiving a continuous flow of heat exchange fluid.
Claim 9
Dependent Claim
31 words
The thermal reactor of claim 1 wherein said heating means includes a tubular heater surrounding said reaction chamber extending from the forward end to the rearward end of said reaction chamber.
Claim 10
Dependent Claim
27 words
The thermal reactor of claim 1 wherein said reactor walls include an interior surface defining a flow path to said first means for removing said liquid product.
Claim 11
Dependent Claim
33 words
The thermal reactor of claim 9 wherein the interior surface of said reactor walls are readily wetted by said liquid product to provide a continuous film of liquid product along said flow path.
Claim 12
Dependent Claim
28 words
The thermal reactor of claim 9 wherein the interior surface of said reactor walls contains a coating whereby discrete beads of liquid product flow along said flow path.
Claim 13
Dependent Claim
30 words
The thermal reactor of claim 10 wherein said reactor walls have an inner coating composed of a substance selected from the group consisting of carbon, silicon carbide and silicon nitride.
Claim 14
Dependent Claim
19 words
The thermal reactor of claim 11 wherein said reactor walls have an inner layer of an alkaline metal fluoride.
Claim 15
Dependent Claim
15 words
The thermal reactor of claim 1 wherein said reactor walls have a circular cross section.
References Cited (Backward Citations)
US1402784A
Cited
US2697031A
Cited
US2849930A
Cited
US3057690A
Cited
US3099523A
Cited
US3694168A
Cited
US3766661A
Cited
US4059415A
Cited
US4123229A
Cited
US4162291A
Cited
JPS5518233A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-08-09 | 1986-02-08 | 1986-08-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-08-09 | 1990-02-08 | 1990-08-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-08-09 | 1994-02-08 | 1994-08-10 | $7700.00 | Window Closed / Lapsed |