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US4341679A Expired / Lapsed US ⏱️ 0.0 years remaining

Vinylidene chloride co-polymer latex compositions

Assignee: Syngenta Ltd
•
Filing: 1977-12-12
•
Granted: 1982-07-27
•
Expires: 1997-12-12
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Abstract

Abstract An aqueous latex of a copolymer derived from defined relative proportions of (i) vinylidene chloride, (ii) vinyl chloride, (iii) an alkyl acrylate or methacrylate and (iv) an unsaturated carboxylic acid forms stable protective films on a variety of substrates.

Inventors

  • 👤 Anthony J. Burgess
  • 👤 David L. Gardner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 10:14
CPC Classifications
C; C09; C09D; C09D127/00; C09D127/02; C09D127/04; C09D127/08; C08; C08F; C08F214/00; C08F214/02; C08F214/04; C08F214/08; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31645; Y10T428/31649; Y10T428/31678; Y10T428/31692; Y10T428/31699; Y10T428/31855

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 144 words
An aqueous latex of a copolymer capable of forming stable films which have excellent protective properties on metallic substrates, said films having good chemical resistance and low permeability to water vapour, said copolymer consisting essentially of (i) vinylidene chloride, (ii) vinyl chloride, (iii) one or more alkyl acrylates having from 1 to 12 carbon atoms in the alkyl group and/or one or more alkyl methacrylates having from 2 to 12 carbon atoms in the alkyl group and (iv) one or more aliphatic alpha-beta-unsaturated carboxylic acids, the proportion of vinylidene chloride being from 65 to 90 parts by weight, the proportion of the said alkyl acrylates and/or methacrylates being from 2 to 15 parts by weight and the proportion of the said carboxylic acids being from 0.2 to 8 parts by weight, per hundred parts by weight of the total vinylidene chloride and vinyl chloride.
Claim 2
Dependent Claim 144 words
An aqueous latex of a copolymer capable of forming stable films which have excellent protective properties on metallic substrates, said films having good chemical resistance and low permeability to water vapour, said copolymer consisting essentially of (i) vinylidene chloride, (ii) vinyl chloride, (iii) one or more alkyl acrylates having from 1 to 12 carbon atoms in the alkyl group and/or one or more alkyl methacrylates having from 2 to 12 carbon atoms in the alkyl group and (iv) one or more aliphatic alpha-beta-unsaturated carboxylic acids, the proportion of vinylidene chloride being from 65 to 90 parts by weight, the proportion of the said alkyl acrylates and/or methacrylates being from 2 to 15 parts by weight and the proportion of the said carboxylic acids being from 0.2 to 8 parts by weight, per hundred parts by weight of the total vinylidene chloride and vinyl chloride.
Claim 3
Dependent Claim 33 words
A latex according to claim 1 wherein the proportion of vinylidene chloride is from 70 to 80 parts by weight per hundred parts by weight of the total vinylidene chloride and vinyl chloride.
Claim 4
Dependent Claim 35 words
A latex according to claim 1 wherein the proportion of the alkyl acrylate(s) and/or methacrylate(s) is from 4 to 10 parts by weight per hundred parts by weight of total vinylidene chloride and vinyl chloride.
Claim 5
Dependent Claim 33 words
A latex according to claim 1 wherein the proportion of the carboxylic acid(s) is from 1 to 4 parts by weight per hundred parts by weight of total vinylidene chloride and vinyl chloride.
Claim 6
Dependent Claim 13 words
A latex according to claim 1 containing 2-ethylhexyl acrylate as the alkyl acrylate.
Claim 7
Dependent Claim 15 words
A latex according to claim 1 containing butyl methacrylate or 2-ethylhexyl methacrylate as the methacrylate.
Claim 8
Dependent Claim 13 words
A latex according to claim 1 containing acrylic acid as the carboxylic acid.
Claim 9
Dependent Claim 17 words
A latex according to claim 1 characterised in that the minimum film-forming temperature is below 30° C.
Claim 10
Dependent Claim 20 words
A latex according to claim 8 having a minimum film-forming temperature in the range from -10° C. to 20° C.
Claim 11
Dependent Claim 20 words
A latex according to claim 9 having a minimum film-forming temperature in the range from 6° C. to 15° C.
Claim 12
Dependent Claim 101 words
An aqueous latex of a copolymer capable of forming stable films which have excellent protection properties on metallic substrates, said films having good chemical resistant and low permeability to water vapour, said copolymer consisting essentially of (i) vinylidene chloride, (ii) vinyl chloride, (iii) 2-ethylhexyl acrylate and (iv) acrylic acid, the proportion of vinylidene chloride being from 65 to 90 parts by weight, the proportion of 2-ethylhexyl acrylate being from 2 to 15 parts by weight and the proportion of acrylic acid being from 0.2 to 8 parts by weight, per hundred parts by weight of total vinylidene chloride and vinyl chloride.
Claim 13
Dependent Claim 101 words
An aqueous latex of a copolymer capable of forming stable films which have excellent protection properties on metallic substrates, said films having good chemical resistant and low permeability to water vapour, said copolymer consisting essentially of (i) vinylidene chloride, (ii) vinyl chloride, (iii) 2-ethylhexyl acrylate and (iv) acrylic acid, the proportion of vinylidene chloride being from 65 to 90 parts by weight, the proportion of 2-ethylhexyl acrylate being from 2 to 15 parts by weight and the proportion of acrylic acid being from 0.2 to 8 parts by weight, per hundred parts by weight of total vinylidene chloride and vinyl chloride.
Claim 14
Dependent Claim 28 words
A latex according to claim 1 wherein said aliphatic alpha-beta-unsaturated carboxylic acids are selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid and citraconic acid.

References Cited (Backward Citations)

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GB761838A Cited
US2829069A Cited
US3226370A Cited
US3468703A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-07-26 1986-01-25 1986-07-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-07-26 1990-01-25 1990-07-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-07-26 1994-01-25 1994-07-27 $7700.00 Window Closed / Lapsed

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