US4340718A
Expired / Lapsed
US
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Stabilized copolyester material
Assignee: Eastman Chemical Co
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Filing: 1980-06-02
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Granted: 1982-07-20
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Expires: 2000-06-02
Abstract
Abstract Disclosed are novel copolyester materials having improved weatherability and useful, for example, as films, fibers, sheeting and the like in outdoor applications where long and daily exposure to actinic radiation is encountered. These copolyesters comprise, for example, polyethylene terephthalate containing a total of from about 0.3 to about 5.0%, preferably from about 0.6 to about 2.0% by weight of one or more moieties having the formula ##STR1## where R 1 is cyano, alkylcarbonyl, cycloalkylcarbonyl or arylcarbonyl; R 2 and R 3 are, for example, alkyl, cycloalkyl, or aryl which may be substituted with a large variety of groups; and --X-- is ortho, meta, or para to the -ylene linkage and is selected from groups of the formulae ##STR2## wherein R is alkylene of 1-10 carbons, aryl, or cycloalkyl, each of which may be substituted.
Inventors
- 👤 Joseph S. Zannucci
- 👤 Bobby J. Sublett
- 👤 Gether Irick, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 16:50
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/12; C08G63/52; C08G63/54; C08G63/68
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
162 words
A copolyester having an inherent viscosity of at least 0.4 and containing in copolymerized form from about 0.3 to about 5.0% by weight of one or more of the stabilizing moieties having the general formula ##STR31## where R 1 is cyano, alkylcarbonyl, cycloalkylcarbonyl or arylcarbonyl; R 2 is alkyl, cycloalkyl, or aryl; R 3 represents 1-4 groups each independently selected from H, Cl, F, alkyl, cycloalkyl, alkoxy, aryl or aryloxy; wherein all of the above alkyl and alkylene moieties comprising or being part of the R 1 , R 2 and R 3 groups contain from 1-8 carbons; --X-- is ortho, meta, or para to the -ylene linkage and is selected from groups of the formulae ##STR32## wherein R is alkylene of 1-10 carbons, arylene, or cycloalkylene; and wherein all of the above alkyl, alkylene, arylene and cycloalkylene groups may be substituted with up to three substituents selected from halogen, alkyl of 1-8 carbons, alkoxy of 1-8 carbons, aryl, cycloalkyl and CN.
Claim 2
Dependent Claim
162 words
A copolyester having an inherent viscosity of at least 0.4 and containing in copolymerized form from about 0.3 to about 5.0% by weight of one or more of the stabilizing moieties having the general formula ##STR31## where R 1 is cyano, alkylcarbonyl, cycloalkylcarbonyl or arylcarbonyl; R 2 is alkyl, cycloalkyl, or aryl; R 3 represents 1-4 groups each independently selected from H, Cl, F, alkyl, cycloalkyl, alkoxy, aryl or aryloxy; wherein all of the above alkyl and alkylene moieties comprising or being part of the R 1 , R 2 and R 3 groups contain from 1-8 carbons; --X-- is ortho, meta, or para to the -ylene linkage and is selected from groups of the formulae ##STR32## wherein R is alkylene of 1-10 carbons, arylene, or cycloalkylene; and wherein all of the above alkyl, alkylene, arylene and cycloalkylene groups may be substituted with up to three substituents selected from halogen, alkyl of 1-8 carbons, alkoxy of 1-8 carbons, aryl, cycloalkyl and CN.
Claim 3
Dependent Claim
18 words
The copolyester according to claim 1 wherein the stabilizing moiety is selected from those of the formulae: ##STR33##
Claim 4
Dependent Claim
106 words
The copolyester according to claim 2 wherein the dibasic acid is selected from one or both of terephthalic and 1,2-, 1,3- or 1,4-cyclohexanedicarboxylic, and may include up to about 40 mole % of a modifying acid such as adipic, sebacic, p,p'-sulfonyldibenzoic, p-hydroxybenzoic, 1,4-, 1,5-, 2,7- or 2,6-naphthalenedicarboxylic, 4,4'-diphenic or 4,4'-benzophenonedicarboxylic and the glycols are selected from one or more of ethylene glycol, 1,2- or 1,3-propanediol, 1,2- or 1,3- or 1,4-cyclohexanedimethanol, neopentyl glycol, 1,5- or 2,4-pentanediol, 1,6- or 2,5-hexanediol, 1,3-, 2,3- or 1,4-butanediol and 2,2,4,4-tetramethylcyclobutane-1,3-diol and may contain up to about 40 mole % of one or more diethylene glycol, poly(ethylene glycol), poly(propylene glycol), and poly(butylene glycol).
Claim 5
Dependent Claim
23 words
The copolyester of claim 3 wherein the principal polyester comprises in a molar ratio of from about 4/1 to about 1/4, ethylene/1,4-cyclohexylenedimethylene terephthalate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-07-19 | 1986-01-18 | 1986-07-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-07-19 | 1990-01-18 | 1990-07-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-07-19 | 1994-01-18 | 1994-07-20 | $7700.00 | Window Closed / Lapsed |