US4339366A
Expired / Lapsed
US
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Process for the production of polyester resins
Assignee: Individual
•
Filing: 1981-11-09
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Granted: 1982-07-13
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Expires: 2001-11-09
Abstract
Abstract Polyester resins are produced by chemically reacting a broken-down alkali metal lignin-cellulose polymer, a substituted organic hydroxy compound and a polycarboxylic acid compound and/or a polycarboxylic acid anhydride. Polyester resins may be used as molding powder, as coating agents and to produce polyurethane foams.
Inventors
- 👤 David H. Blount
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 20:16
CPC Classifications
C; C08; C08H; C08H8/00; C08B; C08B1/00; C08B1/08; C08B15/00; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/64; C08G18/6484; C08G63/00; C08G63/02; C08G63/12
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
131 words
The process for the production of polyester resinous products by mixing, heating and reacting the following components: (a) a broken-down alkali metal lignin-cellulose polymer and/or a broken-down cellulose polymer produced by mixing 3 parts by weight of a cellulose-containing plant or plant derivative with 2 to 5 parts by weight of melted alkali metal hydroxide, then heating the mixture at 150° C. to 220° C. while agitating for 5 to 60 minutes; in an amount of 10 to 50 parts by weight; (b) a substituted organic hydroxy compound, which contains at least one substituent which will split off in the reaction, in an amount of 10 to 50 parts by weight; (c) polycarboxylic acid or polycarboxylic acid anhydride, or mixtures thereof, in an amount of 10 to 50 parts by weight.
Claim 2
Dependent Claim
131 words
The process for the production of polyester resinous products by mixing, heating and reacting the following components: (a) a broken-down alkali metal lignin-cellulose polymer and/or a broken-down cellulose polymer produced by mixing 3 parts by weight of a cellulose-containing plant or plant derivative with 2 to 5 parts by weight of melted alkali metal hydroxide, then heating the mixture at 150° C. to 220° C. while agitating for 5 to 60 minutes; in an amount of 10 to 50 parts by weight; (b) a substituted organic hydroxy compound, which contains at least one substituent which will split off in the reaction, in an amount of 10 to 50 parts by weight; (c) polycarboxylic acid or polycarboxylic acid anhydride, or mixtures thereof, in an amount of 10 to 50 parts by weight.
Claim 3
Dependent Claim
30 words
The process of claim 1 wherein the substituted organic hydroxy compound is a halohydrin compound selected from the group consisting of ethylene chlorohydrin, ethylene bromohydrin, glycerine, α,γdichlorohydrin and mixtures thereof.
Claim 4
Dependent Claim
51 words
The process of claim 1 wherein the polycarboxylic acid is selected from the group consisting of maleic acid, phthalic acid, succinic acid, oxalic acid, malonic acid, glutaric acid, adipic acid, pimelic acid, azelaic acid, suberic acid, isophthalic acid, fumaric acid, sebacic acid, terephthalic acid, itaconic acid, diglycolic acid and mixtures thereof.
Claim 5
Dependent Claim
52 words
The process of claim 1 wherein the polycarboxylic acid anhydride is selected from the group consisting of phthalic acid anhydride, maleic acid anhydride, succinic acid anhydride, glutaric acid anhydride, poly(adipic anhydride), tetrachlorophthalic acid anhydride, pyromellitic and anhydride, tetrohydrophthalic acid anhydride, dodecenylsuccinic acid anhydride, hexadecylsuccinic acid anhydride, nitrophthalic acid anhydride and mixtures thereof.
Claim 6
Dependent Claim
61 words
The process of claim 1 wherein up to 50% by weight of the polycarboxylic acid or polycarboxylic acid anhydride is replaced with a vegetable oil, selected from the group consisting of soybean oil, linseed oil, cottonseed oil, tung oil, fish oil, perilla oil, oiticica oil, sunflower oil, safflower oil, walnut oil, dehydrated castor oil, monoglyceride of vegetable oils and mixtures thereof.
Claim 7
Dependent Claim
9 words
The product produced by the process of claim 1.
Claim 8
Dependent Claim
9 words
The product produced by the process of claim 5.
Claim 9
Dependent Claim
27 words
The process of claim 1 wherein up to 25 parts by weight of a polyhydroxy organic compound are mixed and reacted with Components (a), (b) and (c).
Claim 10
Dependent Claim
48 words
The process of claim 8 wherein the polyhydroxy organic compound is selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, trimethylene glycol, tetramethylene glycol, pentamethylene glycol, hexamethylene glycol, polyethylene glycol, polypropylene glycol, Bisphenol A, resorcinol, glycerol, glycerol monochlorohydrin, trimethylol ethane and mixtures thereof.
Claim 11
Dependent Claim
71 words
The process according to claim 1, wherein an additional step is taken wherein a catalytic amount of a peroxide initiator; selected from the group consisting of acetyl benzoyl peroxide, peracetic acid, methyl ethyl ketone peroxide, cyclohexanone peroxide, cyclohexyl hypoperoxide, 2,4-dichlorobenzoyl peroxide, cumene hypoperoxide, tert-butyl hydroperoxide, methyl amyl ketone peroxide, lauroyl peroxide, benzoyl peroxide, tert-butyl perbenzoate, di-tert-butyl diperphthalate, p-chlorobenzoyl peroxide; dibenzol diperoxide and mixtures thereof, is admixed with the polyester resinous product.
Claim 12
Dependent Claim
81 words
The process of claim 1 wherein an additional step is taken wherein a vinyl monomer, selected from the group consisting of vinyl acetate, styrene, methacrylic acid, methyl methacrylate, vinyl toluene, acrylic acid, acrylonitrile, divinyl benzene and mixtures thereof, in an amount of up to 50% by weight, percentage based on polyester resinous product, is admixed with the polyester resinous product of claim 1, then a catalytic amount of a peroxide initiator and activator is added and is thoroughly mixed and reacted.
Claim 13
Dependent Claim
9 words
The product produced by the process of claim 11.
Claim 14
Dependent Claim
48 words
The process of claim 11 wherein the peroxide initiator is methyl ethyl ketone peroxide in the amount of 0.2% to 0.5% by weight, percentage based on weight of polyester resinous product, and the activator is cobalt naphthanate in the amount of 30 to 100 ppm of cobalt metal.
Claim 15
Dependent Claim
33 words
The process of claim 1 wherein an organic compound selected from the group consisting of formaldehyde, substituted organic compound polyol, vegetable oils, and mixtures thereof, is added with Components (a), (b) and (c).
Claim 16
Dependent Claim
9 words
The product produced by the process of claim 14.
Claim 17
Dependent Claim
91 words
The process of claim 14 wherein the substituted organic compound having a substituent which will split off during the reaction to said broken-down alkali metal lignin-cellulose and/or a broken-down cellulose polymer in the amount wherein the mols of the substituted radicals are about equal to the mols of the alkali radicals in the mixture, the substituent containing at least one substituent selected from the group consisting of acid sulfate, nitrate, sulfate, acid phosphate, bicarbonate, formate, acetate, propionate, laurate, oleate, stearate, oxalate, acid malonate, acid tartrate, acid citrate, halogens and mixtures thereof.
Claim 18
Dependent Claim
27 words
The process of claim 1 wherein up to 25 parts by weight of water is added to the broken-down alkali metal lignin-cellulose or broken-down alkali metal cellulose.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-07-12 | 1986-01-11 | 1986-07-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-07-12 | 1990-01-11 | 1990-07-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-07-12 | 1994-01-11 | 1994-07-13 | $7700.00 | Window Closed / Lapsed |