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US4337155A Expired / Lapsed US ⏱️ 0.0 years remaining

Chemical-resistant wholly aromatic polyamide fiber material

Assignee: Teijin Ltd
•
Filing: 1981-01-14
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Granted: 1982-06-29
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Expires: 2001-01-14
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Abstract

Abstract A wholly aromatic polyamide fiber material having an excellent resistance to chemicals, comprises wholly aromatic polyamide fibers each covered with a coating of a fluorine-containing polymeric resin which coating has been derived from an aqueous emulsion of the fluorine-containing polymer resin.

Inventors

  • 👤 Hideharu Sasaki
  • 👤 Yorikazu Tamura
  • 👤 Keizo Shimada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 03:18
CPC Classifications
B; B01; B01D; B01D39/00; B01D39/08; B01D39/083; B01D39/02; B01D39/04; B01D39/14; B01D39/16; B01D39/1607; B01D39/1623; C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/32; D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/244; D06M15/256; D06N; D06N3/00; D06N3/04; D06N3/047; B01D2239/00; B01D2239/04; B01D2239/0464; B01D2239/0471; B01D2239/0492; B01D2239/12; B01D2239/1233; B01D2239/1241; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2904; Y10T428/2907; Y10T428/2913; Y10T428/2933; Y10T428/2964; Y10T428/2967; Y10T428/2969; Y10T442/00; Y10T442/10; Y10T442/102; Y10T442/103; Y10T442/30; Y10T442/3049; Y10T442/3976; Y10T442/40; Y10T442/419; Y10T442/60; Y10T442/603; Y10T442/607

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 201 words
A chemical-resistant wholly aromatic polyamide fiber material, comprising wholly aromatic polyamide fibers each comprising at least one aromatic polyamide containing repeating units selected from the group consisting of those of the formulae (I) and (II): ##STR6## wherein Ar 1 , Ar 2 , and Ar 3 respectively present, independently from each other, an unsubstituted or substituted divalent aromatic radical which comprises a single aromatic ring, or two or more aromatic rings that are condensed together, or are linked together, by a single bond, or by a bridging atom or radical, and which is oriented either meta or para, and R 1 , R 2 and R 3 each represent independently from each other, a hydrogen atom or an alkyl radical having 1 to 3 carbon atoms, each of which fibers is covered with a coating of a fluorine-containing polymeric resin comprising at least one member selected from the group consisting of tetrafluoroethylene polymers, tetrafluoroethylene-hexafluoropropylene copolymers, tetrafluoroethylene-trifluorochloroethylene copolymers, tetrafluoroethylene-vinylidene fluoride copolymers, tetrafluoroethyleneperfluorovinyl ether copolymers, tetrafluoroethylene-carboxylic acid or sulfonic acid group-containing perfluorovinyl ether copolymers, trifluorochloroethylene polymers, vinyl fluoride polymers, vinylidene fluoride polymers, vinyl fluoride-hexafluoropropylene copolymers, and vinyl chloride-trifluorochloroethylene copolymers, said coating having been derived from an aqueous emulsion of said fluorine-containing polymeric resin.
Claim 2
Dependent Claim 201 words
A chemical-resistant wholly aromatic polyamide fiber material, comprising wholly aromatic polyamide fibers each comprising at least one aromatic polyamide containing repeating units selected from the group consisting of those of the formulae (I) and (II): ##STR6## wherein Ar 1 , Ar 2 , and Ar 3 respectively present, independently from each other, an unsubstituted or substituted divalent aromatic radical which comprises a single aromatic ring, or two or more aromatic rings that are condensed together, or are linked together, by a single bond, or by a bridging atom or radical, and which is oriented either meta or para, and R 1 , R 2 and R 3 each represent independently from each other, a hydrogen atom or an alkyl radical having 1 to 3 carbon atoms, each of which fibers is covered with a coating of a fluorine-containing polymeric resin comprising at least one member selected from the group consisting of tetrafluoroethylene polymers, tetrafluoroethylene-hexafluoropropylene copolymers, tetrafluoroethylene-trifluorochloroethylene copolymers, tetrafluoroethylene-vinylidene fluoride copolymers, tetrafluoroethyleneperfluorovinyl ether copolymers, tetrafluoroethylene-carboxylic acid or sulfonic acid group-containing perfluorovinyl ether copolymers, trifluorochloroethylene polymers, vinyl fluoride polymers, vinylidene fluoride polymers, vinyl fluoride-hexafluoropropylene copolymers, and vinyl chloride-trifluorochloroethylene copolymers, said coating having been derived from an aqueous emulsion of said fluorine-containing polymeric resin.
Claim 3
Dependent Claim 129 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said Ar 1 , Ar 2 and Ar 3 in said formulae (I) and (II) are respectively selected, independently from each other, from the group consisting of the radicals of the formulae: ##STR7## wherein R represents a member selected from the group consisting of lower alkyl radicals having 1 to 6 carbon atoms, lower alkoxy radicals having 1 to 6 carbon atoms, halogen atoms and a nitro radical, n represents zero or an integer of from 1 to 4 and X' represents a member selected from the group consisting of ##STR8## wherein Y 1 represents a member selected from the group consisting of a hydrogen atom and lower alkyl radicals having 1 to 6 carbon atoms.
Claim 4
Dependent Claim 77 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said Ar 1 , Ar 2 and Ar 3 in the formulae (I) and (II) respectively represent, independently from each other, a member selected from p-phenylene radical, m-phenylene radical, biphenylene radical and radicals of the formulae: ##STR9## wherein X 2 represents a member selected from ##STR10## in which Y 2 represents a hydrogen atom or a alkyl radical having 1 to 3 carbon atoms.
Claim 5
Dependent Claim 41 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said aromatic polyamide contains repeating units of the formula (II) in which said Ar 2 and Ar 3 represent, independently from each other, a m-phenylene or p-phenylene radical.
Claim 6
Dependent Claim 27 words
A chemical-resistant wholly aromatic polyamide fiber as claimed in claim 4, wherein both said Ar 2 and Ar 3 in the formula (II) represent a m-phenylene radical.
Claim 7
Dependent Claim 27 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said fiber material is in the form of a mass of loose staple fibers.
Claim 8
Dependent Claim 25 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said fluorine-containing polymeric resin contains at least 30% by weight of fluorine.
Claim 9
Dependent Claim 30 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said aqueous emulsion of said fluorine-containing polymeric resin is one prepared by an aqueous emulsion polymerization method.
Claim 10
Dependent Claim 39 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein the amount of said resinous coating is in the range of from 0.5 to 40% based on the entire weight of said wholly aromatic polyamide fibers.
Claim 11
Dependent Claim 23 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said fiber material is in the form of loose filaments.
Claim 12
Dependent Claim 24 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said fiber material is in the form of a woven fabric.
Claim 13
Dependent Claim 24 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said fiber material is in the form of a knitted fabric.
Claim 14
Dependent Claim 24 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said fiber material is in the form of a non-woven fabric.
Claim 15
Dependent Claim 23 words
A chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1, wherein said fiber material is in the form of a net.
Claim 16
Dependent Claim 17 words
A filtering material made of a chemical-resistant wholly aromatic polyamide fiber material as claimed in claim 1.

References Cited (Backward Citations)

US3097990A Cited
US4075172A Cited
US4029585A Cited
US4165404A Cited
US4217227A Cited
US4234839A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-28 1985-12-28 1986-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-28 1989-12-28 1990-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-28 1993-12-28 1994-06-29 $7700.00 Window Closed / Lapsed

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