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US4336348A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic compositions, process for their preparation and their use

Assignee: Bayer AG
•
Filing: 1980-01-25
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Granted: 1982-06-22
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Expires: 2000-01-25
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Abstract

Abstract This disclosure is concerned with an improved process for preparing polymer blends by synthesizing a polyester by the phase boundary condensation synthesis wherein a preformed polymer is dissolved in the organic solvent phase of the synthesis system. This polymer is inert to the diphenol acid chloride and alkali used to form the polyester and differs from this polyester by at least molecular weight and may differ from it in chemical identity. This disclosure is also concerned with the polymer blends so obtained which display superior properties to those obtained by physically blending two already formed polymers.

Inventors

  • 👤 Dieter Margotte

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 11:46
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L67/03; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/19; C08G64/00; C08G64/04; C08G64/06; C08G64/14; C08G64/20; C08G64/22; C08G64/24; C08G64/26; C08G64/28; C08L69/00; C08L69/005

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 66 words
A process for the production of a polyester based on a diphenol and a bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of a polymeric compound which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process.
Claim 2
Dependent Claim 66 words
A process for the production of a polyester based on a diphenol and a bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of a polymeric compound which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process.
Claim 3
Dependent Claim 24 words
The process according to claim 1 wherein an agent selected from the group consisting of chain stoppers, branching agents and mixtures thereof are used.
Claim 4
Dependent Claim 43 words
A process according to claim 1 or 2 in which the polymeric compound which is dissolved in the organic phase and is inert under the reaction conditions is selected from the group consisting of vinyl polymers, polyaryl ether sulphones, poly-(2,6-dialkyl-1,4-phenyl oxides) and polycarbonates.
Claim 5
Dependent Claim 16 words
The process according to claim 1 or 2 in which the polyester produced is a polycarbonate.
Claim 6
Dependent Claim 31 words
The process according to claim 1 or 2 wherein said polymeric compound is selected from the group consisting of polystyrenes, styrene acrylonitrile copolymers, rubber modified styrene acrylonitrile copolymers and polymethyl methacrylates.
Claim 7
Dependent Claim 13 words
A polyester mixture produced according to the process of claim 1 or 2.
Claim 8
Dependent Claim 11 words
A polyester mixture produced according to the process of claim 4.
Claim 9
Dependent Claim 81 words
A process for the production of a polyester based on a diphenol and a bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of between 10 and 40 percent of a polymeric compound which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process, said percentages relative to the weight of said polyester.
Claim 10
Dependent Claim 81 words
A process for the production of a polyester based on a diphenol and a bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of between 10 and 40 percent of a polymeric compound which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process, said percentages relative to the weight of said polyester.
Claim 11
Dependent Claim 118 words
A process for the production of a polyester based on a diphenol and bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of a polymeric compound selected from the group consisting of vinyl polymers having a weight average molecular weight of 150,000-350,000, polysulphones having a weight average molecular weight of 1,000 to 200,000, polyaryl ether-sulphones, poly-(2,6-dialkyl-1,4-phenyl oxides) having a weight average molecular weight of 2,000 to 100,000 and polycarbonates having a weight average molecular weight of 1,000 to 200,000 which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process.
Claim 12
Dependent Claim 118 words
A process for the production of a polyester based on a diphenol and bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of a polymeric compound selected from the group consisting of vinyl polymers having a weight average molecular weight of 150,000-350,000, polysulphones having a weight average molecular weight of 1,000 to 200,000, polyaryl ether-sulphones, poly-(2,6-dialkyl-1,4-phenyl oxides) having a weight average molecular weight of 2,000 to 100,000 and polycarbonates having a weight average molecular weight of 1,000 to 200,000 which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process.
Claim 13
Dependent Claim 12 words
The process according to claim 3 wherein said vinyl polymers are polybutadienes.
Claim 14
Dependent Claim 74 words
A process for the production of a polyester based on a diphenol and a bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of polybutadiene having a weight average molecular weight of 1,000 to 200,000 which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process.
Claim 15
Dependent Claim 74 words
A process for the production of a polyester based on a diphenol and a bis-acid halide by the phase boundary process, comprising an aqueous alkaline phase and an inert organic phase, in which the phase boundary process is carried out in the presence of polybutadiene having a weight average molecular weight of 1,000 to 200,000 which is dissolved only in the organic phase and is inert under the conditions of the phase boundary process.
Claim 16
Dependent Claim 10 words
A polyester mixture produced according to claim 9 or 11.

References Cited (Backward Citations)

US3000849A Cited
DE1420232A1 Cited
US3143525A Cited
DE1745695A1 Cited
GB1245852A Cited
DE1794053A1 Cited
EP0002218A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-21 1985-12-21 1986-06-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-21 1989-12-21 1990-06-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-21 1993-12-21 1994-06-22 $7700.00 Window Closed / Lapsed

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