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US4335225A Expired / Lapsed US ⏱️ 0.0 years remaining

Elastomeric polypropylene

Assignee: EIDP Inc
•
Filing: 1981-03-03
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Granted: 1982-06-15
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Expires: 2001-03-03
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Abstract

Abstract A fractionable elastic polypropylene which has an inherent viscosity of 1.5-9, exhibits no yield point, has a tensile set not exceeding 150% and contains about 10 to 80% by weight of a diethyl ether-soluble fraction having an inherent viscosity exceeding 1.50. This polypropylene is a direct reaction product and thus need not be separated into its component parts to be a useful elastomer. Also described is the diethyl ether-soluble polypropylene fraction of the direct reaction product which has about 0.5% to about 5% isotactic crystallinity and exhibits birefringence when a film formed from said fraction is viewed under crossed Nicol prisms in a polarizing microscope at about 25° C. or is stretched between crossed polarizing sheets at about 25° C. The diethyl ether-soluble fraction itself is a useful elastomeric material.

Inventors

  • 👤 John W. Collette
  • 👤 Charles W. Tullock

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 04:28
CPC Classifications
C; C08; C08F; C08F110/00; C08F110/04; C08F110/06; C08F10/00; C08F10/04; C08F10/06; Y; Y10; Y10S; Y10S526/00; Y10S526/905

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 99 words
As a new product, a fractionable elastic polymer consisting essentially of units derived from propylene which has an inherent viscosity of 1.5-9, a major melting point between about 135°-155° C., exhibits no yield point, has a tensile set not exceeding 150% and contains 10-80% by weight of a diethyl ether-soluble fraction which has an inherent viscosity exceeding 1.50, said diethyl ether-soluble fraction having an isotactic crystalline content of about 0.5% to about 5% by weight and exhibiting birefringence when a film formed from said fraction is viewed under crossed Nicol prisms in a polarizing microscope at about 25° C.
Claim 2
Dependent Claim 99 words
As a new product, a fractionable elastic polymer consisting essentially of units derived from propylene which has an inherent viscosity of 1.5-9, a major melting point between about 135°-155° C., exhibits no yield point, has a tensile set not exceeding 150% and contains 10-80% by weight of a diethyl ether-soluble fraction which has an inherent viscosity exceeding 1.50, said diethyl ether-soluble fraction having an isotactic crystalline content of about 0.5% to about 5% by weight and exhibiting birefringence when a film formed from said fraction is viewed under crossed Nicol prisms in a polarizing microscope at about 25° C.
Claim 3
Dependent Claim 128 words
As a new product, a fractionable elastic polymer consisting essentially of units derived from propylene which has an inherent viscosity of 1.5-9, a major melting point between about 135°-155° C., exhibits no yield point, has a tensile set not exceeding 150% and contains from about 10-35% by weight of a fraction soluble in boiling hexane but insoluble in boiling diethyl ether, from about 10-55% of a fraction insoluble in boiling hexane and 40-75% by weight of a diethyl ether-soluble fraction which has an inherent viscosity exceeding 1.50, said diethyl ether-soluble fraction having an isotactic crystalline content of about 0.5% to about 5% by weight and exhibiting birefringence when a film formed from said fraction is viewed under crossed Nicol prisms in a polarizing microscope at about 25° C.
Claim 4
Dependent Claim 128 words
As a new product, a fractionable elastic polymer consisting essentially of units derived from propylene which has an inherent viscosity of 1.5-9, a major melting point between about 135°-155° C., exhibits no yield point, has a tensile set not exceeding 150% and contains from about 10-35% by weight of a fraction soluble in boiling hexane but insoluble in boiling diethyl ether, from about 10-55% of a fraction insoluble in boiling hexane and 40-75% by weight of a diethyl ether-soluble fraction which has an inherent viscosity exceeding 1.50, said diethyl ether-soluble fraction having an isotactic crystalline content of about 0.5% to about 5% by weight and exhibiting birefringence when a film formed from said fraction is viewed under crossed Nicol prisms in a polarizing microscope at about 25° C.
Claim 5
Dependent Claim 16 words
A polymer of claim 1 or claim 2 which has a tensile set not exceeding 100%.
Claim 6
Dependent Claim 15 words
A polymer of claim 1 or claim 2 which has an inherent viscosity of 2-8.
Claim 7
Dependent Claim 15 words
A polymer of claim 1 which contains about 40-75% by weight of said ether-soluble fraction.
Claim 8
Dependent Claim 36 words
A polypropylene of claim 1 which has an inherent viscosity of 3-8, a tensile set not exceeding 100% and contains about 40-75% by eight of a diethyl ether-soluble fraction having a inherent viscosity greater than 2.5.
Claim 9
Dependent Claim 29 words
A polymer consisting essentially of a blend of about 5-95 parts by weight of the polymer of claim 1 and about 95-5 parts by weight of highly isotactic polypropylene.
Claim 10
Dependent Claim 29 words
A polymer consisting essentially of a blend of about 60-95 parts by weight of the polymer of claim 1 and about 5-40 parts by weight of highly isotactic polypropylene.
Claim 11
Dependent Claim 11 words
A polymer of claim 1 in the form of a film.
Claim 12
Dependent Claim 11 words
A polymer film of claim 9 wherein the film is oriented.
Claim 13
Dependent Claim 11 words
A polymer of claim 8 in the form of a film.
Claim 14
Dependent Claim 11 words
A polymer film of claim 11 wherein the film is oriented.
Claim 15
Dependent Claim 12 words
A polymer of claim 1 in the form of an extruded tubing.
Claim 16
Dependent Claim 12 words
A polymer of claim 8 in the form of an extruded tubing.
Claim 17
Dependent Claim 19 words
A polymer of claim 1 which contains up to 10 mole % of polymerized α-monoolefin units other than propylene.

References Cited (Backward Citations)

US3112301A Cited
FR1138290A Cited
US3175999A Cited
GB856736A Cited
US3257370A Cited
US3329741A Cited
US3511824A Cited
US3784502A Cited
US3932307A Cited
US3950269A Cited
DE2653379A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-14 1985-12-14 1986-06-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-14 1989-12-14 1990-06-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-14 1993-12-14 1994-06-15 $7700.00 Window Closed / Lapsed

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