US4334932A
Expired / Lapsed
US
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Pigment formulations, processes for their preparation and their use for pigmenting aqueous, alcoholic or aqueous-alcoholic printing ink systems and colored lacquer systems
Assignee: BASF Corp
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Filing: 1981-04-06
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Granted: 1982-06-15
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Expires: 2001-04-06
Abstract
Abstract Pigment formulations which contain (1) 10-90% by weight, based on the whole formulation, of a pigment mixture of (a) 99.5-90 mol %, based on the pigment mixture, of at least one monoazo pigment of the general formula A--N=N--B and (b) 0.5-10 mol %, based on the pigment mixture, of at least one monoazo pigment of the formula (A'-N=N-B'--(X).sub.m characterized by the presence of at least one --COOH, --SO 3 H, metal carboxylate or metal sulfonate group per pigment molecule, and (2) 90-10% by weight, based on the whole preparation, of a polyacrylate resin containing carboxylic acid groups. The novel pigment formulations are outstandingly suitable for pigmenting aqueous, alcoholic and aqueous-alcoholic printing ink systems and colored lacquer systems and are distinguished in particularlby good shelf life. The substituents A, B, A', B', X and m are as defined in claim 1.
Inventors
- 👤 Armand Roueche
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 10:08
CPC Classifications
C; C09; C09B; C09B67/00; C09B67/0033; C09B67/0046; C09B67/0051; C09B63/00; C09B67/006; C09D; C09D11/00; C09D11/02; C09D11/03; C09D11/037
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
153 words
A pigment formulation which contains (1) 10-90% by weight, based on the whole formulation, of a pigment mixture of (a) 99.5-90 mol %, based on the pigment mixture, of at least one monoazo pigment of the general formula I A--N=N--B (I) (b) 0.5-10 mol %, based on the pigment mixture, of at least one monoazo pigment of the general formula II (A'--N=N--B'--X).sub.m (II) in which A and A' are radicals of a diazo component of the benzene or naphthalene series, B and B' are radicals of a coupling component of the acetoacetic acid arylamide, naphthol or naphthoic acid arylamide series, X is --COOH, --SO 3 H or a group of the formula III ##EQU4## in which Me is a metal, and m and n independently of one another are the numbers 1, 2 or 3, and (2) 90-10% by weight, based on the whole formulation, of a polyacrylate resin containing carboxylic acid groups.
Claim 2
Dependent Claim
153 words
A pigment formulation which contains (1) 10-90% by weight, based on the whole formulation, of a pigment mixture of (a) 99.5-90 mol %, based on the pigment mixture, of at least one monoazo pigment of the general formula I A--N=N--B (I) (b) 0.5-10 mol %, based on the pigment mixture, of at least one monoazo pigment of the general formula II (A'--N=N--B'--X).sub.m (II) in which A and A' are radicals of a diazo component of the benzene or naphthalene series, B and B' are radicals of a coupling component of the acetoacetic acid arylamide, naphthol or naphthoic acid arylamide series, X is --COOH, --SO 3 H or a group of the formula III ##EQU4## in which Me is a metal, and m and n independently of one another are the numbers 1, 2 or 3, and (2) 90-10% by weight, based on the whole formulation, of a polyacrylate resin containing carboxylic acid groups.
Claim 3
Dependent Claim
182 words
A pigment formulation according to claim 1, wherein, in the formulae I and II respectively, A is a radical of the formulae ##STR16## B is a radical of the formulae ##STR17## A'--X) m is a radical of the formulae ##STR18## and B'--X) m is a radical of the formulae ##STR19## in which R and R 1 independently of one another are hydrogen, halogen, C 1 -C 2 alkyl, C 1 -C 2 alkoxy, C 2 -C 4 alkylcarbamoyl, C 2 -C 4 alkoxycarbonyl, trifluoromethyl or nitro, R 3 , R 4 and R 5 independently of one another are hydrogen, halogen, C 1 -C 2 alkyl, C 1 -C 2 alkoxy, C 2 -C 4 alkylcarbamoyl or nitro, R 6 and R 7 independently of one another are hydrogen, halogen, methyl, methoxy, trifluoromethyl or nitro, R 8 and R 9 independently of one another are hydrogen or halogen, X is as defined in claim 1, and p and q independently of one another are the numbers zero, 1, 2 or 3, with the proviso that the sum p+q is at least 1.
Claim 4
Dependent Claim
169 words
A pigment formulation according to claim 1, which contains at least one monoazo pigment of the formulae V or VI ##STR20## and at least one monoazo pigment of the formulae VII, VIII or IX ##STR21## in which R' and R 1 independently of one another are hydrogen, chlorine, methyl, methoxy, ethoxy or nitro, R" and R 1" independently of one another are hydrogen, chlorine, methyl, methoxy or nitro, R 3' and R 5' independently of one another are hydrogen, chlorine, methyl, methoxy or ethoxy, R 4' is hydrogen, chlorine, methyl, methoxy, ethoxy or methylcarbamoyl, R 6' is hydrogen, chlorine, methyl, methoxy or nitro, R 7' is hydrogen or chlorine, R 8' is hydrogen or bromine, X' is --COOH, --SO 3 H or one of the two groups of the formulae IIIa or IVa ##EQU5## in which Me can be Ca, Mg or Sr, and p' and q' independently of one another are the numbers zero or 1, with the proviso that the sum p'+q' must be at least one.
Claim 5
Dependent Claim
26 words
A pigment formulation according to claim 3, in which X' is a group of the formulae IIIa or IVa and Me is Ca, Mg or Sr.
Claim 6
Dependent Claim
25 words
A pigment formulation according to claim 1, which consists of 30-70% by weight of pigment mixture (1) and 70-30% by weight of polyacrylate resin (2).
Claim 7
Dependent Claim
28 words
A pigment formulation according to claim 1, which contains 1-3 mol %, based on the pigment mixture, of at least one monoazo pigment of the general formula II.
Claim 8
Dependent Claim
107 words
A pigment formulation according to claim 1, which contains a pigment mixture of (a) a monoazo pigment of the formula ##STR22## a monoazo pigment of the formula ##STR23## (b) a monoazo pigment of the formula ##STR24## a monoazo pigment of the formula ##STR25## or especially a pigment mixture of (c) a monoazo pigment of the formula ##STR26## a monoazo pigment of the formula ##STR27## (d) a monoazo pigment of the formula ##STR28## a monoazo pigment of the formula ##STR29## in which A" is ##STR30## and the proportion of monoazo pigment containing --SO 3 (Ca/2) groups is in each case 1.5-3 mol %, based on the pigment mixture.
Claim 9
Dependent Claim
159 words
A process for the preparation of a pigment formulation according to claim 1, which comprises coupling a coupling component or a mixture of coupling components of the naphthol, naphthoic acid arylamide or acetoacetic acid arylamide series, in an aqueous medium, with a diazonium compound of an amine of the benzene or naphthalene series or with a mixture of these diazonium compounds, in a molar ratio of about 1:1, it being necessary for the proportion of the coupling components and/or diazo components containing free carboxylic acid groups or sulfonic acid groups to be 0.5-10 mol %, an alkaline polyacrylate resin solution additionally being admixed before, during or after the coupling, and then, if appropriate, reacting the mixture with a water-soluble salt of a metal of valency n, n being as defined in claim 1, in order to form the metal carboxylates or metal sulfonates, precipitating the resin as the free acid by acidification and working up the pigment formulation obtained.
Claim 10
Dependent Claim
54 words
A process for the preparation of printing inks or colored lacquers, which comprises incorporating a pigment formulation according to claim 1, in water, aqueous alcohol or alcohol, into the desired polymer, with the addition of ammonia or an amine, the carrier resin being dissolved and the pigment being finely dispersed in the application medium.
References Cited (Backward Citations)
US3725101A
Cited
US3759731A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-06-14 | 1985-12-14 | 1986-06-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-06-14 | 1989-12-14 | 1990-06-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-06-14 | 1993-12-14 | 1994-06-15 | $7700.00 | Window Closed / Lapsed |