US4332708A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polycarboxylic acid/ester-diamine aqueous coating composition
Assignee: Von Roll Isola USA Inc
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Filing: 1980-02-27
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Granted: 1982-06-01
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Expires: 2000-02-27
Abstract
Abstract Wire coating formulations are provided by heating a mixture of aromatic dianhydride, water and a monoalkyl glycol ether, followed by the addition of organic diamine. The resulting mixture is a stable wire coating enamel capable of forming flexible wire enamels upon cure.
Inventors
- 👤 Edith M. Boldebuck
- 👤 Eugene G. Banucci
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 16:31
CPC Classifications
C; C09; C09D; C09D179/00; C09D179/04; C09D179/08; H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/303; H01B3/305; H01B3/308
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
204 words
Aqueous coating solution comprising by weight (A) from about 40% to 75% of solids and (B) from about 25% to 60% of solvent, where (A) is a polycarboxylic acid/ester-organic diamine mixture wherein the organic diamine has the formula, NH.sub.2 R.sup.1 NH.sub.2, is present in about equal molar amounts and up to about a 25 mole percent excess over the moles of organic polycarboxylic acid/ester which mixture is a member selected from (i) a mixture of 40 to 80 mole percent of tetra-acid of the formula, ##STR9## and 20 to 60 mole percent of a half-ester of the formula, ##STR10## or (ii) a mixture consisting essentially of (i) and from 0 to 10 mole percent, based on total moles of said tetra-acid and said half-ester, of organic dianhydride of the formula, ##STR11## where (B) is a solvent mixture comprising by weight 1 to 20% by weight of water and 80 to 99% by weight of monoalkyl glycol ether having 1 to 4 carbon atoms in the alkyl group, where R is a C.sub.(6-30) aromatic organic radical, R 1 is a C.sub.(6-30) organic radical, R 2 is an alkyl terminated alkylene ether or dialkylene ether radical and R 3 is selected from R 2 or hydrogen.
Claim 2
Dependent Claim
204 words
Aqueous coating solution comprising by weight (A) from about 40% to 75% of solids and (B) from about 25% to 60% of solvent, where (A) is a polycarboxylic acid/ester-organic diamine mixture wherein the organic diamine has the formula, NH.sub.2 R.sup.1 NH.sub.2, is present in about equal molar amounts and up to about a 25 mole percent excess over the moles of organic polycarboxylic acid/ester which mixture is a member selected from (i) a mixture of 40 to 80 mole percent of tetra-acid of the formula, ##STR9## and 20 to 60 mole percent of a half-ester of the formula, ##STR10## or (ii) a mixture consisting essentially of (i) and from 0 to 10 mole percent, based on total moles of said tetra-acid and said half-ester, of organic dianhydride of the formula, ##STR11## where (B) is a solvent mixture comprising by weight 1 to 20% by weight of water and 80 to 99% by weight of monoalkyl glycol ether having 1 to 4 carbon atoms in the alkyl group, where R is a C.sub.(6-30) aromatic organic radical, R 1 is a C.sub.(6-30) organic radical, R 2 is an alkyl terminated alkylene ether or dialkylene ether radical and R 3 is selected from R 2 or hydrogen.
Claim 3
Dependent Claim
15 words
A coating composition in accordance with claim 1, wherein the organic dianhydride is 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride.
Claim 4
Dependent Claim
15 words
A coating composition in accordance with claim 1, wherein the organic diamine is methylene dianiline.
Claim 5
Dependent Claim
14 words
A coating composition in accordance with claim 1, wherein the organic diamine is oxydianiline.
Claim 6
Dependent Claim
14 words
A coating composition in accordance with claim 1, wherein the organic diamine is metaphenylenediamine.
Claim 7
Dependent Claim
20 words
A coating composition in accordance with claim 1, wherein the monoalkyl glycol ether is the methyl ether of diethylene glycol.
Claim 8
Dependent Claim
17 words
A coating composition in accordance with claim 1, wherein glycol is a mixture of monoalkyl glycol ethers.
References Cited (Backward Citations)
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US3518219A
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US3575891A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-05-31 | 1985-11-30 | 1986-06-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-05-31 | 1989-11-30 | 1990-06-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-05-31 | 1993-11-30 | 1994-06-01 | $7700.00 | Window Closed / Lapsed |