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US4332708A Expired / Lapsed US ⏱️ 0.0 years remaining

Polycarboxylic acid/ester-diamine aqueous coating composition

Assignee: Von Roll Isola USA Inc
•
Filing: 1980-02-27
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Granted: 1982-06-01
•
Expires: 2000-02-27
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Abstract

Abstract Wire coating formulations are provided by heating a mixture of aromatic dianhydride, water and a monoalkyl glycol ether, followed by the addition of organic diamine. The resulting mixture is a stable wire coating enamel capable of forming flexible wire enamels upon cure.

Inventors

  • 👤 Edith M. Boldebuck
  • 👤 Eugene G. Banucci

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:31
CPC Classifications
C; C09; C09D; C09D179/00; C09D179/04; C09D179/08; H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/303; H01B3/305; H01B3/308

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 204 words
Aqueous coating solution comprising by weight (A) from about 40% to 75% of solids and (B) from about 25% to 60% of solvent, where (A) is a polycarboxylic acid/ester-organic diamine mixture wherein the organic diamine has the formula, NH.sub.2 R.sup.1 NH.sub.2, is present in about equal molar amounts and up to about a 25 mole percent excess over the moles of organic polycarboxylic acid/ester which mixture is a member selected from (i) a mixture of 40 to 80 mole percent of tetra-acid of the formula, ##STR9## and 20 to 60 mole percent of a half-ester of the formula, ##STR10## or (ii) a mixture consisting essentially of (i) and from 0 to 10 mole percent, based on total moles of said tetra-acid and said half-ester, of organic dianhydride of the formula, ##STR11## where (B) is a solvent mixture comprising by weight 1 to 20% by weight of water and 80 to 99% by weight of monoalkyl glycol ether having 1 to 4 carbon atoms in the alkyl group, where R is a C.sub.(6-30) aromatic organic radical, R 1 is a C.sub.(6-30) organic radical, R 2 is an alkyl terminated alkylene ether or dialkylene ether radical and R 3 is selected from R 2 or hydrogen.
Claim 2
Dependent Claim 204 words
Aqueous coating solution comprising by weight (A) from about 40% to 75% of solids and (B) from about 25% to 60% of solvent, where (A) is a polycarboxylic acid/ester-organic diamine mixture wherein the organic diamine has the formula, NH.sub.2 R.sup.1 NH.sub.2, is present in about equal molar amounts and up to about a 25 mole percent excess over the moles of organic polycarboxylic acid/ester which mixture is a member selected from (i) a mixture of 40 to 80 mole percent of tetra-acid of the formula, ##STR9## and 20 to 60 mole percent of a half-ester of the formula, ##STR10## or (ii) a mixture consisting essentially of (i) and from 0 to 10 mole percent, based on total moles of said tetra-acid and said half-ester, of organic dianhydride of the formula, ##STR11## where (B) is a solvent mixture comprising by weight 1 to 20% by weight of water and 80 to 99% by weight of monoalkyl glycol ether having 1 to 4 carbon atoms in the alkyl group, where R is a C.sub.(6-30) aromatic organic radical, R 1 is a C.sub.(6-30) organic radical, R 2 is an alkyl terminated alkylene ether or dialkylene ether radical and R 3 is selected from R 2 or hydrogen.
Claim 3
Dependent Claim 15 words
A coating composition in accordance with claim 1, wherein the organic dianhydride is 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride.
Claim 4
Dependent Claim 15 words
A coating composition in accordance with claim 1, wherein the organic diamine is methylene dianiline.
Claim 5
Dependent Claim 14 words
A coating composition in accordance with claim 1, wherein the organic diamine is oxydianiline.
Claim 6
Dependent Claim 14 words
A coating composition in accordance with claim 1, wherein the organic diamine is metaphenylenediamine.
Claim 7
Dependent Claim 20 words
A coating composition in accordance with claim 1, wherein the monoalkyl glycol ether is the methyl ether of diethylene glycol.
Claim 8
Dependent Claim 17 words
A coating composition in accordance with claim 1, wherein glycol is a mixture of monoalkyl glycol ethers.

References Cited (Backward Citations)

US3190856A Cited
US3347808A Cited
US3518219A Cited
US3575891A Cited
US4255471A Cited
US4215157A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-05-31 1985-11-30 1986-06-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-05-31 1989-11-30 1990-06-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-05-31 1993-11-30 1994-06-01 $7700.00 Window Closed / Lapsed

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