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US4331799A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolymers of etherimides and amideimides

Assignee: General Electric Co
•
Filing: 1981-03-02
•
Granted: 1982-05-25
•
Expires: 2001-03-02
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Abstract

Abstract Copolymers of etherimides and amideimides have been found to be useful in the coating and molding arts.

Inventors

  • 👤 Fred F. Holub
  • 👤 Gary A. Mellinger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 16:52
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/14; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31623

Claims Analysis

Total Claims: 37
Claim 1
Independent Claim 178 words
A method for making copolymers of etherimide units and amideimide units which comprises simultaneously interacting a mixture of ingredients comprising (I) an organic diamine of the formula: H.sub.2 NR.sup.1 NH.sub.2 (II) An aromatic bis (etheranhydride) of the general formula: ##STR22## and (III) A trimellitic acid halide of the formula: ##STR23## where Z is halogen, R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR24## and (b) divalent organic radicals of the general formula: ##STR25## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR26## where Q is a member selected from the class consisting of ##STR27## and x is a whole number equal to from 1 to 5, inclusive.
Claim 2
Independent Claim 178 words
A method for making copolymers of etherimide units and amideimide units which comprises simultaneously interacting a mixture of ingredients comprising (I) an organic diamine of the formula: H.sub.2 NR.sup.1 NH.sub.2 (II) An aromatic bis (etheranhydride) of the general formula: ##STR22## and (III) A trimellitic acid halide of the formula: ##STR23## where Z is halogen, R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR24## and (b) divalent organic radicals of the general formula: ##STR25## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR26## where Q is a member selected from the class consisting of ##STR27## and x is a whole number equal to from 1 to 5, inclusive.
Claim 3
Dependent Claim 14 words
The process as in claim 1, wherein the trimellitic anhydride is 4-chloroformyl phthalic anhydride.
Claim 4
Dependent Claim 39 words
The process as in claim 1 wherein the trimellitic acid halide and the aromatic bisether dianhydride are employed in a molar ratio of from 0.95 to 1.05 total moles of these two reactants per mole of the organic diamine.
Claim 5
Dependent Claim 13 words
The process as in claim 1 wherein the organic diamine is meta-phenylene diamine.
Claim 6
Dependent Claim 13 words
The process as in claim 1 wherein the diamine is diphenyl sulfone diamine.
Claim 7
Dependent Claim 12 words
The process as in claim 1 wherein the diamine is diaminodiphenyl ether.
Claim 8
Dependent Claim 12 words
The process as in claim 1 wherein the diamine is diaminodiphenyl methane.
Claim 9
Dependent Claim 13 words
The process as in claim 1 wherein the diamino compound is 2,2-bis(4-aminophenyl) propane.
Claim 10
Dependent Claim 21 words
The process as in claim 1 wherein the trimellitic compound is 4-chloroformyl phthalic anhydride and the the dianhydride is 4,4'-bisphenol-A dianhydride.
Claim 11
Dependent Claim 25 words
The process as in claim 1 wherein the amine is m-phenylenediamine, the trimellitic acid halide has the formula ##STR28## and the dianhydride is 4,4'-bisphenol-A dianhydride.
Claim 12
Dependent Claim 14 words
The process as in claim 1 wherein the reactants are interacted at elevated temperatures.
Claim 13
Dependent Claim 11 words
A product obtained in accordance with the process of claim 1.
Claim 14
Dependent Claim 11 words
A product obtained in accordance with the process of claim 2.
Claim 15
Dependent Claim 11 words
A product obtained in accordance with the process of claim 3.
Claim 16
Dependent Claim 11 words
A product obtained in accordance with the process of claim 4.
Claim 17
Dependent Claim 11 words
A product obtained in accordance with the process of claim 5.
Claim 18
Dependent Claim 11 words
A product obtained in accordance with the process of claim 6.
Claim 19
Dependent Claim 11 words
A product obtained in accordance with the process of claim 7.
Claim 20
Dependent Claim 11 words
A product obtained in accordance with the process of claim 8.
Claim 21
Dependent Claim 11 words
A product obtained in accordance with the process of claim 9.
Claim 22
Dependent Claim 11 words
A product obtained in accordance with the process of claim 10.
Claim 23
Dependent Claim 11 words
A product obtained in accordance with the process of claim 11.
Claim 24
Dependent Claim 189 words
A random copolymeric composition selected from the class of general formulas consisting of (a) ##STR29## and (b) ##STR30## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR31## and (b) divalent organic radicals of the general formula: ##STR32## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class containing of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, siloxanes, and (d) divalent radicals included by the formula, ##STR33## where Q is a member selected from the class consisting of ##STR34## and x is a whole number equal to from 1 to 5 inclusive, m and n are whole numbers independently equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric compositions are interacted simultaneously.
Claim 25
Dependent Claim 189 words
A random copolymeric composition selected from the class of general formulas consisting of (a) ##STR29## and (b) ##STR30## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR31## and (b) divalent organic radicals of the general formula: ##STR32## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class containing of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, siloxanes, and (d) divalent radicals included by the formula, ##STR33## where Q is a member selected from the class consisting of ##STR34## and x is a whole number equal to from 1 to 5 inclusive, m and n are whole numbers independently equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric compositions are interacted simultaneously.
Claim 26
Dependent Claim 176 words
A random copolymer comprising (a) from 5 to 95 mol percent of chemically combined units of the formula ##STR35## and (b) from 95 to 5 mol percent of chemically combined units of the formula ##STR36## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR37## and (b) divalent organic radicals of the general formula: ##STR38## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR39## where Q is a member selected from the class consisting of ##STR40## and x is a whole number equal to from 1 to 5, inclusive, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 27
Dependent Claim 176 words
A random copolymer comprising (a) from 5 to 95 mol percent of chemically combined units of the formula ##STR35## and (b) from 95 to 5 mol percent of chemically combined units of the formula ##STR36## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR37## and (b) divalent organic radicals of the general formula: ##STR38## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR39## where Q is a member selected from the class consisting of ##STR40## and x is a whole number equal to from 1 to 5, inclusive, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 28
Dependent Claim 49 words
A random copolymeric composition of matter corresponding to the formula ##STR41## where m and n are whole numbers independently, equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 29
Dependent Claim 49 words
A random copolymeric composition of matter corresponding to the formula ##STR41## where m and n are whole numbers independently, equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 30
Dependent Claim 49 words
A random copolymeric composition of matter corresponding to the formula ##STR42## where m and n are independently whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 31
Dependent Claim 49 words
A random copolymeric composition of matter corresponding to the formula ##STR42## where m and n are independently whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 32
Dependent Claim 49 words
A random copolymeric composition of matter corresponding to the formula ##STR43## where m and n, independently are whole numbers equal to at least 1, and p is a whole number, greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 33
Dependent Claim 49 words
A random copolymeric composition of matter corresponding to the formula ##STR43## where m and n, independently are whole numbers equal to at least 1, and p is a whole number, greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 34
Dependent Claim 46 words
A random copolymeric composition having the formula ##STR44## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 35
Dependent Claim 46 words
A random copolymeric composition having the formula ##STR44## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 36
Dependent Claim 46 words
A random copolymeric composition having the formula ##STR45## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 37
Dependent Claim 46 words
A random copolymeric composition having the formula ##STR45## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.

References Cited (Backward Citations)

CA917844A Cited
US3847867A Cited
US3972902A Cited
US3905942A Cited
US4197396A Cited
US4215157A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-05-24 1985-11-23 1986-05-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-05-24 1989-11-23 1990-05-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-05-24 1993-11-23 1994-05-25 $7700.00 Window Closed / Lapsed

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