US4331799A
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Copolymers of etherimides and amideimides
Assignee: General Electric Co
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Filing: 1981-03-02
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Granted: 1982-05-25
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Expires: 2001-03-02
Abstract
Abstract Copolymers of etherimides and amideimides have been found to be useful in the coating and molding arts.
Inventors
- 👤 Fred F. Holub
- 👤 Gary A. Mellinger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 16:52
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/14; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31623
Claims Analysis
Total Claims: 37
Claim 1
Independent Claim
178 words
A method for making copolymers of etherimide units and amideimide units which comprises simultaneously interacting a mixture of ingredients comprising (I) an organic diamine of the formula: H.sub.2 NR.sup.1 NH.sub.2 (II) An aromatic bis (etheranhydride) of the general formula: ##STR22## and (III) A trimellitic acid halide of the formula: ##STR23## where Z is halogen, R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR24## and (b) divalent organic radicals of the general formula: ##STR25## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR26## where Q is a member selected from the class consisting of ##STR27## and x is a whole number equal to from 1 to 5, inclusive.
Claim 2
Independent Claim
178 words
A method for making copolymers of etherimide units and amideimide units which comprises simultaneously interacting a mixture of ingredients comprising (I) an organic diamine of the formula: H.sub.2 NR.sup.1 NH.sub.2 (II) An aromatic bis (etheranhydride) of the general formula: ##STR22## and (III) A trimellitic acid halide of the formula: ##STR23## where Z is halogen, R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR24## and (b) divalent organic radicals of the general formula: ##STR25## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR26## where Q is a member selected from the class consisting of ##STR27## and x is a whole number equal to from 1 to 5, inclusive.
Claim 3
Dependent Claim
14 words
The process as in claim 1, wherein the trimellitic anhydride is 4-chloroformyl phthalic anhydride.
Claim 4
Dependent Claim
39 words
The process as in claim 1 wherein the trimellitic acid halide and the aromatic bisether dianhydride are employed in a molar ratio of from 0.95 to 1.05 total moles of these two reactants per mole of the organic diamine.
Claim 5
Dependent Claim
13 words
The process as in claim 1 wherein the organic diamine is meta-phenylene diamine.
Claim 6
Dependent Claim
13 words
The process as in claim 1 wherein the diamine is diphenyl sulfone diamine.
Claim 7
Dependent Claim
12 words
The process as in claim 1 wherein the diamine is diaminodiphenyl ether.
Claim 8
Dependent Claim
12 words
The process as in claim 1 wherein the diamine is diaminodiphenyl methane.
Claim 9
Dependent Claim
13 words
The process as in claim 1 wherein the diamino compound is 2,2-bis(4-aminophenyl) propane.
Claim 10
Dependent Claim
21 words
The process as in claim 1 wherein the trimellitic compound is 4-chloroformyl phthalic anhydride and the the dianhydride is 4,4'-bisphenol-A dianhydride.
Claim 11
Dependent Claim
25 words
The process as in claim 1 wherein the amine is m-phenylenediamine, the trimellitic acid halide has the formula ##STR28## and the dianhydride is 4,4'-bisphenol-A dianhydride.
Claim 12
Dependent Claim
14 words
The process as in claim 1 wherein the reactants are interacted at elevated temperatures.
Claim 13
Dependent Claim
11 words
A product obtained in accordance with the process of claim 1.
Claim 14
Dependent Claim
11 words
A product obtained in accordance with the process of claim 2.
Claim 15
Dependent Claim
11 words
A product obtained in accordance with the process of claim 3.
Claim 16
Dependent Claim
11 words
A product obtained in accordance with the process of claim 4.
Claim 17
Dependent Claim
11 words
A product obtained in accordance with the process of claim 5.
Claim 18
Dependent Claim
11 words
A product obtained in accordance with the process of claim 6.
Claim 19
Dependent Claim
11 words
A product obtained in accordance with the process of claim 7.
Claim 20
Dependent Claim
11 words
A product obtained in accordance with the process of claim 8.
Claim 21
Dependent Claim
11 words
A product obtained in accordance with the process of claim 9.
Claim 22
Dependent Claim
11 words
A product obtained in accordance with the process of claim 10.
Claim 23
Dependent Claim
11 words
A product obtained in accordance with the process of claim 11.
Claim 24
Dependent Claim
189 words
A random copolymeric composition selected from the class of general formulas consisting of (a) ##STR29## and (b) ##STR30## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR31## and (b) divalent organic radicals of the general formula: ##STR32## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class containing of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, siloxanes, and (d) divalent radicals included by the formula, ##STR33## where Q is a member selected from the class consisting of ##STR34## and x is a whole number equal to from 1 to 5 inclusive, m and n are whole numbers independently equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric compositions are interacted simultaneously.
Claim 25
Dependent Claim
189 words
A random copolymeric composition selected from the class of general formulas consisting of (a) ##STR29## and (b) ##STR30## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR31## and (b) divalent organic radicals of the general formula: ##STR32## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class containing of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, siloxanes, and (d) divalent radicals included by the formula, ##STR33## where Q is a member selected from the class consisting of ##STR34## and x is a whole number equal to from 1 to 5 inclusive, m and n are whole numbers independently equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric compositions are interacted simultaneously.
Claim 26
Dependent Claim
176 words
A random copolymer comprising (a) from 5 to 95 mol percent of chemically combined units of the formula ##STR35## and (b) from 95 to 5 mol percent of chemically combined units of the formula ##STR36## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR37## and (b) divalent organic radicals of the general formula: ##STR38## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR39## where Q is a member selected from the class consisting of ##STR40## and x is a whole number equal to from 1 to 5, inclusive, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 27
Dependent Claim
176 words
A random copolymer comprising (a) from 5 to 95 mol percent of chemically combined units of the formula ##STR35## and (b) from 95 to 5 mol percent of chemically combined units of the formula ##STR36## where R is a member selected from the class consisting of (a) the following divalent organic radicals: ##STR37## and (b) divalent organic radicals of the general formula: ##STR38## where X is --C y H 2y --, y is a whole number equal to from 1 to 5 inclusive, and R 1 is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxanes, and (d) divalent radicals included by the formula, ##STR39## where Q is a member selected from the class consisting of ##STR40## and x is a whole number equal to from 1 to 5, inclusive, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 28
Dependent Claim
49 words
A random copolymeric composition of matter corresponding to the formula ##STR41## where m and n are whole numbers independently, equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 29
Dependent Claim
49 words
A random copolymeric composition of matter corresponding to the formula ##STR41## where m and n are whole numbers independently, equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 30
Dependent Claim
49 words
A random copolymeric composition of matter corresponding to the formula ##STR42## where m and n are independently whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 31
Dependent Claim
49 words
A random copolymeric composition of matter corresponding to the formula ##STR42## where m and n are independently whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 32
Dependent Claim
49 words
A random copolymeric composition of matter corresponding to the formula ##STR43## where m and n, independently are whole numbers equal to at least 1, and p is a whole number, greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 33
Dependent Claim
49 words
A random copolymeric composition of matter corresponding to the formula ##STR43## where m and n, independently are whole numbers equal to at least 1, and p is a whole number, greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 34
Dependent Claim
46 words
A random copolymeric composition having the formula ##STR44## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 35
Dependent Claim
46 words
A random copolymeric composition having the formula ##STR44## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 36
Dependent Claim
46 words
A random copolymeric composition having the formula ##STR45## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
Claim 37
Dependent Claim
46 words
A random copolymeric composition having the formula ##STR45## where m and n, independently are whole numbers equal to at least 1, and p is a whole number greater than 1, with the proviso that the reactants used to prepare the random copolymeric composition are interacted simultaneously.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-05-24 | 1985-11-23 | 1986-05-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-05-24 | 1989-11-23 | 1990-05-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-05-24 | 1993-11-23 | 1994-05-25 | $7700.00 | Window Closed / Lapsed |