Abstract The instant invention is directed to faceplate glasses for television picture tubes which, because they are essentially free from MgO, have liquidus temperatures below 800° C. Such glasses consist essentially, in weight percent on the oxide basis, of: ______________________________________ SiO 2 58-65
Al 2 O 3 1-3
CaO 1-4
SrO 6-12
BaO 2-9
PbO 1-3
Na 2 O 5-9
K 2 O 5-12
Na 2 O + K 2 O 14-18
TiO 2 0.3-1
CeO 2 0.05-0.5
______________________________________
A glass suitable for the faceplate of a television picture tube having a softening point between 685°-700° C., an annealing point between 495°-515° C., a strain point between 455°-475°, a coefficient of thermal expansion between 98-100×10 -7 /°C., a log resistivity at 250° C. greater than 9, a log resistivity at 350° C. greater than 7, a linear X-ray absorption coefficient at 0.6 A of at least 26 cm -1 , good resistance to X-ray and electron browning, and a liquidus temperature below 800° C. consisting essentially, in weight percent on the oxide basis as calculated from the batch, of: ______________________________________
SiO.sub.2 58-65
Al.sub.2 O.sub.3
1-3
CaO 1-4
SrO 6-12
BaO 2-9
PbO 1-3
Na.sub.2 O 5-9
K.sub.2 O 5-12
Na.sub.2 O + K.sub.2 O 14-18
TiO.sub.2 0.3-1
CeO.sub.2 0.05-0.5
______________________________________ and being essentially free from MgO.
Claim 2
Dependent Claim
137 words
A glass suitable for the faceplate of a television picture tube having a softening point between 685°-700° C., an annealing point between 495°-515° C., a strain point between 455°-475°, a coefficient of thermal expansion between 98-100×10 -7 /°C., a log resistivity at 250° C. greater than 9, a log resistivity at 350° C. greater than 7, a linear X-ray absorption coefficient at 0.6 A of at least 26 cm -1 , good resistance to X-ray and electron browning, and a liquidus temperature below 800° C. consisting essentially, in weight percent on the oxide basis as calculated from the batch, of: ______________________________________
SiO.sub.2 58-65
Al.sub.2 O.sub.3
1-3
CaO 1-4
SrO 6-12
BaO 2-9
PbO 1-3
Na.sub.2 O 5-9
K.sub.2 O 5-12
Na.sub.2 O + K.sub.2 O 14-18
TiO.sub.2 0.3-1
CeO.sub.2 0.05-0.5
______________________________________ and being essentially free from MgO.
Claim 3
Dependent Claim
14 words
A glass according to claim 1 wherein the mole ratio BaO:BaO+SrO ranges about 0.45-0.65.