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US4330628A Expired / Lapsed US ⏱️ 0.0 years remaining

Alkali-resistant glass fibres

Assignee: Pilkington Group Ltd
•
Filing: 1980-03-17
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Granted: 1982-05-18
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Expires: 2000-03-17
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Abstract

Abstract Alkali-resistant glass fibres, in the form of continuous-filament for use as reinforcement in cementitious products, or in the form of glass wool, are given enhanced alkali resistance by the incorporation of ThO 2 . The fibres are formed from a glass composition comprising, in weight percentages: ______________________________________ SiO 2 50 to 75% ThO 2 + ZrO 2 5 to 30% with ThO 2 at least 0.4% R 2 O 0 to 25% R'O 0 to 40% R 2 O + R'O 10 to 40% Rare earth oxides 0 to 20% ______________________________________ the content of ThO 2 being at least 1% when the content of ZrO 2 is less than 6% but not exceeding 9.5% when ZrO 2 exceeds 8%, where R 2 O represents Na 2 O, K 2 O or LiO 2 , with K 2 O not exceeding 10% and Li 2 O not exceeding 5% and R'O represents one or more of MgO, CaO, SrO, BaO, ZnO and MnO.

Inventors

  • 👤 David R. Cockram
  • 👤 Kenneth M. Fyles

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 23:39
CPC Classifications
C; C03; C03C; C03C13/00; C03C13/001; C03C13/002; E; E04; E04C; E04C5/00; E04C5/07

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 128 words
Alkali-resistant glass fibres formed from a glass composition consisting essentially of, in weight percentages: ______________________________________ SiO.sub.2 50 to 75% ThO.sub. 2 + ZrO.sub.2 5 to 30% with ThO.sub.2 being in the range of at least 0.4% up to 4% R.sub.2 O 0 to 25% R'O 0 to 40% R.sub.2 O + R'O 10 to 40% Rare earth oxides 0 to 20% TiO.sub.2 0 to 10% ______________________________________ the content of ThO 2 being at least 1% when the content of ZrO 2 is less than 6%, where R 2 O represents Na 2 O, K 2 O or Li 2 O, with K 2 O not exceeding 10% and Li 2 O not exceeding 5% and R'O represents one or more of MgO, CaO, SrO, BaO, ZnO and MnO.
Claim 2
Dependent Claim 128 words
Alkali-resistant glass fibres formed from a glass composition consisting essentially of, in weight percentages: ______________________________________ SiO.sub.2 50 to 75% ThO.sub. 2 + ZrO.sub.2 5 to 30% with ThO.sub.2 being in the range of at least 0.4% up to 4% R.sub.2 O 0 to 25% R'O 0 to 40% R.sub.2 O + R'O 10 to 40% Rare earth oxides 0 to 20% TiO.sub.2 0 to 10% ______________________________________ the content of ThO 2 being at least 1% when the content of ZrO 2 is less than 6%, where R 2 O represents Na 2 O, K 2 O or Li 2 O, with K 2 O not exceeding 10% and Li 2 O not exceeding 5% and R'O represents one or more of MgO, CaO, SrO, BaO, ZnO and MnO.
Claim 3
Dependent Claim 26 words
Glass fibres according to claim 1, wherein the R 2 O content is between 10 and 25% and the R'O content is from 0 to 15%.
Claim 4
Dependent Claim 26 words
Glass fibres according to claim 1, wherein the R 2 O content is from 0 to 10% and the R'O content is between 15 and 40%.
Claim 5
Dependent Claim 20 words
Glass fibres according to claim 1, wherein the glass composition further comprises up to 20% Al 2 O 3 .
Claim 6
Dependent Claim 20 words
Glass fibres according to claim 1, wherein the glass composition further comprises up to 10% B 2 O 3 .
Claim 7
Dependent Claim 20 words
Glass fibres according to claim 1, wherein the glass composition further comprises up to 5% Fe 2 O 3 .
Claim 8
Dependent Claim 16 words
Glass fibres according to claim 1, wherein the glass composition further comprises up to 2% F.
Claim 9
Dependent Claim 72 words
Glass fibres according to claim 2 formed from a glass composition consisting essentially of, in weight percentages: ______________________________________ SiO.sub.2 51 to 73% ZrO.sub.2 9 to 21% ThO.sub.2 0.5 to 2.5% R.sub.2 O 10 to 21% R'O 0 to 13% Rare earth oxides 4 to 18% F.sub.2 0 to 2% ______________________________________ with K 2 O not exceeding 5% and Li 2 O not exceeding 3% and R 2 O+R'O from 14% to 30%.
Claim 10
Dependent Claim 13 words
Glass fibres according to claim 8, wherein CaO is the principal R'O constituent.
Claim 11
Dependent Claim 24 words
Glass fibres according to claim 8 wherein ZrO 2 exceeds 18%, R 2 O is at least 14% and R'O does not exceed 3%.
Claim 12
Dependent Claim 14 words
A fibre-reinforced cementitious product containing, as reinforcement, alkali-resistant glass fibres according to claim 2.
Claim 13
Dependent Claim 25 words
A cementitious product according to claim 11, wherein the glass fibres constitute from 2 to 10% by weight of the total solids in the product.
Claim 14
Dependent Claim 20 words
A cementitious product according to claim 12, wherein the glass fibres constitute substantially 5% by weight of the total solids.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-05-17 1985-11-16 1986-05-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-05-17 1989-11-16 1990-05-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-05-17 1993-11-16 1994-05-18 $7700.00 Window Closed / Lapsed

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