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US4329423A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic coated film bases

Assignee: Imperial Chemical Industries Ltd
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Filing: 1980-10-22
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Granted: 1982-05-11
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Expires: 2000-10-22
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Abstract

Abstract Improvements in coated film bases. Photobase comprising a film support, e.g. a polyethylene terephthalate film, having a copolymeric subbing layer comprising a copolymer of acrylic acid or an alkyl ester thereof/methacrylic acid or an alkyl ester thereof/itaconic acid or itaconic anhydride, e.g. an ethyl acrylate/methyl methacrylate/itaconic acid copolymer, and containing free itaconic acid, half ester or anhydride which is directly adherent to light-sensitive photographic emulsions.

Inventors

  • 👤 Cyril J. Ealding
  • 👤 Graham Jarrett

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:24
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/91; G03C1/93; Y; Y10; Y10S; Y10S430/00; Y10S430/136

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 183 words
A light-sensitive photographic film, which comprises a self-supporting plastics film, a copolymeric subbing layer applied to at least one surface of said film and a light-sensitive photographic emulsion layer bonded directly to the copolymeric subbing layer, said copolymeric subbing layer comprising a copolymer prepared from a comonomer mixture consisting essentially of 35 to 55 mole % acrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, 35 to 55 mole % methacrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, and 1 to 15 mole % of itaconic acid or itaconic anhydride and 0 to 8 mole % of additional monomer selected from the class consisting of acrylamide, methacrylamide, N-methylol acrylamide, N-ethanol acrylamide, N-propanol acrylamide, N-methylol methacrylamide, N-ethanol methacrylamide, N-methyl acrylamide, N-tertiary-butyl acrylamide, acrylonitrile, halo-substituted acrylonitrile, methacrylonitrile, and dimethylaminoethyl methacrylate, and said copolymeric subbing layer having a dry coat weight in the range 0.05 to 3.00 mg/dm 2 and being applied from an aqueous dispersion having a pH in the range 2.0 to 5.0.
Claim 2
Dependent Claim 183 words
A light-sensitive photographic film, which comprises a self-supporting plastics film, a copolymeric subbing layer applied to at least one surface of said film and a light-sensitive photographic emulsion layer bonded directly to the copolymeric subbing layer, said copolymeric subbing layer comprising a copolymer prepared from a comonomer mixture consisting essentially of 35 to 55 mole % acrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, 35 to 55 mole % methacrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, and 1 to 15 mole % of itaconic acid or itaconic anhydride and 0 to 8 mole % of additional monomer selected from the class consisting of acrylamide, methacrylamide, N-methylol acrylamide, N-ethanol acrylamide, N-propanol acrylamide, N-methylol methacrylamide, N-ethanol methacrylamide, N-methyl acrylamide, N-tertiary-butyl acrylamide, acrylonitrile, halo-substituted acrylonitrile, methacrylonitrile, and dimethylaminoethyl methacrylate, and said copolymeric subbing layer having a dry coat weight in the range 0.05 to 3.00 mg/dm 2 and being applied from an aqueous dispersion having a pH in the range 2.0 to 5.0.
Claim 3
Dependent Claim 23 words
A photographic film according to claim 1, in which the self-supporting plastics film comprises a biaxially oriented and heat-set film of polyethylene terephthalate.
Claim 4
Dependent Claim 25 words
A photographic film according to claim 1, in which the subbing copolymer is prepared from a comonomer mixture which includes ethyl acrylate and methyl methacrylate.
Claim 5
Dependent Claim 38 words
A photographic film according to claim 1, in which the subbing layer comprises at least 1.0% by weight based on the weight of the subbing copolymer of free itaconic acid, half ester of itaconic acid, or itaconic anhydride.
Claim 6
Dependent Claim 49 words
A photographic film according to claim 1, in which the subbing copolymer is prepared from a comonomer mixture which includes 42 to 50 mole % of acrylic acid or the lower alkyl ester thereof and 44 to 55 mole % of methacrylic acid or the lower alkyl ester thereof.
Claim 7
Dependent Claim 37 words
A photographic film according to claim 1, in which the subbing copolymer consists of 43 to 50 mole % ethyl acrylate, 45 to 53 mole % methyl methacrylate and 4 to 10 mole % of itaconic acid.
Claim 8
Dependent Claim 24 words
A photographic film according to claim 1, in which the dried coat weight of the subbing layer is 0.5 to 1.00 mg/dm 2 .
Claim 9
Dependent Claim 171 words
A process for the production of a light-sensitive photographic film, which comprises coating at least one surface of a self-supporting plastics film with a subbing composition consisting essentially of an aqueous dispersion having a pH in the range 2.0 to 5.0 or a solution in an organic solvent of a copolymer prepared from a comonomer mixture comprising 35 to 55 mole % of acrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, 35 to 55 mole % methacrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, and 1 to 15 mole % of itaconic acid or itaconic anhydride and being applied from an aqueous dispersion having a pH in the range 2.0 to 5.0, and causing or allowing the coating to dry to a coat weight in the range 0.05 to 3.00 mg/dm 2 , and applying a layer of a light-sensitive photographic emulsion directly onto the resulting copolymeric subbing layer.
Claim 10
Dependent Claim 171 words
A process for the production of a light-sensitive photographic film, which comprises coating at least one surface of a self-supporting plastics film with a subbing composition consisting essentially of an aqueous dispersion having a pH in the range 2.0 to 5.0 or a solution in an organic solvent of a copolymer prepared from a comonomer mixture comprising 35 to 55 mole % of acrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, 35 to 55 mole % methacrylic acid or a lower alkyl ester thereof in which the alkyl group comprises up to 8 carbon atoms, and 1 to 15 mole % of itaconic acid or itaconic anhydride and being applied from an aqueous dispersion having a pH in the range 2.0 to 5.0, and causing or allowing the coating to dry to a coat weight in the range 0.05 to 3.00 mg/dm 2 , and applying a layer of a light-sensitive photographic emulsion directly onto the resulting copolymeric subbing layer.
Claim 11
Dependent Claim 37 words
A process according to claim 8, in which the self-supporting plastics film is biaxially oriented and the subbing composition is applied to the surface of the film between the two stretching operations employed to orient the film.
Claim 12
Dependent Claim 20 words
A process according to claim 8, in which the subbing composition has a pH in the range 2.5 to 3.0.
Claim 13
Dependent Claim 21 words
A process according to claim 8, in which the subbing composition includes 2 to 10% by weight of the subbing copolymer.
Claim 14
Dependent Claim 22 words
A process according to claim 8, in which the self-supporting plastics film comprises a biaxially oriented and heat-set film of polyethylene terephthalate.
Claim 15
Dependent Claim 24 words
A process according to claim 8, in which the subbing copolymer is prepared from a comonomer mixture which includes ethyl acrylate and methyl methacrylate.
Claim 16
Dependent Claim 32 words
A process according to claim 8, in which the subbing layer comprises at least 1.0% by weight based on the weight of the subbing copolymer of free itaconic acid or itaconic anhydride.
Claim 17
Dependent Claim 48 words
A process according to claim 8, in which the subbing copolymer is prepared from a comonomer mixture which includes 42 to 50 mole % of acrylic acid or the lower alkyl ester thereof and 44 to 55 mole % of methacrylic acid or the lower alkyl ester thereof.
Claim 18
Dependent Claim 36 words
A process according to claim 8, in which the subbing copolymer consists of 43 to 50 mole % ethyl acrylate, 45 to 53 mole % methyl methacrylate and 4 to 10 mole % of itaconic acid.
Claim 19
Dependent Claim 23 words
A process according to claim 8, in which the dried coat weight of the subbing layer is 0.5 to 1.00 mg/dm 2 .

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-05-10 1985-11-09 1986-05-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-05-10 1989-11-09 1990-05-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-05-10 1993-11-09 1994-05-11 $7700.00 Window Closed / Lapsed

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