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US4329252A Expired / Lapsed US ⏱️ 0.0 years remaining

Olefine polymerization catalyst and the production and use thereof

Assignee: Imperial Chemical Industries Ltd
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Filing: 1980-01-10
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Granted: 1982-05-11
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Expires: 2000-01-10
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Abstract

Abstract A component of a polymerisation catalyst is prepared by reacting an organo-magnesium halide with a solid, inorganic oxide, then reacting the product with a Lewis Base compound, particularly as ester and finally with titanium tetrachloride. After reacting the organo-magnesium halide with the inorganic oxide it may be treated with a halogenating agent before it is reacted with the Lewis Base compound. The product obtained is combined with an organo=aluminium compound preferably together with a Lewis Base and used to polymerise an olefine monomer particularly propylene or mixtures of ethylene and a I-olefine containing at least 4 carbon atoms. The catalyst system has a high activity, is stereospecific and has a lower proportion of halogen than some other catalyst systems.

Inventors

  • 👤 Paul D. Gavens
  • 👤 Malcolm P. Rochefort

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 13:03
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 184 words
A process for the production of a composition suitable for use as a component of an olefine polymerisation catalyst, which process comprises treating a component I which is at least one solid inorganic oxide with a component II which is a magnesium hydrocarbyl halide compound, a component III which is an organic Lewis Base compound which affects either the activity or stereospecificity of a Ziegler polymerisation catalyst system and a component IV which is titanium tetrachloride, wherein component III is an ether, a ketone, an alcohol, an ortho-ester, a sulphide, an ester of a thiocarboxylic acid, a thioketone, a thiol, a sulphone, a sulphonamide, a fused ring compound containing a heterocyclic sulphur atom, an organosilicon compond, an amide, urea, a substituted derivative of urea, thiourea, an amine, an organo-phosphine, an organo-phosphine oxide, an organo-phosphite or an organo-phosphate, and (A) component I is reacted with component II; (B) the product of stage (A) is reacted with either component III or component IV; and (C) the product of stage (B) is reacted with whichever of component III or component IV is not used in stage (B).
Claim 2
Dependent Claim 184 words
A process for the production of a composition suitable for use as a component of an olefine polymerisation catalyst, which process comprises treating a component I which is at least one solid inorganic oxide with a component II which is a magnesium hydrocarbyl halide compound, a component III which is an organic Lewis Base compound which affects either the activity or stereospecificity of a Ziegler polymerisation catalyst system and a component IV which is titanium tetrachloride, wherein component III is an ether, a ketone, an alcohol, an ortho-ester, a sulphide, an ester of a thiocarboxylic acid, a thioketone, a thiol, a sulphone, a sulphonamide, a fused ring compound containing a heterocyclic sulphur atom, an organosilicon compond, an amide, urea, a substituted derivative of urea, thiourea, an amine, an organo-phosphine, an organo-phosphine oxide, an organo-phosphite or an organo-phosphate, and (A) component I is reacted with component II; (B) the product of stage (A) is reacted with either component III or component IV; and (C) the product of stage (B) is reacted with whichever of component III or component IV is not used in stage (B).
Claim 3
Dependent Claim 181 words
A process for the production of a composition suitable for use as a component of an olefine polymerisation catalyst, which process comprises treating a component "which is at least one solid inorganic oxide with a component II". I which is a magnesium hydrocarbyl halide compound, a component III which is an organic Lewis Base compound which is an ether, a ketone, an alcohol, an orthoester, a sulphide, an ester of a thiocarboxylic acid, a thioketone, a thiol, a sulphone, a sulphonamide, a fused ring compound containing a heterocyclic sulphur acid, an organo-silicon compound, an amide, urea, a substituted derivative of urea, thiourea, an amine, an organo-phosphine, an organo-phosphine oxide, an organo-phosphite or an organo-phosphite, and a component IV which is titanium tetrachloride, wherein (A) component I is reacted component II; (B) the product of stage (A) is reacted with either component III or component IV; (C) the product of stage (B) is reacted with whichever of component III or component IV is not used in stage (B); and the titanium tetrachloride which is component IV is the only titanium compound used.
Claim 4
Dependent Claim 181 words
A process for the production of a composition suitable for use as a component of an olefine polymerisation catalyst, which process comprises treating a component "which is at least one solid inorganic oxide with a component II". I which is a magnesium hydrocarbyl halide compound, a component III which is an organic Lewis Base compound which is an ether, a ketone, an alcohol, an orthoester, a sulphide, an ester of a thiocarboxylic acid, a thioketone, a thiol, a sulphone, a sulphonamide, a fused ring compound containing a heterocyclic sulphur acid, an organo-silicon compound, an amide, urea, a substituted derivative of urea, thiourea, an amine, an organo-phosphine, an organo-phosphine oxide, an organo-phosphite or an organo-phosphite, and a component IV which is titanium tetrachloride, wherein (A) component I is reacted component II; (B) the product of stage (A) is reacted with either component III or component IV; (C) the product of stage (B) is reacted with whichever of component III or component IV is not used in stage (B); and the titanium tetrachloride which is component IV is the only titanium compound used.
Claim 5
Dependent Claim 61 words
An olefine polymerisation catalyst which comprises (1) the reaction product obtained by the process of claim 2; and (2) an organic compound of a metal of Group IIA of the Periodic Table or of aluminium or a complex of an organo-metallic compound of a metal of Group IA or Group IIA of the Periodic Table with an organic compound of aluminium.
Claim 6
Dependent Claim 49 words
The catalyst of claim 3 wherein component (2) is an aluminium trihydrocarbyl compound and the catalyst also includes an ester of the formula R.sup.1 COOR.sup.2 wherein R 1 is an aryl group which may be substituted by one or more hydrocarbyloxy groups; and R 2 is an alkyl group.
Claim 7
Dependent Claim 43 words
The process of claim 2 wherein, in stage (A), component I is reacted with component II, in stage (B), the product from stage (A) is reacted with component III, and in stage (C), the product of stage (B) is reacted with component IV.
Claim 8
Dependent Claim 19 words
The process of claim 2 wherein component I is silica, alumina, magnesia or mixtures of two or more thereof.
Claim 9
Dependent Claim 40 words
The process of claim 2 wherein component II is a compound of the formula MgR.sub.(2-x) X.sub.x wherein R is a hydrocarbyl group; X is a halogen atom, other than fluorine; and x is a number from 0.5 up to 1.5.
Claim 10
Dependent Claim 28 words
The process of claim 2 wherein the quantity of component II is in excess of one mole for each mole of reactive sites in the solid inorganic oxide.
Claim 11
Dependent Claim 33 words
The process of claim 2 wherein the Lewis Base which is component III is used in an amount of from 0.1 up to 0.8 mole for each mole of the reacted magnesium compound.
Claim 12
Dependent Claim 26 words
The process of claim 2 wherein the amount of titanium tetrachloride which is component IV is in a molar excess relative to the reacted magnesium compound.
Claim 13
Dependent Claim 47 words
The process of claim 2 wherein before or after stage (A), the at least one solid inorganic oxide which is component I, or the supported product from stage (A), is treated with at least one halogenating agent before it is treated with component III or component IV.
Claim 14
Dependent Claim 29 words
The process of claim 2 wherein the product of stage (A) is reacted simultaneously with at least one halogenating agent and the Lewis Base compound which is component III.
Claim 15
Dependent Claim 117 words
The process of claim 11 or claim 10 wherein the halogenating agent is a hydrogen halide, a silicon halide of the formula R.sub.a.sup.3 SiX.sub.(4-a), a carboxylic acid halide of the formula R.sup.4 COX, a hydrocarbyl halide of the formula R.sup.5 X.sub.b, phosphorus pentachloride, thionyl chloride, sulphuryl chloride, phosgene, nitrosyl chloride, a halide of a mineral acid, chlorine, bromine, a chlorinated polysiloxane, a hydrocarbyl aluminium halide, aluminium chloride or ammonium hexafluorosilicate, wherein R 3 is hydrogen or a hydrocarbyl group; R 4 is a hydrocarbyl group; R 5 is a hydrocarbyl residue; X is as hereinbefore defined; a is 0 or an integer from 1 up to 3; and b is an integer from 1 up to 10.
Claim 16
Dependent Claim 43 words
The process of claim 9 or claim 10 wherein the quantity of the at least one halogenating agent is sufficient to provide at least one halogen atom at every reactive site on the at least one solid inorganic oxide which is component I.
Claim 17
Dependent Claim 21 words
The process of claim 2 or claim 9 wherein the product is separated and washed between each stage of the reaction.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-05-10 1985-11-09 1986-05-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-05-10 1989-11-09 1990-05-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-05-10 1993-11-09 1994-05-11 $7700.00 Window Closed / Lapsed

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