US4329233A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the purification of water
Assignee: Shell USA Inc
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Filing: 1980-11-25
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Granted: 1982-05-11
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Expires: 2000-11-25
Abstract
Abstract A process for purification of water containing certain organic hetero compounds by contacting with certain crystalline iron silicates found to be unexpectedly efficient to adsorb said organic compounds from the water.
Inventors
- 👤 Andreas B. van Aken
- 👤 George C. Blytas
- 👤 Rene M. Visser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 08:19
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/28; C02F1/281; B; B01; B01J; B01J20/00; B01J20/02; B01J20/10; B01J20/16; B01J20/18
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
189 words
A process for the purification of water, containing at least one organic compound comprising carbon, hydrogen and at least one atom selected from oxygen and nitrogen, said organic compound having a solubility in water at 20° C. of more than 1 g/100 ml, which process comprises contacting said water as feed in a contact zone with a crystalline iron silicate having the following properties: (a) thermally stable up to a temperature above 600° C., (b) an X-ray powder diffraction pattern showing, inter alia, the reflections given in Table A of the specification, (c) in the dehydrated form the following overall composition, expressed in moles of the oxides: (1.0±0.3)(R).sub.2/n O.[a Fe.sub.2 O.sub.3.b Al.sub.2 O.sub.3.c Ga.sub.2 O.sub.3 ].y (d SiO.sub.2.e (GeO.sub.2), where R=one or more monovalent or bivalent cations, a>0.1; b>0, c>0, a+b+c=1; y>10, d>0.1, e>0, d+e=1; and n=the valency of R; and in which oxides of hydrogen, alkali metal and/or alkaline-earth metal, silicon and iron are present, and the Fe 2 O 3 /SiO 2 molar ratio is less than 0.1; and separating a water product having lower content of said at least one organic compound than said feed water.
Claim 2
Dependent Claim
189 words
A process for the purification of water, containing at least one organic compound comprising carbon, hydrogen and at least one atom selected from oxygen and nitrogen, said organic compound having a solubility in water at 20° C. of more than 1 g/100 ml, which process comprises contacting said water as feed in a contact zone with a crystalline iron silicate having the following properties: (a) thermally stable up to a temperature above 600° C., (b) an X-ray powder diffraction pattern showing, inter alia, the reflections given in Table A of the specification, (c) in the dehydrated form the following overall composition, expressed in moles of the oxides: (1.0±0.3)(R).sub.2/n O.[a Fe.sub.2 O.sub.3.b Al.sub.2 O.sub.3.c Ga.sub.2 O.sub.3 ].y (d SiO.sub.2.e (GeO.sub.2), where R=one or more monovalent or bivalent cations, a>0.1; b>0, c>0, a+b+c=1; y>10, d>0.1, e>0, d+e=1; and n=the valency of R; and in which oxides of hydrogen, alkali metal and/or alkaline-earth metal, silicon and iron are present, and the Fe 2 O 3 /SiO 2 molar ratio is less than 0.1; and separating a water product having lower content of said at least one organic compound than said feed water.
Claim 3
Dependent Claim
16 words
A process according to claim 1 wherein the feed water contains 10-10000 ppmw of organic compounds.
Claim 4
Dependent Claim
16 words
A process according to claim 2 wherein said feed water contains 100-5000 ppmw of organic compounds.
Claim 5
Dependent Claim
45 words
A process according to claim 1 which comprises the following additional steps: after separating said product, regenerating the crystalline iron silicate, and then purifying additional water containing said at least one organic compound by contacting said water as feed with said regenerated crystalline iron silicate.
Claim 6
Dependent Claim
33 words
A process according to claim 4 wherein both the contacting step and the regeneration of the iron silicate are effected on an iron silicate that is in the form of a fixed bed.
Claim 7
Dependent Claim
31 words
A process according to claim 4 wherein the regeneration of the iron silicate is carried out by contacting said silicate with an oxygen-containing gas at a temperature higher than 400° C.
Claim 8
Dependent Claim
21 words
A process according to claim 1 wherein said feed water is contacted with crystalline iron silicate substantially in the hydrogen form.
Claim 9
Dependent Claim
26 words
A process according to claim 1 wherein said feed water is contacted with a crystalline iron silicate substantially in the alkali metal and/or alkaline-earth metal form.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-05-10 | 1985-11-09 | 1986-05-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-05-10 | 1989-11-09 | 1990-05-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-05-10 | 1993-11-09 | 1994-05-11 | $7700.00 | Window Closed / Lapsed |