US4328384A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Fluid zeolite catalyst conversion of alcohols and oxygenated derivatives to hydrocarbons by controlling exothermic reaction heat
Assignee: Mobil Oil AS
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Filing: 1980-09-29
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Granted: 1982-05-04
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Expires: 2000-09-29
Abstract
Abstract Alcohols and related oxygenates are converted in a riser reactor and dense fluid catalyst bed (ZSM-5 zeolite catalyst) circulated through a plurality of satellite stripping-cooling zones for temperature control. Catalyst utilized comprises from 5 to 20 weight percent coke for activity and selectivity characteristics promoting the formation of olefins and aromatics at temperatures below about 427 DEG C. (800 DEG F.).
Inventors
- 👤 Nicholas Daviduk
- 👤 James H. Haddad
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:37
CPC Classifications
C; C07; C07C; C07C1/00; C07C1/20; B; B01; B01J; B01J8/00; B01J8/18; B01J8/24; B01J8/26; C10; C10G; C10G3/00; C10G3/42; C10G3/44; C10G3/48; C10G3/49; C10G3/54; C10G3/55; C10G3/57; C10G3/60; C10G3/62; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; C07C2529/65; C07C2529/70; C10G2300/00; C10G2300/40; C10G2300/4006; C10G2300/4093; C10G2300/70; C10G2300/708; C10G2400/00; C10G2400/02; C10G2400/28; C10G2400/30; Y; Y02; Y02P; Y02P30/00; Y02P30/20
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
230 words
A method for converting reactants comprising lower alcohols and related oxygenates to C 10 and lower boiling hydrocarbon compounds, including LPG and gasoline boiling range components, which comprises: passing a suspension of vaporized reactant material and fluid catalyst particles comprising a crystalline zeolite material characterized by a silica to alumina mole ratio of at least 12 and a constraint index of within the approximate range of 1-12 upwardly through a relatively dispersed catalyst phase riser contact zone for a time, temperature and pressure suitable to achieve up to 70% conversion of methanol in the reactant feed; passing the suspension comprising products of reaction upwardly through a relatively dense fluid mass of catalyst particles for a residence time and temperature sufficient to achieve a total conversion of alcohol in the feed equivalent to at least 90% and produce simultaneously a product mixture of C 1 to C 10 hydrocarbons comprising paraffins, olefins, and aromatics; passing catalyst withdrawn from a lower portion of said relatively dense fluid mass of catalyst particles downwardly through a plurality of separate catalyst stripping-cooling zones of desired temperature restriction and thence to the riser reactor for admixture with charged vaporous reactant; passing stripped products from the stripping-cooling zone into admixture with product mixture above said more dense fluid mass of catalyst and withdrawing reaction products separated from said catalyst from an upper portion of said reaction zone.
Claim 2
Independent Claim
230 words
A method for converting reactants comprising lower alcohols and related oxygenates to C 10 and lower boiling hydrocarbon compounds, including LPG and gasoline boiling range components, which comprises: passing a suspension of vaporized reactant material and fluid catalyst particles comprising a crystalline zeolite material characterized by a silica to alumina mole ratio of at least 12 and a constraint index of within the approximate range of 1-12 upwardly through a relatively dispersed catalyst phase riser contact zone for a time, temperature and pressure suitable to achieve up to 70% conversion of methanol in the reactant feed; passing the suspension comprising products of reaction upwardly through a relatively dense fluid mass of catalyst particles for a residence time and temperature sufficient to achieve a total conversion of alcohol in the feed equivalent to at least 90% and produce simultaneously a product mixture of C 1 to C 10 hydrocarbons comprising paraffins, olefins, and aromatics; passing catalyst withdrawn from a lower portion of said relatively dense fluid mass of catalyst particles downwardly through a plurality of separate catalyst stripping-cooling zones of desired temperature restriction and thence to the riser reactor for admixture with charged vaporous reactant; passing stripped products from the stripping-cooling zone into admixture with product mixture above said more dense fluid mass of catalyst and withdrawing reaction products separated from said catalyst from an upper portion of said reaction zone.
Claim 3
Dependent Claim
43 words
The method of claim 1 wherein the exothermic temperature rise of said conversion in said riser and said relatively dense fluid mass of catalyst is restricted to maintain a dispersed phase temperature above said dense fluid mass of not more than 427° C.
Claim 4
Dependent Claim
17 words
The method of claim 2 wherein said dispersed phase temperature is restricted not to exceed 407° C.
Claim 5
Dependent Claim
27 words
The method of claim 1 wherein the catalyst to reactant ratio of the initially formed suspension in the riser is within the range of 10/1 to 20/1.
Claim 6
Dependent Claim
42 words
The method of claim 1 wherein the relatively dense fluid mass of catalyst is provided with vertically extending baffle means arranged to restrict the vaporous catalyst mixture passing upwardly therethrough to a hydraulic diameter within the range of 4 to 8 inches.
Claim 7
Dependent Claim
47 words
The method of claim 1 wherein a portion of the circulated catalyst is withdrawn, subjected to partial regeneration, and thereafter returned to the circulated catalyst inventory, and the catalyst charged to the riser contains in from about 5 to about 20 weight percent coke on the catalyst.
Claim 8
Dependent Claim
48 words
The method of claim 1 wherein catalyst circulation through the riser, dense fluid mass of catalyst thereabove and the stripper-cooling zone is in response to the reactant feed rate and the catalyst pressure at the base of a catalyst transfer zone in communication with said riser reaction zone.
Claim 9
Dependent Claim
30 words
The method of claim 1, 2, 3, 4, 5, 6 or 7 wherein said zeolite is chosen from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38 and ZSM-48.
Claim 10
Dependent Claim
10 words
The method of claim 8 wherein said zeolite is ZSM-5.
Claim 11
Dependent Claim
13 words
The method of claim 8 wherein said zeolite additionally comprises a binder therefor.
Claim 12
Dependent Claim
10 words
The method of claim 1 wherein said reactants comprise methanol.
Claim 13
Dependent Claim
11 words
The method of claim 1 wherein said reactants comprise dimethyl ether.
Claim 14
Dependent Claim
16 words
The method of claim 1 wherein said reactants comprise a mixture of lower alcohols and ethers.
Claim 15
Dependent Claim
16 words
The method of claim 1 wherein said reactants comprise a mixture of lower alcohols and aldehydes.
Claim 16
Dependent Claim
16 words
The method of claim 1 wherein said reactants comprise a mixture of lower alcohols and ketones.
Claim 17
Independent Claim
21 words
The method of claims 2 or 3 wherein the residence time in the riser contact zone is 1 to 10 seconds.
Claim 18
Independent Claim
25 words
The method of claims 2 or 3 wherein the residence time in the relatively dense fluid mass of catalyst particles is 5 to 80 seconds.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-05-03 | 1985-11-02 | 1986-05-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-05-03 | 1989-11-02 | 1990-05-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-05-03 | 1993-11-02 | 1994-05-04 | $7700.00 | Window Closed / Lapsed |