US4327192A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of fabricating nested shells and resulting product
Assignee: United States Department of Energy
•
Filing: 1980-10-06
•
Granted: 1982-04-27
•
Expires: 2000-10-06
Abstract
Abstract A multiple shell structure and a method of manufacturing such structure wherein a hollow glass microsphere is surface treated in an organosilane solution so as to render the shell outer surface hydrophobic. The surface treated glass shell is then suspended in the oil phase of an oil-aqueous phase dispersion. The oil phase includes an organic film-forming monomer, a polymerization initiator and a blowing agent. A polymeric film forms at each phase boundary of the dispersion and is then expanded in a blowing operation so as to form an outer homogeneously integral monocellular substantially spherical thermoplastic shell encapsulating an inner glass shell of lesser diameter.
Inventors
- 👤 Timothy M. Henderson
- 👤 Lawrence B. Kool
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 11:25
CPC Classifications
G; G21; G21B; G21B1/00; G21B1/11; G21B1/19; B; B01; B01J; B01J13/00; B01J13/02; B01J13/06; B01J13/14; B01J13/18; B01J13/185; C; C08; C08J; C08J9/00; C08J9/32; Y; Y02; Y02E; Y02E30/00; Y02E30/10; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2993; Y10T428/2996
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
149 words
A method of in situ microencapsulation of hollow nested shells of the type which comprise an inner shell floating within a surrounding outer shell, said method comprising the steps: (a) surface treating a precursor shell so as to render the outer surface of said precursor shell hydrophobic, (b) suspending the surface-treated precursor shell within the oil phase of an oil-aqueous phase dispersion, with said oil phase including an organic film-forming monomer and a liquid blowing agent, and (c) initiating polymerization within said oil phase such that particles are formed comprising a polymeric film at the oil-aqueous phase boundary of said dispersion encapsulating said surface-treated precursor shell, and (d) heating the polymeric particle formed in said step (c) to a temperature sufficient to cause volatilization of the liquid blowing agent thereby expanding said particle to form a homogeneously integral monocellular substantially spherical polymeric shell having said precursor shell encapsulated therewithin.
Claim 2
Independent Claim
149 words
A method of in situ microencapsulation of hollow nested shells of the type which comprise an inner shell floating within a surrounding outer shell, said method comprising the steps: (a) surface treating a precursor shell so as to render the outer surface of said precursor shell hydrophobic, (b) suspending the surface-treated precursor shell within the oil phase of an oil-aqueous phase dispersion, with said oil phase including an organic film-forming monomer and a liquid blowing agent, and (c) initiating polymerization within said oil phase such that particles are formed comprising a polymeric film at the oil-aqueous phase boundary of said dispersion encapsulating said surface-treated precursor shell, and (d) heating the polymeric particle formed in said step (c) to a temperature sufficient to cause volatilization of the liquid blowing agent thereby expanding said particle to form a homogeneously integral monocellular substantially spherical polymeric shell having said precursor shell encapsulated therewithin.
Claim 3
Dependent Claim
33 words
The method set forth in claim 1 wherein said precursor shell is of glass material composition, and wherein said step (a) comprises the step of suspending said inner shell in an organosilane solution.
Claim 4
Dependent Claim
13 words
The method set forth in claim 2 wherein said monomer comprises methyl methacrylate.
Claim 5
Dependent Claim
28 words
The method set forth in claim 1, 2 or 3 wherein said precursor shell is of material composition selected from the group consisting of glass, metal and thermoplastics.
Claim 6
Dependent Claim
18 words
A nested shell structure manufactured in accordance with the method set forth in claim 1, 2 or 3.
Claim 7
Dependent Claim
39 words
A multiple shell structure comprising a homogeneously integral monocellular substantially spherical hollow outer shell of thermoplastic polymeric construction, and an inner shell of substantially spherical hollow glass construction with hydrophobic surface pre-treatment encapsulated and floating within said outer shell.
Claim 8
Dependent Claim
39 words
A multiple shell structure comprising a homogeneously integral monocellular substantially spherical hollow outer shell of thermoplastic polymeric construction, and an inner shell of substantially spherical hollow glass construction with hydrophobic surface pre-treatment encapsulated and floating within said outer shell.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-04-26 | 1985-10-26 | 1986-04-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-04-26 | 1989-10-26 | 1990-04-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-04-26 | 1993-10-26 | 1994-04-27 | $7700.00 | Window Closed / Lapsed |