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US4327007A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyethylene terephthalate composition containing aliphatic plasticizer and nucleating agent

Assignee: Honeywell International Inc
•
Filing: 1980-12-22
•
Granted: 1982-04-27
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Expires: 2000-12-22
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Abstract

Abstract A polyester composition comprising: the sodium salt of a hydrocarbon acid; and the ester of an aliphatic carboxylic acid having at least one carboxyl group and from 2 to 8 carbon atoms; and an alcohol having one hydroxyl group and from 1 to 10 carbon atoms. The sodium salt is preferably sodium stearate and the ester is preferably di(2-ethyl-hexyl)adipate. The composition can be filled and have impact modifiers.

Inventors

  • 👤 Nicholas Vanderkooi, Jr.
  • 👤 Harold W. Tuller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 13:43
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08K5/10; C08K5/11

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 98 words
A composition comprising: polyethylene terephthalate; up to about 15 percent based on the weight of the polyethylene terephthalate of a plasticizer which comprises an ester of an aliphatic carboxylic acid having from 2 to 8 carbon atoms and at least 1 carboxyl group, and an alcohol having from 1 to 10 carbon atoms and 1 hydroxyl group; and up to about 10 percent, based on the weight of the polyethylene terephthalate, of a nucleating agent which comprises the sodium salt of a hydrocarbon acid having from 9 to about 25 carbon atoms, and at least 1 carboxyl group.
Claim 2
Dependent Claim 98 words
A composition comprising: polyethylene terephthalate; up to about 15 percent based on the weight of the polyethylene terephthalate of a plasticizer which comprises an ester of an aliphatic carboxylic acid having from 2 to 8 carbon atoms and at least 1 carboxyl group, and an alcohol having from 1 to 10 carbon atoms and 1 hydroxyl group; and up to about 10 percent, based on the weight of the polyethylene terephthalate, of a nucleating agent which comprises the sodium salt of a hydrocarbon acid having from 9 to about 25 carbon atoms, and at least 1 carboxyl group.
Claim 3
Dependent Claim 27 words
The composition as recited in claim 1 wherein there is from about 0.1% to about 10%, based on the weight of the polyethylene terephthalate, of the plasticizer.
Claim 4
Dependent Claim 27 words
The composition as recited in claim 2 wherein there is from about 1% to about 6%, based on the weight of the polyethylene terephthalate, of the plasticizer.
Claim 5
Dependent Claim 28 words
The composition as recited in claims 1 or 3 wherein the nucleating agent is the sodium salt of a hydrocarbon acid having from 16 to 18 carbon atoms.
Claim 6
Dependent Claim 12 words
The composition as recited in claim 4 wherein the plasticizer is di(2-ethyl-hexyl)adipate.
Claim 7
Dependent Claim 26 words
The composition as recited in claim 4 wherein there is from about 0.2% to 2%, based on the weight of the polyethylene terephthalate, of nucleating agent.
Claim 8
Dependent Claim 14 words
The composition as recited in claim 4 wherein the nucleating agent is sodium stearate.
Claim 9
Dependent Claim 20 words
The composition as recited in claim 7 where there is from about 0.2% to about 1% of the sodium stearate.
Claim 10
Dependent Claim 12 words
The composition as recited in claim 8 wherein the plasticizer in di(2-ethyl-hexyl)adipate.
Claim 11
Dependent Claim 23 words
The composition as recited in claim 1 further comprising up to 150%, based on the weight of the polyethylene terephthalate, of a filler.
Claim 12
Dependent Claim 28 words
The composition as recited in claim 10 wherein there is between about 30% and about 90%, based on the weight of the polyethylene terephthalate, of glass fiber filler.
Claim 13
Dependent Claim 25 words
The composition as recited in claim 1, 4 further comprising up to 10%, based on the weight of the polyethylene terephthalate, of an impact modifier.
Claim 14
Dependent Claim 34 words
The composition as recited in claim 12 wherein the impact modifier is selected from a group consisting of the following copolymers: ethylene acrylic acid, methylene acrylic acid, ethylene ethyl acrylate, and ethylene vinyl acetate.
Claim 15
Dependent Claim 26 words
The composition as recited in claim 13 containing between about 2% and about 6%, based on the weight of the polyethylene terephthalate, of the impact modifier.
Claim 16
Dependent Claim 19 words
The composition as recited in claim 4, further comprising up to 3% of the polyethylene terephthalate of an epoxy.
Claim 17
Dependent Claim 25 words
The composition as recited in claim 1 containing sufficient nucleating agent for the composition to have a T cc of at least about 210° C.
Claim 18
Dependent Claim 24 words
The composition as recited in claim 1 containing sufficient plasticizer for the composition to have a T ch of not greater than 110° C.
Claim 19
Dependent Claim 39 words
A composition comprising: polyethylene terephthalate; from about 1% to about 6%, based on the weight of the polyethylene terephthalate, of di(2-ethyl-hexyl)adipate; and from about 0.2% to about 2%, based on the weight of the polyethylene terephthalate, of sodium stearate.
Claim 20
Dependent Claim 39 words
A composition comprising: polyethylene terephthalate; from about 1% to about 6%, based on the weight of the polyethylene terephthalate, of di(2-ethyl-hexyl)adipate; and from about 0.2% to about 2%, based on the weight of the polyethylene terephthalate, of sodium stearate.
Claim 21
Dependent Claim 23 words
The composition as recited in claim 18 further comprising up to 150%, based on the weight of the polyethylene terephthalate, of a filler.
Claim 22
Dependent Claim 27 words
The composition as recited in claim 19 wherein there is from about 30% to about 90%, based on the weight of the polyethylene terephthalate, of a filler.
Claim 23
Dependent Claim 13 words
The composition as recited in claim 20 wherein the filler is glass fibers.
Claim 24
Dependent Claim 26 words
The composition as recited in claims 18 or 19 further comprising about 2% to about 6%, by weight of the polyethylene terephthalate, of an impact modifier.
Claim 25
Dependent Claim 16 words
The composition as recited in claim 20 wherein the impact modifier is ethylene acrylic acid copolymer.
Claim 26
Dependent Claim 19 words
The composition as recited in claim 18 further comprising up to 3% of the polyethylene terephthalate of an epoxy.

References Cited (Backward Citations)

US3516957A Cited
NL7901609A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-04-26 1985-10-26 1986-04-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-04-26 1989-10-26 1990-04-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-04-26 1993-10-26 1994-04-27 $7700.00 Window Closed / Lapsed

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