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US4325983A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalytic promoters in electroless plating catalysts added prior to a colloidal nucleation process

Assignee: Individual
•
Filing: 1979-03-29
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Granted: 1982-04-20
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Expires: 1999-03-29
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Abstract

Abstract A composition for catalyzing a substrate prior to electroless metal deposition. The catalyst formulation comprises the admixture of a principal catalytic agent and a catalytic promoting agent. The principal catalytic agent is selected preferably from the metals of Period 4 and Groups IB and VIII of the Periodic Table of the Elements while the catalytic promoting agents are selected from metals of Period 4, 5, 6 and Groups IVB, VB, VIB, and VIIB of the Periodic Table of the Elements.

Inventors

  • 👤 Nathan Feldstein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 17:14
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/28; H; H05; H05K; H05K3/00; H05K3/10; H05K3/18; H05K3/181

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 189 words
A process for electroless metal deposition onto a non-conductor surface (1) contacting said surface with a colloidal catalytic composition comprising the admixture of a principal catalytic agent wherein said principal catalytic agent is a compound of a metal selected from the groups of metals consisting of copper, nickel, cobalt, and iron and mixtures thereof and a catalytic promoter agent wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Mg, Ca, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Tc and Re and mixtures thereof and further said catalytic promoter is added prior to the colloidal nucleation process in which the principal catalytic agent is allowed to react as to yield a colloid, and further wherein the concentrations for the principal catalytic agent and the catalytic promoter agent are so adjusted as to yield a catalytic composition having a greater catalytic activity for electroless metal deposition in comparison to the same catalytic composition in the absence of said catalytic promoter agent, and (2) contacting the treated non-conductor with a compatible electroless plating bath to deposit a metallic layer.
Claim 2
Dependent Claim 189 words
A process for electroless metal deposition onto a non-conductor surface (1) contacting said surface with a colloidal catalytic composition comprising the admixture of a principal catalytic agent wherein said principal catalytic agent is a compound of a metal selected from the groups of metals consisting of copper, nickel, cobalt, and iron and mixtures thereof and a catalytic promoter agent wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Mg, Ca, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Tc and Re and mixtures thereof and further said catalytic promoter is added prior to the colloidal nucleation process in which the principal catalytic agent is allowed to react as to yield a colloid, and further wherein the concentrations for the principal catalytic agent and the catalytic promoter agent are so adjusted as to yield a catalytic composition having a greater catalytic activity for electroless metal deposition in comparison to the same catalytic composition in the absence of said catalytic promoter agent, and (2) contacting the treated non-conductor with a compatible electroless plating bath to deposit a metallic layer.
Claim 3
Dependent Claim 29 words
The process according to claim 1 wherein said catalytic promoter agent is selected from at least one member of the group consisting of chromium, vanadium, molybdenum, tungstem and zirconium.
Claim 4
Dependent Claim 14 words
The process according to claim 1 wherein said electroless metal deposition is electroless copper.
Claim 5
Dependent Claim 15 words
The process according to claim 1 wherein said electroless metal deposition yields an image intensification.
Claim 6
Dependent Claim 16 words
The process according to claim 1 wherein said principal catalytic agent is a compound containing copper.
Claim 7
Dependent Claim 22 words
The process according to claim 1 further containing the step of activation and wherein said activation step is devoid of precious metal(s).
Claim 8
Dependent Claim 13 words
The process according to claim 6 further containing the step of electroless deposition.
Claim 9
Dependent Claim 11 words
The process according to claim 1 wherein said non-conductor is ABS.
Claim 10
Dependent Claim 31 words
The process according to claim 1 wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Zr, Hf, V, Cr, Mo, W,.
Claim 11
Dependent Claim 22 words
The process according to claim 1 wherein said principal catalytic agent is a compound of copper and further contains a nickel compound.
Claim 12
Dependent Claim 22 words
The process according to claim 1 wherein said principal catalytic agent is a copper compound and further contains a compound of cobalt.
Claim 13
Dependent Claim 24 words
The process according to claim 1 wherein the concentration of the principal catalytic agent is greater than the concentration of the catalytic promoter agent.
Claim 14
Dependent Claim 23 words
The process according to claim 1 further containing the step of activation whereby the induction time for the actual metal deposition is reduced.
Claim 15
Dependent Claim 31 words
The process according to claim 13 wherein said activation comprises a reduction step and wherein said reduction may be effected via chemical reducing agent or light or heat and combinations thereof.
Claim 16
Dependent Claim 23 words
The process according to claim 1 wherein the concentration of said catalytic promoter agent is from about 0.12 g/l to about 1.2 g/l.
Claim 17
Dependent Claim 16 words
The process according to claim 1 wherein said colloidal catalytic composition is in an alkaline pH.
Claim 18
Dependent Claim 13 words
The process according to claim 1 further containing the step of water rinsing.
Claim 19
Dependent Claim 18 words
The process according to claim 1 wherein said colloidal catalytic composition further contains at least one colloid stabilizer.
Claim 20
Dependent Claim 35 words
The process according to claim 1 further containing the step of activation and wherein said activation selectively removes colloid stabilizer present on the non-conductor surface after contacting said non-conductor surface with said colloidal catalytic composition.
Claim 21
Dependent Claim 12 words
The process according to claim 1 further containing the step of drying.
Claim 22
Dependent Claim 20 words
The process according to claim 1 wherein said non-conductor is preconditioned prior to contacting with said said colloidal catalytic composition.
Claim 23
Dependent Claim 15 words
The process according to claim 1 wherein said non-conductor is a printed circuitry type substrate.

References Cited (Backward Citations)

US3513109A Cited
US3767590A Cited
US3958048A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-04-19 1985-10-19 1986-04-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-04-19 1989-10-19 1990-04-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-04-19 1993-10-19 1994-04-20 $7700.00 Window Closed / Lapsed

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