US4325933A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for stabilization of sodium percarbonate
Assignee: Kao Corp
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Filing: 1980-06-11
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Granted: 1982-04-20
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Expires: 2000-06-11
Abstract
Abstract Sodium percarbonate can be stabilized by treatment with an aqueous solution of an alkaline earth metal salt to form a thin layer of an alkaline earth metal carbonate on the surface. The resulting sodium percarbonate is improved its respect to the nonhygroscopic property, while maintaining the same solubility in water and effective oxygen content as initially.
Inventors
- 👤 Tadao Matsumoto
- 👤 Masaaki Koizawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 12:11
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3902; C11D3/3937; C01; C01B; C01B15/00; C01B15/055; C01B15/10; C01B15/106
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
72 words
A process for preparing stabilized sodium percarbonate which comprises the steps of: contacting particles of sodium percarbonate with a treating agent comprised of an aqueous solution of barium chloride under conditions effective to react the sodium percarbonate on the surfaces of said particles with said barium chloride to form a thin surface layer of barium carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated particles.
Claim 2
Dependent Claim
72 words
A process for preparing stabilized sodium percarbonate which comprises the steps of: contacting particles of sodium percarbonate with a treating agent comprised of an aqueous solution of barium chloride under conditions effective to react the sodium percarbonate on the surfaces of said particles with said barium chloride to form a thin surface layer of barium carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated particles.
Claim 3
Dependent Claim
72 words
A process for preparing stabilized sodium percarbonate which comprises the steps of: contacting particles of sodium percarbonate with a treating agent comprised of an aqueous solution of strontium chloride under conditions effective to react the sodium percarbonate on the surfaces of said particles with said strontium chloride to form a thin surface layer of strontium carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated particles.
Claim 4
Dependent Claim
72 words
A process for preparing stabilized sodium percarbonate which comprises the steps of: contacting particles of sodium percarbonate with a treating agent comprised of an aqueous solution of strontium chloride under conditions effective to react the sodium percarbonate on the surfaces of said particles with said strontium chloride to form a thin surface layer of strontium carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated particles.
Claim 5
Dependent Claim
72 words
A process for preparing stabilized sodium percarbonate which comprises the steps of: contacting particles of sodium percarbonate with a treating agent comprised of an aqueous solution of calcium chloride under conditions effective to react the sodium percarbonate on the surfaces of said particles with said calcium chloride to form a thin surface layer of calcium carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated particles.
Claim 6
Dependent Claim
72 words
A process for preparing stabilized sodium percarbonate which comprises the steps of: contacting particles of sodium percarbonate with a treating agent comprised of an aqueous solution of calcium chloride under conditions effective to react the sodium percarbonate on the surfaces of said particles with said calcium chloride to form a thin surface layer of calcium carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated particles.
Claim 7
Dependent Claim
123 words
A process for treating sodium percarbonate particles to stabilize same, which consists essentially of the steps of: spraying onto the surfaces of preformed particles of sodium percarbonate having a particle size of from 100 to 1,000 microns, a treating agent consisting essentially of an aqueous solution of one or more water-soluble alkaline earth metal salts selected from the group consisting of magnesium sulfate, magnesium chloride, calcium chloride, strontium chloride and barium chloride, under conditions effective to react from 0.07 to 0.3 mole of said alkaline earth metal salt per mole of said sodium percarbonate to form a thin surface layer of alkaline earth metal carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated sodium percarbonate particles.
Claim 8
Dependent Claim
123 words
A process for treating sodium percarbonate particles to stabilize same, which consists essentially of the steps of: spraying onto the surfaces of preformed particles of sodium percarbonate having a particle size of from 100 to 1,000 microns, a treating agent consisting essentially of an aqueous solution of one or more water-soluble alkaline earth metal salts selected from the group consisting of magnesium sulfate, magnesium chloride, calcium chloride, strontium chloride and barium chloride, under conditions effective to react from 0.07 to 0.3 mole of said alkaline earth metal salt per mole of said sodium percarbonate to form a thin surface layer of alkaline earth metal carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated sodium percarbonate particles.
Claim 9
Dependent Claim
124 words
A process for treating sodium percarbonate particles to stabilize same, which consists essentially of the steps of: adding preformed particles of sodium percarbonate having a particle size of from 100 to 1,000 microns, to a treating agent consisting essentially of an aqueous solution of one or more water-soluble alkaline earth metal salts selected from the group consisting of magnesium sulfate, magnesium chloride, calcium chloride, strontium chloride and barium chloride, and agitating the mixture under conditions effective to react from 0.07 to 0.3 mole of said alkaline earth metal salt per mole of said sodium percarbonate to form a thin surface layer of alkaline earth metal carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated sodium percarbonate particles.
Claim 10
Dependent Claim
124 words
A process for treating sodium percarbonate particles to stabilize same, which consists essentially of the steps of: adding preformed particles of sodium percarbonate having a particle size of from 100 to 1,000 microns, to a treating agent consisting essentially of an aqueous solution of one or more water-soluble alkaline earth metal salts selected from the group consisting of magnesium sulfate, magnesium chloride, calcium chloride, strontium chloride and barium chloride, and agitating the mixture under conditions effective to react from 0.07 to 0.3 mole of said alkaline earth metal salt per mole of said sodium percarbonate to form a thin surface layer of alkaline earth metal carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated sodium percarbonate particles.
Claim 11
Dependent Claim
124 words
A process for treating sodium percarbonate particles to stabilize same, which consists essentially of the steps of: adding to an aqueous slurry of preformed particles of sodium percarbonate having a particle size of from 100 to 1,000 microns, a treating agent consisting essentially of one or more water-soluble alkaline earth metal salts selected from the group consisting of magnesium sulfate, magnesium chloride, calcium chloride, strontium chloride and barium chloride, and agitating the mixture under conditions effective to react from 0.07 to 0.3 mole of said alkaline earth metal salt per mole of said sodium percarbonate to form a thin surface layer of alkaline earth metal carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated sodium percarbonate particles.
Claim 12
Dependent Claim
124 words
A process for treating sodium percarbonate particles to stabilize same, which consists essentially of the steps of: adding to an aqueous slurry of preformed particles of sodium percarbonate having a particle size of from 100 to 1,000 microns, a treating agent consisting essentially of one or more water-soluble alkaline earth metal salts selected from the group consisting of magnesium sulfate, magnesium chloride, calcium chloride, strontium chloride and barium chloride, and agitating the mixture under conditions effective to react from 0.07 to 0.3 mole of said alkaline earth metal salt per mole of said sodium percarbonate to form a thin surface layer of alkaline earth metal carbonate on the surfaces of said sodium percarbonate particles; and then separating and drying said surface-treated sodium percarbonate particles.
Claim 13
Dependent Claim
42 words
A process as claimed in claim 4, claim 5 or claim 6 wherein the amount of said alkaline earth metal salt that is reacted with said sodium percarbonate particles is from 0.1 to 0.2 mole per one mole of said sodium percarbonate.
Claim 14
Dependent Claim
16 words
Sodium percarbonate obtained by a process as claimed in claim 4, claim 5 or claim 6.
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JPS4732519U
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US3860694A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-04-19 | 1985-10-19 | 1986-04-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-04-19 | 1989-10-19 | 1990-04-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-04-19 | 1993-10-19 | 1994-04-20 | $7700.00 | Window Closed / Lapsed |