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US4324648A Expired / Lapsed US ⏱️ 0.0 years remaining

Cracking catalyst poisons passivated with tin compounds plus both sulfur and phosphorus

Assignee: Phillips Petroleum Co
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Filing: 1980-03-24
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Granted: 1982-04-13
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Expires: 2000-03-24
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Abstract

Abstract Deposits on a cracking catalyst are passivated by contacting the cracking catalyst with tin and at least one of phosphorus or sulfur.

Inventors

  • 👤 John S. Roberts
  • 👤 Brent J. Bertus
  • 👤 Dwight L. McKay
  • 👤 H. Wayne Mark

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:29
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/90; B01J23/94; B01J23/14; C; C07; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/16; C07F9/165; C07F9/1654; C10; C10G; C10G11/00; C10G11/02; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/584; Y10; Y10S; Y10S502/00; Y10S502/521

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 215 words
In a process comprising: (a) contacting a hydrocarbon feedstock with a fluidized zeolite-containing cracking catalyst in a cracking zone under cracking conditions in the absence of added hydrogen or antimony to obtain a cracked product; (b) recovering the cracked product; (c) passing the cracking catalyst from the cracking zone to a regeneration zone; (d) regenerating the cracking catalyst in the regeneration zone by contact with oxygen-containing gas under regeneration conditions to produce a regenerated catalyst; and (e) introducing the regenerated catalyst to the cracking zone for contact with the hydrocarbon feedstock; wherein the regenerated catalyst contains contaminants selected from the group consisting of nickel, vanadium and iron deposited on said cracking catalyst in such a way that said cracking catalyst cannot be fully regenerated in the regeneration zone, the improvement comprising contacting the cracking catalyst with a treating agent containing tin, phosphorus and sulfur in an amount sufficient to impart to said cracking catalyst a tin concentration of from about 0.0001 to about 4 percent by weight of contacted cracking catalyst wherein the cracking catalyst is contacted with from about one-half to about 8 parts by weight of sulfur and/or from about one quarter to about one part by weight of phosphorus for each part by weight of tin with which it has been contacted.
Claim 2
Dependent Claim 215 words
In a process comprising: (a) contacting a hydrocarbon feedstock with a fluidized zeolite-containing cracking catalyst in a cracking zone under cracking conditions in the absence of added hydrogen or antimony to obtain a cracked product; (b) recovering the cracked product; (c) passing the cracking catalyst from the cracking zone to a regeneration zone; (d) regenerating the cracking catalyst in the regeneration zone by contact with oxygen-containing gas under regeneration conditions to produce a regenerated catalyst; and (e) introducing the regenerated catalyst to the cracking zone for contact with the hydrocarbon feedstock; wherein the regenerated catalyst contains contaminants selected from the group consisting of nickel, vanadium and iron deposited on said cracking catalyst in such a way that said cracking catalyst cannot be fully regenerated in the regeneration zone, the improvement comprising contacting the cracking catalyst with a treating agent containing tin, phosphorus and sulfur in an amount sufficient to impart to said cracking catalyst a tin concentration of from about 0.0001 to about 4 percent by weight of contacted cracking catalyst wherein the cracking catalyst is contacted with from about one-half to about 8 parts by weight of sulfur and/or from about one quarter to about one part by weight of phosphorus for each part by weight of tin with which it has been contacted.
Claim 3
Dependent Claim 43 words
A process as in claim 1 wherein the cracking catalyst is contacted with the treating agent in an amount sufficient to impart to said cracking catalyst a tin concentration of from about 0.001 to about 2 percent by weight of contacted cracking catalyst.
Claim 4
Dependent Claim 37 words
A process as in claim 2 wherein the cracking catalyst is contacted with a treating agent compound having at least one phosphorus atom and at least one sulfur atom located gamma or closer to a tin atom.
Claim 5
Dependent Claim 16 words
A process as in claim 3 wherein the cracking catalyst is contacted with a tin thiophosphate.
Claim 6
Dependent Claim 218 words
In a process comprising: (a) contacting a hydrocarbon feedstock with a fluidized zeolite-containing cracking catalyst in a cracking zone under cracking conditions in the absence of added hydrogen or antimony to obtain a cracked product; (b) recovering the cracked product; (c) passing the cracking catalyst from the cracking zone to a regeneration zone; (d) regenerating the cracking catalyst in the regeneration zone by contact with oxygen-containing gas under regeneration conditions to produce a regenerated catalyst; and (e) introducing the regenerated catalyst to the cracking zone for contact with the hydrocarbon feedstock; wherein the regenerated cracking catalyst contains contaminants selected from the group consisting of nickel, vanadium and iron deposited on said cracking catalyst in such a way that said cracking catalyst cannot be fully regenerated in the regeneration zone, the improvement comprising contacting the cracking catalyst with a treating agent represented by the formula: ##STR3## wherein each R can be the same or different and comprises a hydrocarbyl group having from 1 to about 24 carbon atoms, wherein X is selected from the group consisting of oxygen and sulfur and at least one X is sulfur, and wherein n is 2 or 4 so as to impart to the cracking catalyst a tin concentration of from about 0.0001 to about 4 percent by weight of contacted cracking catalyst.
Claim 7
Dependent Claim 218 words
In a process comprising: (a) contacting a hydrocarbon feedstock with a fluidized zeolite-containing cracking catalyst in a cracking zone under cracking conditions in the absence of added hydrogen or antimony to obtain a cracked product; (b) recovering the cracked product; (c) passing the cracking catalyst from the cracking zone to a regeneration zone; (d) regenerating the cracking catalyst in the regeneration zone by contact with oxygen-containing gas under regeneration conditions to produce a regenerated catalyst; and (e) introducing the regenerated catalyst to the cracking zone for contact with the hydrocarbon feedstock; wherein the regenerated cracking catalyst contains contaminants selected from the group consisting of nickel, vanadium and iron deposited on said cracking catalyst in such a way that said cracking catalyst cannot be fully regenerated in the regeneration zone, the improvement comprising contacting the cracking catalyst with a treating agent represented by the formula: ##STR3## wherein each R can be the same or different and comprises a hydrocarbyl group having from 1 to about 24 carbon atoms, wherein X is selected from the group consisting of oxygen and sulfur and at least one X is sulfur, and wherein n is 2 or 4 so as to impart to the cracking catalyst a tin concentration of from about 0.0001 to about 4 percent by weight of contacted cracking catalyst.
Claim 8
Dependent Claim 41 words
A process as in claim 5 wherein the treating agent is contacted with the cracking catalyst so as to impart to said cracking catalyst a tin concentration of from about 0.001 to about 2 percent by weight of contacted cracking catalyst.
Claim 9
Dependent Claim 41 words
A process as in claim 6 wherein the treating agent is contacted with the cracking catalyst so as to impart to said cracking catalyst a tin concentration of from about 0.005 to about 1 percent by weight of contacted cracking catalyst.
Claim 10
Dependent Claim 41 words
A process as in claim 7 wherein the treating agent is contacted with the cracking catalyst so as to impart to said cracking catalyst a tin concentration of from about 0.01 to about 0.15 percent by weight of contacted cracking catalyst.
Claim 11
Dependent Claim 36 words
A process as in claim 6 wherein said treating agent is represented by the formula ##STR4## wherein R comprises a hydrocarbyl group having from 1 to about 24 carbon atoms and n is 2 or 4.
Claim 12
Dependent Claim 45 words
A process as in claim 9 wherein n equals 2 and R is selected from the group consisting of ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, amyl, n-hexyl, sec-hexyl, n-heptyl, n-octyl, isooctyl, tert-octyl, cyclopentyl, cyclohexyl, dimethylcyclohexyl, diethylcyclohexyl, phenyltolyl, cresyl, ethylphenyl, butylphenyl, amylphenyl, octylphenyl and vinylphenyl.
Claim 13
Dependent Claim 45 words
A process as in claim 9 wherein n equals 4 and R is selected from the group consisting of ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, amyl, n-hexyl, sec-hexyl, n-heptyl, n-octyl, isooctyl, tert-octyl, cyclopentyl, cyclohexyl, dimethylcyclohexyl, diethylcyclohexyl, phenyltolyl, cresyl, ethylphenyl, butylphenyl, amylphenyl, octylphenyl and vinylphenyl.
Claim 14
Dependent Claim 20 words
A process as in claim 9 wherein said treating agent is contacted with the cracking catalyst in the cracking zone.
Claim 15
Dependent Claim 22 words
A process as in claim 12 wherein said treating agent is introduced into said cracking zone in contact with the hydrocarbon feedstock.
Claim 16
Dependent Claim 19 words
A process as in claim 12 wherein said cracking catalyst has deposited thereon at least 5,000 ppm vanadium equivalents.
Claim 17
Dependent Claim 19 words
A process as in claim 14 wherein said cracking catalyst has deposited thereon at least 10,000 ppm vanadium equivalents.
Claim 18
Dependent Claim 42 words
A process as in claim 14 wherein the treating compound is contacted with the cracking catalyst so as to impart to said cracking catalyst a weight ratio of tin to vanadium equivalents on the cracking catalyst of between 0.5:100 to about 50:100.
Claim 19
Dependent Claim 41 words
A process as in claim 16 wherein the treating agent is contacted with the cracking catalyst so as to impart to the cracking catalyst a tin concentration of from about 0.005 to about 1 percent by weight of contacted cracking catalyst.
Claim 20
Dependent Claim 39 words
A process as in claim 17 wherein the treating agent is contacted with the cracking catalyst to impart to the cracking catalyst a tin concentration of from about 0.01 to about 0.15 percent by weight of contacted cracking catalyst.
Claim 21
Dependent Claim 37 words
A process as in claim 18 wherein the treating agent is dissolved in the hydrocarbon feedstock to impart to the feedstock a tin concentration of from about 1 to about 200 parts tin per million parts feedstock.
Claim 22
Dependent Claim 13 words
A process as in claim 19 wherein said treating agent comprises stannic di-n-propylphosphorodithioate.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-04-12 1985-10-12 1986-04-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-04-12 1989-10-12 1990-04-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-04-12 1993-10-12 1994-04-13 $7700.00 Window Closed / Lapsed

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