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US4323709A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of polymeric reaction products of poly(alkoxyalkylene)amines and epihalohydrins

Assignee: Honeywell UOP LLC
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Filing: 1980-10-15
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Granted: 1982-04-06
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Expires: 2000-10-15
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Abstract

Abstract Novel polymeric products are formed in the process which comprises commingling one molar proportion of a poly(oxyalkylene)amine with from about 0.5 to about 2.0 molar proportions of an epihalohydrin. Epichlorohydrin is the epihalohydrin of choice.

Inventors

  • 👤 Gary W. Y. Kwong

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:08
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/222; C10L1/2222; C10L1/2225

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 171 words
The process of making a polymeric reaction product which comprises reacting one molar proportion of a poly(oxyalkylene)amine of the structure A-(R 1 O) n -RNH 2 , wherein (a) R and each R 1 are independently selected from the group consisting of alkylene moieties containing from 2 to about 10 carbon atoms; (b) n is an integer from 2 to about 50; (c) A is selected from the group consiting of H 2 N, alkoxy, where the carbonaceous portion contains from 1 to about 40 carbon atoms, and ##STR3## wherein B is selected from the group consisting of hydrogen and alkyl containing from 1 to about 10 carbon atoms, and y, z are integers from 1 to about 10; with about 0.5 to about 2.0 molar proportions of an epihalohydrin selected from the group consisting of epihalohydrin, 1-halo-3,4-epoxybutane, 1-halo-2,3-epoxybutane, 1-halo-4,5-epoxypentane, and 1-halo-3,4-epoxypentane, at a temperature from about 40° C. to about 150° C., thereafter reacting the resultant adduct with an inorganic base at said temperature, and recovering the polymeric reaction product.
Claim 2
Dependent Claim 171 words
The process of making a polymeric reaction product which comprises reacting one molar proportion of a poly(oxyalkylene)amine of the structure A-(R 1 O) n -RNH 2 , wherein (a) R and each R 1 are independently selected from the group consisting of alkylene moieties containing from 2 to about 10 carbon atoms; (b) n is an integer from 2 to about 50; (c) A is selected from the group consiting of H 2 N, alkoxy, where the carbonaceous portion contains from 1 to about 40 carbon atoms, and ##STR3## wherein B is selected from the group consisting of hydrogen and alkyl containing from 1 to about 10 carbon atoms, and y, z are integers from 1 to about 10; with about 0.5 to about 2.0 molar proportions of an epihalohydrin selected from the group consisting of epihalohydrin, 1-halo-3,4-epoxybutane, 1-halo-2,3-epoxybutane, 1-halo-4,5-epoxypentane, and 1-halo-3,4-epoxypentane, at a temperature from about 40° C. to about 150° C., thereafter reacting the resultant adduct with an inorganic base at said temperature, and recovering the polymeric reaction product.
Claim 3
Dependent Claim 10 words
The process of claim 1 wherein said epihalohydrin is epichlorohydrin.
Claim 4
Dependent Claim 18 words
The process of claim 2 wherein R is selected from the group consisting of ethylene and propylene moieties.
Claim 5
Dependent Claim 21 words
The process of claim 2 wherein each R 1 is independently selected from the group consisting of ethylene and propylene moieties.
Claim 6
Dependent Claim 31 words
The process of claim 2 wherein A is selected from the group consisting of H 2 N and alkoxy, where the carbonaceous portion contains from 1 to about 20 carbon atoms.
Claim 7
Dependent Claim 21 words
The process of claim 2 wherein the temperature is in the range of from about 60° C. to about 120° C.

References Cited (Backward Citations)

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US3257250A Cited
US3499930A Cited
US3424681A Cited
US3636114A Cited
US3567659A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-04-05 1985-10-05 1986-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-04-05 1989-10-05 1990-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-04-05 1993-10-05 1994-04-06 $7700.00 Window Closed / Lapsed

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