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US4322375A Expired / Lapsed US ⏱️ 0.0 years remaining

2-Substituted 5-phenoxyphenylphosphonic acid derivatives

Assignee: Novartis Corp
•
Filing: 1980-01-31
•
Granted: 1982-03-30
•
Expires: 2000-01-31
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Abstract

Abstract The present invention relates to novel herbicidal and plant growth-inhibiting 2-substituted 5-phenoxyphenylphosphonic acid derivatives of the formula ##STR1## wherein each of R 1 and R 2 independently is hydroxyl, lower alkoxy, lower alkylthio, alkylamino, dialkylamino, chlorine, benzyloxy or benzylthio, X is halogen or a --CF 3 , --NO 2 , --CN, --CONH 2 or --CSNH 2 group, n is 0 to 3, and Y is --OH, halogen, NO 2 , --CN, NH 2 , --NHCO--R, --NHCOOR or --NH--SO 2 --R, wherein R is an unsubstituted or halogenated lower alkyl radical. Preferred compounds are 2-nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)-phenylphosphonic acid and the lower dialkyl esters thereof. The invention also relates to the production of the novel phosphonic acid derivatives, starting from a 3,4-dinitrodiphenyl ether and reacting it with a trialkylphosphite as first step. The invention further relates to herbicidal and plant growth-regulating compositions which contain one of the novel compounds as active component, and also to the use of these compounds and compositions for controlling weeds (also selectively), for inhibiting plant growth and desiccating parts of plants above the soil, as well as for totally destroying existing plant growth.

Inventors

  • 👤 Ludwig Maier
  • 👤 Dieter Durr

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 22:22
CPC Classifications
A; A01; A01N; A01N57/00; A01N57/18; A01N57/22; A01N57/26; A01N57/30; A01N57/34; C; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/38; C07F9/3804; C07F9/3834; C07F9/40; C07F9/4003; C07F9/4021; C07F9/42; C07F9/44; C07F9/4403; C07F9/4419

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 39 words
A 5-(2'-halogeno-4'-trifluoromethylphenoxy)-phenylphosphonic acid derivative of the formula ##STR8## wherein each of R 1 and R 2 is hydroxyl, lower alkoxy, lower alkylthio, (lower alkyl) amino, di(lower alkyl) amino, chlorine, benzyloxy or benzylthio, and Y' is halogen, nitro or cyano.
Claim 2
Dependent Claim 39 words
A 5-(2'-halogeno-4'-trifluoromethylphenoxy)-phenylphosphonic acid derivative of the formula ##STR8## wherein each of R 1 and R 2 is hydroxyl, lower alkoxy, lower alkylthio, (lower alkyl) amino, di(lower alkyl) amino, chlorine, benzyloxy or benzylthio, and Y' is halogen, nitro or cyano.
Claim 3
Dependent Claim 12 words
A phosphonic acid derivative according to claim 1, wherein Hal is chlorine.
Claim 4
Dependent Claim 12 words
A phosphonic acid derivative according to claim 1, wherein Y' is nitro.
Claim 5
Dependent Claim 21 words
A 2-nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)phenylphosphonic acid derivative of the formula ##STR9## wherein R 1 and R 2 are C 1 -C 3 alkoxy radicals.
Claim 6
Dependent Claim 21 words
A 2-nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)phenylphosphonic acid derivative of the formula ##STR9## wherein R 1 and R 2 are C 1 -C 3 alkoxy radicals.
Claim 7
Dependent Claim 4 words
2-Nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)phenylphosphonic acid dimethyl ester.
Claim 8
Dependent Claim 4 words
2-Nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)phenylphosphonic acid dimethyl ester.
Claim 9
Dependent Claim 15 words
A phosphonic acid derivative according to claim 1 wherein Y' in formula IV is chlorine.
Claim 10
Dependent Claim 12 words
The compound according to claim 6 which is 2-chloro-5-(2'-chloro-4'-trifluoromethylphenoxy)-phenylphosphonic acid dimethyl ester.

References Cited (Backward Citations)

US3833691A Cited
US3927149A Cited
US4141718A Cited
US4133675A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-03-29 1985-09-28 1986-03-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-03-29 1989-09-28 1990-03-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-03-29 1993-09-28 1994-03-30 $7700.00 Window Closed / Lapsed

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