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US4319974A Expired / Lapsed US ⏱️ 0.0 years remaining

UV Curable compositions and substrates treated therewith

Assignee: General Electric Co
•
Filing: 1980-04-21
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Granted: 1982-03-16
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Expires: 2000-04-21
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Abstract

Abstract UV curable mixtures of C(8-28) alpha -olefin oxides and certain onium salt photoinitiators, for example, certain diaryliodonium salts, or triarylsulfonium salts, and optionally polyfunctional epoxy resin, have been found useful in paper release coating applications.

Inventors

  • 👤 James V. Crivello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 09:56
CPC Classifications
D; D21; D21H; D21H19/00; D21H19/10; D21H19/14; D21H19/16; C; C08; C08G; C08G59/00; C08G59/14; C08G59/1433; C08G59/1438; C08G59/145; C08G59/18; C08G59/20; C08G59/32; C08G59/36; C08G59/68; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/08; C08G65/10; C08G65/105; C09; C09J; C09J7/00; C09J7/40; C09J7/401; D21H27/00; D21H27/001; C09J2400/00; C09J2400/20; C09J2400/28; C09J2400/283; C09J2463/00; C09J2463/005

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 210 words
Curable or polymerizable compositions comprising by weight (A) 15 to 100% of a C.sub.(8-12) α-olefin oxide, (B) 0 to 85% of a polyfunctional epoxy resin, (C) 0.1 to 10% based on the sum of the weight (A), (B) and (C) of an aryl onium salt of the formula, [Y].sup.+ [MQ.sub.n ].sup.-, where Y is a member selected from [(R).sub.a (R.sup.1).sub.b I] and [(R).sub.c (R.sup.2).sub.d (R.sup.3).sub.e S], where R is a monovalent aromatic organic radical, R 1 is a divalent aromatic organic radical, R 2 is a monovalent organic aliphatic radical selected from alkyl, cyano alkyl and substituted alkyl, R 3 is a polyvalent organic radical forming a heterocyclic or fused ring structure, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 or 2, b is a whole number equal to 0 or 1, and the sum of a+b is equal to 1 or 2, c is a whole number equal to 0 to 3 inclusive, d is a whole number equal to 0 to 2 inclusive, e is a whole number equal to 0 or 1, and the sum of c, d and e is equal to 1 to 3 inclusive, and n is an integer equal to 4-6 inclusive.
Claim 2
Dependent Claim 210 words
Curable or polymerizable compositions comprising by weight (A) 15 to 100% of a C.sub.(8-12) α-olefin oxide, (B) 0 to 85% of a polyfunctional epoxy resin, (C) 0.1 to 10% based on the sum of the weight (A), (B) and (C) of an aryl onium salt of the formula, [Y].sup.+ [MQ.sub.n ].sup.-, where Y is a member selected from [(R).sub.a (R.sup.1).sub.b I] and [(R).sub.c (R.sup.2).sub.d (R.sup.3).sub.e S], where R is a monovalent aromatic organic radical, R 1 is a divalent aromatic organic radical, R 2 is a monovalent organic aliphatic radical selected from alkyl, cyano alkyl and substituted alkyl, R 3 is a polyvalent organic radical forming a heterocyclic or fused ring structure, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 or 2, b is a whole number equal to 0 or 1, and the sum of a+b is equal to 1 or 2, c is a whole number equal to 0 to 3 inclusive, d is a whole number equal to 0 to 2 inclusive, e is a whole number equal to 0 or 1, and the sum of c, d and e is equal to 1 to 3 inclusive, and n is an integer equal to 4-6 inclusive.
Claim 3
Dependent Claim 15 words
A curable composition in accordance with claim 1, where the C.sub.(8-28) α-olefin oxide is 1,2-epoxydodecene.
Claim 4
Dependent Claim 15 words
A curable mixture in accordance with claim 1, where the epoxy resin is 3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexane carboxylate.
Claim 5
Dependent Claim 17 words
A curable composition in accordance with claim 1, where the aryl onium salt is 4,4'-di-t-butyl diphenyliodonium hexafluoroantimonate.

References Cited (Backward Citations)

US4058401A Cited
US4161405A Cited
US4173551A Cited
US3981897A Cited
US4159975A Cited
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US4230814A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-03-15 1985-09-14 1986-03-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-03-15 1989-09-14 1990-03-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-03-15 1993-09-14 1994-03-16 $7700.00 Window Closed / Lapsed

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