US4319974A
Expired / Lapsed
US
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UV Curable compositions and substrates treated therewith
Assignee: General Electric Co
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Filing: 1980-04-21
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Granted: 1982-03-16
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Expires: 2000-04-21
Abstract
Abstract UV curable mixtures of C(8-28) alpha -olefin oxides and certain onium salt photoinitiators, for example, certain diaryliodonium salts, or triarylsulfonium salts, and optionally polyfunctional epoxy resin, have been found useful in paper release coating applications.
Inventors
- 👤 James V. Crivello
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 09:56
CPC Classifications
D; D21; D21H; D21H19/00; D21H19/10; D21H19/14; D21H19/16; C; C08; C08G; C08G59/00; C08G59/14; C08G59/1433; C08G59/1438; C08G59/145; C08G59/18; C08G59/20; C08G59/32; C08G59/36; C08G59/68; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/08; C08G65/10; C08G65/105; C09; C09J; C09J7/00; C09J7/40; C09J7/401; D21H27/00; D21H27/001; C09J2400/00; C09J2400/20; C09J2400/28; C09J2400/283; C09J2463/00; C09J2463/005
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
210 words
Curable or polymerizable compositions comprising by weight (A) 15 to 100% of a C.sub.(8-12) α-olefin oxide, (B) 0 to 85% of a polyfunctional epoxy resin, (C) 0.1 to 10% based on the sum of the weight (A), (B) and (C) of an aryl onium salt of the formula, [Y].sup.+ [MQ.sub.n ].sup.-, where Y is a member selected from [(R).sub.a (R.sup.1).sub.b I] and [(R).sub.c (R.sup.2).sub.d (R.sup.3).sub.e S], where R is a monovalent aromatic organic radical, R 1 is a divalent aromatic organic radical, R 2 is a monovalent organic aliphatic radical selected from alkyl, cyano alkyl and substituted alkyl, R 3 is a polyvalent organic radical forming a heterocyclic or fused ring structure, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 or 2, b is a whole number equal to 0 or 1, and the sum of a+b is equal to 1 or 2, c is a whole number equal to 0 to 3 inclusive, d is a whole number equal to 0 to 2 inclusive, e is a whole number equal to 0 or 1, and the sum of c, d and e is equal to 1 to 3 inclusive, and n is an integer equal to 4-6 inclusive.
Claim 2
Dependent Claim
210 words
Curable or polymerizable compositions comprising by weight (A) 15 to 100% of a C.sub.(8-12) α-olefin oxide, (B) 0 to 85% of a polyfunctional epoxy resin, (C) 0.1 to 10% based on the sum of the weight (A), (B) and (C) of an aryl onium salt of the formula, [Y].sup.+ [MQ.sub.n ].sup.-, where Y is a member selected from [(R).sub.a (R.sup.1).sub.b I] and [(R).sub.c (R.sup.2).sub.d (R.sup.3).sub.e S], where R is a monovalent aromatic organic radical, R 1 is a divalent aromatic organic radical, R 2 is a monovalent organic aliphatic radical selected from alkyl, cyano alkyl and substituted alkyl, R 3 is a polyvalent organic radical forming a heterocyclic or fused ring structure, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 or 2, b is a whole number equal to 0 or 1, and the sum of a+b is equal to 1 or 2, c is a whole number equal to 0 to 3 inclusive, d is a whole number equal to 0 to 2 inclusive, e is a whole number equal to 0 or 1, and the sum of c, d and e is equal to 1 to 3 inclusive, and n is an integer equal to 4-6 inclusive.
Claim 3
Dependent Claim
15 words
A curable composition in accordance with claim 1, where the C.sub.(8-28) α-olefin oxide is 1,2-epoxydodecene.
Claim 4
Dependent Claim
15 words
A curable mixture in accordance with claim 1, where the epoxy resin is 3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexane carboxylate.
Claim 5
Dependent Claim
17 words
A curable composition in accordance with claim 1, where the aryl onium salt is 4,4'-di-t-butyl diphenyliodonium hexafluoroantimonate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-03-15 | 1985-09-14 | 1986-03-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-03-15 | 1989-09-14 | 1990-03-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-03-15 | 1993-09-14 | 1994-03-16 | $7700.00 | Window Closed / Lapsed |