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US4316951A Expired / Lapsed US ⏱️ 0.0 years remaining

Multilayer photosensitive element with solvent-soluble layer

Assignee: EIDP Inc
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Filing: 1980-08-18
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Granted: 1982-02-23
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Expires: 2000-08-18
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Abstract

Abstract An improved peel apart photosensitive element for producing duplicate solvent-developed images comprising a strippable cover sheet, a photoadherent layer, a solvent-soluble, nontonable, polymeric nonphotosensitive contiguous layer and a support for photomechanical applications.

Inventors

  • 👤 Abraham B. Cohen
  • 👤 Roxy N. Fan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:35
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/34; G03F3/00; G03F3/10; G03F3/106

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 272 words
A peel apart photosensitive element comprising, in order, from top to bottom (1) a strippable cover sheet, (2) a photoadherent layer coated on cover sheet (1) comprising a material with ethylenically unsaturated or benzophenone type groups, a polymeric binder and a photoinitiating system, (3) a solvent-soluble, nontonable, polymeric, nonphotosensitive contiguous layer, and (4) a sheet support, the unexposed element having the following force relationship: C>A 1 <<A 2 wherein C represents the cohesive value of the unexposed photoadherent layer (2); A 1 represents the adhesive force between cover sheet (1) and unexposed photoadherent layer (2); and A 2 represents the adhesive force between unexposed photoadherent layer (2) and contiguous layer (3); the exposed areas (5) of said photoadherent layer, after imagewise exposure through the cover sheet (1) of said element to actinic radiation, having greater adhesion to said cover sheet than to said contiguous layer, and are completely removable with said cover sheet and the unexposed areas (6) of said photoadherent layer having greater adhesion to said contiguous layer than to said cover sheet, the exposed element having the following force relationship: C<A 1 *>>A 2 *<C* wherein C is as defined above; A 1 * represents the adhesive force between exposed areas (5) of photoadherent layer (2) and cover sheet (1); A 2 * represents the adhesive force between exposed areas (5) and contiguous layer (3); and C* represents the cohesive value of the photoadherent layer in the exposed areas (5); the areas of the photoadherent layer remaining on the contiguous layer after stripping off the cover sheet must be insoluble under a condition under which the contiguous layer is soluble.
Claim 2
Dependent Claim 272 words
A peel apart photosensitive element comprising, in order, from top to bottom (1) a strippable cover sheet, (2) a photoadherent layer coated on cover sheet (1) comprising a material with ethylenically unsaturated or benzophenone type groups, a polymeric binder and a photoinitiating system, (3) a solvent-soluble, nontonable, polymeric, nonphotosensitive contiguous layer, and (4) a sheet support, the unexposed element having the following force relationship: C>A 1 <<A 2 wherein C represents the cohesive value of the unexposed photoadherent layer (2); A 1 represents the adhesive force between cover sheet (1) and unexposed photoadherent layer (2); and A 2 represents the adhesive force between unexposed photoadherent layer (2) and contiguous layer (3); the exposed areas (5) of said photoadherent layer, after imagewise exposure through the cover sheet (1) of said element to actinic radiation, having greater adhesion to said cover sheet than to said contiguous layer, and are completely removable with said cover sheet and the unexposed areas (6) of said photoadherent layer having greater adhesion to said contiguous layer than to said cover sheet, the exposed element having the following force relationship: C<A 1 *>>A 2 *<C* wherein C is as defined above; A 1 * represents the adhesive force between exposed areas (5) of photoadherent layer (2) and cover sheet (1); A 2 * represents the adhesive force between exposed areas (5) and contiguous layer (3); and C* represents the cohesive value of the photoadherent layer in the exposed areas (5); the areas of the photoadherent layer remaining on the contiguous layer after stripping off the cover sheet must be insoluble under a condition under which the contiguous layer is soluble.
Claim 3
Dependent Claim 14 words
An element according to claim 1 wherein said contiguous layer contains an added colorant.
Claim 4
Dependent Claim 27 words
An element according to claim 1 wherein said strippable cover sheet is an electrostatic discharge or flame surface treated polymeric film which is transparent to actinic radiation.
Claim 5
Dependent Claim 16 words
An element according to claim 3 wherein said strippable cover sheet is a polyethylene terephthalate film.
Claim 6
Dependent Claim 23 words
An element according to claim 1 wherein said contiguous layer is comprised of a polymeric material that is soluble in an aqueous solution.
Claim 7
Dependent Claim 14 words
An element according to claim 1 wherein said photoadherent layer contains an added colorant.
Claim 8
Dependent Claim 19 words
An element according to claim 2 wherein said colored contiguous layer has an optical density of at least 3.0.
Claim 9
Dependent Claim 21 words
An element according to claim 1 containing an auxiliary layer interposed between the contiguous layer (3) and the sheet support (4).
Claim 10
Dependent Claim 14 words
An element according to claim 8 wherein the auxiliary layer is a release layer.
Claim 11
Dependent Claim 14 words
An element according to claim 8 wherein the auxiliary layer is an anchoring layer.
Claim 12
Dependent Claim 12 words
An element according to claim 8 wherein the auxiliary layer is thermoplastic.
Claim 13
Dependent Claim 24 words
An element according to claim 1 wherein the sheet support (4) has a metal surface in contact with the surface of said contiguous layer.
Claim 14
Dependent Claim 12 words
An element according to claim 12 wherein the metal surface is copper.
Claim 15
Dependent Claim 13 words
An element according to claim 1 wherein the sheet support (4) is transparent.
Claim 16
Dependent Claim 15 words
An element according to claim 1 wherein the sheet support (4) is a polymeric film.
Claim 17
Dependent Claim 13 words
An element according to claim 15 wherein the polymeric film is polyethylene terephthalate.
Claim 18
Dependent Claim 15 words
An element according to claim 1 wherein the sheet support (4) contains an added colorant.
Claim 19
Dependent Claim 28 words
An element according to claim 17 wherein the colored sheet support has an optical density of at least 3 over a portion of the visible or actinic spectrum.

References Cited (Backward Citations)

US3241973A Cited
US3375112A Cited
US3359107A Cited
US3891441A Cited
US3754920A Cited
US3793017A Cited
NL7413916A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-22 1985-08-24 1986-02-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-22 1989-08-24 1990-02-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-22 1993-08-24 1994-02-23 $7700.00 Window Closed / Lapsed

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