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US4316836A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized fluoroelastomer compositions

Assignee: EIDP Inc
•
Filing: 1980-04-23
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Granted: 1982-02-23
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Expires: 2000-04-23
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Abstract

Abstract Vulcanizates of certain fluoroelastomer terpolymer compositions, wherein the terpolymer is derived from tetrafluoroethylene, perfluoro(methyl vinyl ether), and a cure-site monomer, and further wherein the composition contains non-black filler, exhibit significantly improved stability upon heat aging when small quantities of quinacridone-type pigments are incorporated therein.

Inventors

  • 👤 Carl A. Aufdermarsh, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 04:01
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3437

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 63 words
A vulcanizable composition comprising a fluoroelastomer which is a terpolymer derived from tetrafluoroethylene, perfluoromethyl perfluorovinyl ether and a cure-site monomer, at least one non-black filler, and a small quantity of at least one quinacridone-type pigment selected from the group consisting of quinacridone, quinacridone quinone, substituted quinacridone, substituted quinacridone quinone, and mixtures and solid solutions of such substituted and unsubstituted quinacridones and quinacridone quinones.
Claim 2
Dependent Claim 63 words
A vulcanizable composition comprising a fluoroelastomer which is a terpolymer derived from tetrafluoroethylene, perfluoromethyl perfluorovinyl ether and a cure-site monomer, at least one non-black filler, and a small quantity of at least one quinacridone-type pigment selected from the group consisting of quinacridone, quinacridone quinone, substituted quinacridone, substituted quinacridone quinone, and mixtures and solid solutions of such substituted and unsubstituted quinacridones and quinacridone quinones.
Claim 3
Dependent Claim 35 words
A composition of claim 1 wherein the cure-site monomer is selected from the group consisting of: (a) perfluoro(4-cyanobutyl vinyl ether), (b) perfluoro(4-carbomethoxybutyl vinyl ether), (c) perfluoro(2-phenoxypropyl vinyl ether), (d) perfluoro(3-phenoxypropyl vinyl ether), and (e) perfluoro(8-cyano-5-methyl-3,6-dioxa-1-octene).
Claim 4
Dependent Claim 31 words
A composition of claim 1 wherein the terpolymer consists essentially of 53-79.8 mole percent of tetrafluoroethylene, 20-45 mole percent of perfluoromethyl perfluorovinyl ether and 0.2-2 mole percent of the cure-site monomer.
Claim 5
Dependent Claim 31 words
A composition of claim 2 wherein the terpolymer consists essentially of 53-79.8 mole percent of tetrafluoroethylene, 20-45 mole percent of perfluoromethyl perfluorovinyl ether and 0.2-2 mole percent of the cure-site monomer.
Claim 6
Dependent Claim 13 words
A composition of claim 2 wherein the cure-site monomer is perfluoro(2-phenoxypropyl vinyl ether).
Claim 7
Dependent Claim 31 words
A composition of claim 5 wherein the terpolymer consists essentially of 65.4-73.6 mole percent of tetrafluoroethylene, 26-34 mole percent of perfluoromethyl perfluorovinyl ether and 0.5 mole percent of perfluoro(2-phenoxypropyl vinyl ether).
Claim 8
Dependent Claim 27 words
A composition of claim 1 wherein the non-black filler is selected from the group consisting of titanium dioxide, zirconium dioxide, silica, clay asbestos and hydrated aluminum oxide.
Claim 9
Dependent Claim 12 words
A composition of claim 7 wherein the non-black filler is titanium dioxide.
Claim 10
Dependent Claim 30 words
A composition of claim 1 wherein the quinacridone-type pigment is selected from the group consisting of quinacridone, quinacridone quinone, substituted quinacridone, substituted quinacridone quinone, and mixtures and solid solutions thereof.
Claim 11
Dependent Claim 15 words
A composition of claim 9 wherein the quinacridone-type pigment is a solid solution containing quinacridone.
Claim 12
Dependent Claim 19 words
A composition of claim 1 wherein quinacridone-type pigment is present in the composition in an amount of 0.1-10 phr.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-22 1985-08-24 1986-02-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-22 1989-08-24 1990-02-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-22 1993-08-24 1994-02-23 $7700.00 Window Closed / Lapsed

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