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US4316004A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing oxybenzoyl copolyesters

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1980-04-25
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Granted: 1982-02-16
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Expires: 2000-04-25
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Abstract

Abstract A process for producing oxybenzoyl copolyesters comprising 3 to 300 of repeating unit of the formula, ##STR1## wherein m and n are each 0 or 1, and W is --O--, --SO 2 --, --S-- or --CO--, which comprises reacting a compound of the formula, ##STR2## wherein R 1 is a hydrogen atom, a benzyl, lower alkyl or phenyl group, and Y is a hydrogen atom or a lower alkanoyl group, with a compound of the formula, ##STR3## wherein X is a halogen atom, in the presence of an aliphatic, alicyclic or aromatic hydrocarbon solvent having a boiling point of 100° to 260° C. under atmospheric pressure to produce bis(carboxyphenyl)phthalate, adding a compound of the formula, ##STR4## wherein W is --O--, --SO 2 --, --S-- or --CO--, Z is a hydrogen atom or an alkanoyl group, and m and n are each 0 or 1, and optionally a compound of the formula, ##STR5## wherein R 2 and R 3 are each a hydrogen atom, a benzyl, lower alkyl or phenyl group, and carrying out polycondensation with the removal of the solvent and byproducts so that the polycondensation system is made substantially free from the solvent at least at the end of the polycondensation to carry out substantial bulk polycondensation.

Inventors

  • 👤 Shozaburo Imai
  • 👤 Hiroaki Sugimoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:01
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/66; C08G63/02; C08G63/60; C08G63/605; C08G63/68; C08G63/688

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 236 words
A process for producing oxybenzoyl copolyesters comprising 3 to 300 of at least a portion of a repeating unit of the formula, ##STR11## wherein m and n are each 0 or 1, and W is --O--, --SO 2 --, --S--, or --CO--, which comprises reacting at least a portion of the amount present of a compound of the formula (II), ##STR12## wherein R 1 is a hydrogen atom, a benxyl, lower alkyl or phenyl group, and Y is a hydrogen atom or a lower alkanoyl group, with at least a portion of the amount present of a compound of the formula (III), ##STR13## wherein X is a halogen atom, in the presence of an aliphatic, alicyclic or aromatic hydrocarbon solvent having a boiling point of 100° to 260° C. under atmospheric pressure to produce bis(carboxyphenyl)phthalate, adding a compound of the formula (V), ##STR14## wherein W is --O--, --SO 2 --, --S-- or --CO--, Z is a hydrogen atom or an alkanoyl group, and m and n are each 0 or 1, and optionally a compound of the formula (IV), ##STR15## wherein R 2 and R 3 are each a hydrogen atom, a benzyl, lower alkyl or phenyl group, and carrying out polycondensation with the removal of the solvent and by-products so that the polymerization system is made substantially free from the solvent at least at the end of the polycondensation to carry out substantial bulk polycondensation.
Claim 2
Dependent Claim 236 words
A process for producing oxybenzoyl copolyesters comprising 3 to 300 of at least a portion of a repeating unit of the formula, ##STR11## wherein m and n are each 0 or 1, and W is --O--, --SO 2 --, --S--, or --CO--, which comprises reacting at least a portion of the amount present of a compound of the formula (II), ##STR12## wherein R 1 is a hydrogen atom, a benxyl, lower alkyl or phenyl group, and Y is a hydrogen atom or a lower alkanoyl group, with at least a portion of the amount present of a compound of the formula (III), ##STR13## wherein X is a halogen atom, in the presence of an aliphatic, alicyclic or aromatic hydrocarbon solvent having a boiling point of 100° to 260° C. under atmospheric pressure to produce bis(carboxyphenyl)phthalate, adding a compound of the formula (V), ##STR14## wherein W is --O--, --SO 2 --, --S-- or --CO--, Z is a hydrogen atom or an alkanoyl group, and m and n are each 0 or 1, and optionally a compound of the formula (IV), ##STR15## wherein R 2 and R 3 are each a hydrogen atom, a benzyl, lower alkyl or phenyl group, and carrying out polycondensation with the removal of the solvent and by-products so that the polymerization system is made substantially free from the solvent at least at the end of the polycondensation to carry out substantial bulk polycondensation.
Claim 3
Dependent Claim 23 words
A method according to claim 1, wherein said oxybenzoyl copolyesters contain at least 50 mole % of the structure of the formula (I).
Claim 4
Dependent Claim 23 words
A method according to claim 2, wherein said oxybenzoyl copolyesters contain at least 70 mole % of the structure of the formula (I).
Claim 5
Dependent Claim 25 words
A method according to claim 1, wherein the boiling point of the solvent is within a range of 120° to 230° C. under atmospheric pressure.
Claim 6
Dependent Claim 50 words
A method according to claim 4, wherein the solvent is a member selected from the group consisting of ethylbenzene, xylene, cumene, n-propylbenzene, p-diethylbenzene, o-, m-, and p-cymene, n-butylbenzene, o-, m-, and p-ethyltoluene, 1,2,3,4-tetramethylbenzene, 1,2,3,5-tetramethylbenzene, 1,2,4,5-tetramethylbenzene, 1-methylanthracene, indane, β-ethylnaphthalene, biphenyl, octane, cyclooctane, nonane, decane, undecane, dodecane, tridecane, tetradecane, α-methylnaphthalene and β-methyl-naphthalene.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-15 1985-08-17 1986-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-15 1989-08-17 1990-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-15 1993-08-17 1994-02-16 $7700.00 Window Closed / Lapsed

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