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US4316002A Expired / Lapsed US ⏱️ 0.0 years remaining

Molding compositions comprised of polyimide/N-vinylpyrrolidone prepolymer and epoxy resin

Assignee: BASF Corp
•
Filing: 1979-10-23
•
Granted: 1982-02-16
•
Expires: 1999-10-23
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Abstract

Abstract Novel thermosetting compositions, including a polyimide/N-vinylpyrrolidone prepolymer, optionally comprising an unsaturated polyester, and an epoxy resin, are well adapted for the molding of a variety of useful shaped articles.

Inventors

  • 👤 Robert Cassat
  • 👤 Gerard Guillot

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:24
CPC Classifications
C; C08; C08L; C08L63/00; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G59/44; C08G59/442; C08G59/46; C08G59/48; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31721; Y10T428/31786

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 99 words
A composition of matter comprising (i) a prepolymer consisting essentially of a reaction product obtained by reacting (a) a polyimide having the structural formula: ##STR6## wherein D is selected from the group consisting of ##STR7## wherein Y is selected from the group consisting of H, CH 3 , and Cl, m is 0, 1 or 2, R is an organic radical of valency n, containing from 2 to 50 carbon atoms, and n is a number having an average value between 2 and 5, and (b) N-vinyl-2-pyrrolidone; and (ii) an epoxy resin having at least one 1,2 epoxy group.
Claim 2
Dependent Claim 99 words
A composition of matter comprising (i) a prepolymer consisting essentially of a reaction product obtained by reacting (a) a polyimide having the structural formula: ##STR6## wherein D is selected from the group consisting of ##STR7## wherein Y is selected from the group consisting of H, CH 3 , and Cl, m is 0, 1 or 2, R is an organic radical of valency n, containing from 2 to 50 carbon atoms, and n is a number having an average value between 2 and 5, and (b) N-vinyl-2-pyrrolidone; and (ii) an epoxy resin having at least one 1,2 epoxy group.
Claim 3
Dependent Claim 19 words
The composition of matter as defined by claim 1, further comprising (iii) a hardening agent for the epoxy resin.
Claim 4
Dependent Claim 31 words
The composition of matter as defined by claim 2, wherein the prepolymer (i) comprises from 5 to 95% by weight of the total amount of prepolymer (i) and epoxy resin (ii).
Claim 5
Dependent Claim 31 words
The composition of matter as defined by claim 3, wherein the prepolymer (i) comprises from 20 to 80% by weight of the total amount of prepolymer (i) and epoxy resin (ii).
Claim 6
Dependent Claim 61 words
The composition of matter as defined by claim 3, wherein the polyimide (a) has the structural formula: ##STR8## wherein L is a divalent radical selected from the group consisting of cyclohexylene, phenylene and radicals having the structural formula: ##STR9## wherein T is selected from the group consisting of --CH 2 --, --C(CH 3 ) 2 --, --O-- and --SO 2 --.
Claim 7
Dependent Claim 15 words
The composition of matter as defined by claim 5, wherein the polyimide (a) is N,N',4,4'-diphenylmethane-bis-maleimide.
Claim 8
Dependent Claim 17 words
The composition of matter as defined by claim 5, further comprising a reinforcing amount of a filler.
Claim 9
Dependent Claim 25 words
The composition of matter as defined by claim 5, wherein the epoxy resin (ii) is the glycidyl ethers of a poly(hydroxyphenyl)alkane or phenol- formaldehyde resin.
Claim 10
Dependent Claim 17 words
The composition of matter as defined by claim 2, wherein said composition is in a hardened state.
Claim 11
Dependent Claim 13 words
A shaped article comprising the composition of matter as defined by claim 2.
Claim 12
Dependent Claim 13 words
A shaped article comprising the composition of matter as defined by claim 9.
Claim 13
Dependent Claim 17 words
The composition of matter as defined by claim 2 wherein said hardening agent comprises BF 3 .

References Cited (Backward Citations)

US4035345A Cited
US4005154A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-15 1985-08-17 1986-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-15 1989-08-17 1990-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-15 1993-08-17 1994-02-16 $7700.00 Window Closed / Lapsed

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