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US4315784A Expired / Lapsed US ⏱️ 0.0 years remaining

Water-in-oil emulsion explosive composition with imidazoline derivative emulsifier

Assignee: NOF Corp
•
Filing: 1979-11-27
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Granted: 1982-02-16
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Expires: 1999-11-27
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Abstract

Abstract A water-in-oil emulsion explosive composition consisting of ammonium nitrate or a mixture of ammonium nitrate and the other inorganic oxidizer salts, water, oil and/or wax, 1-hydroxyethyl-2-imidazoline derivative as an emulsifier and at least one of hollow microsphere and bubbles generated from a chemical foaming agent is excellent in the emulsion stability in storage, low temperature detonability and explosion reactivity.

Inventors

  • 👤 Katsuhide Hattori
  • 👤 Yoshiaki Fukatsu
  • 👤 Masao Takahashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:20
CPC Classifications
C; C06; C06B; C06B47/00; C06B47/14; C06B47/145

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 72 words
A water-in-oil emulsion explosive composition consisting of (a) ammonium nitrate or a mixture of ammonium nitrate with at least one other inorganic oxidizer salt, (b) water, (c) an oil and/or wax, (d) an emulsifier of 1-hydroxyethyl-2-imidazoline derivative represented by the following general formula ##STR2## wherein R represents an alkyl or alkenyl group having 10-26 carbon atoms, and (e) at least one of bubbles generated from a chemical foaming agent and hollow microspheres.
Claim 2
Dependent Claim 72 words
A water-in-oil emulsion explosive composition consisting of (a) ammonium nitrate or a mixture of ammonium nitrate with at least one other inorganic oxidizer salt, (b) water, (c) an oil and/or wax, (d) an emulsifier of 1-hydroxyethyl-2-imidazoline derivative represented by the following general formula ##STR2## wherein R represents an alkyl or alkenyl group having 10-26 carbon atoms, and (e) at least one of bubbles generated from a chemical foaming agent and hollow microspheres.
Claim 3
Dependent Claim 28 words
A water-in-oil emulsion explosive composition as claimed in claim 1, wherein the other inorganic oxidizer salts are sodium nitrate, potassium nitrate, calcium nitrate, sodium chlorate and sodium perchlorate.
Claim 4
Dependent Claim 27 words
A water-in-oil emulsion explosive composition as claimed in claim 1, wherein the oil and/or wax is light oil, heavy oil, paraffin wax, petrolatum wax or microcrystalline wax.
Claim 5
Dependent Claim 21 words
A water-in-oil emulsion explosive composition as claimed in claim 1, wherein said emulsifier is 1-hydroxyethyl-2-alkyl(rice bran oil)-2-imidazoline, 1-hydroxyethyl-2-alkyl-(coconut oil)-imidazoline or 1-hydroxyethyl-2-alkyl(tallow)-2-imidazoline.
Claim 6
Dependent Claim 29 words
A water-in-oil emulsion explosive composition as claimed in claim 1, wherein the hollow microsphere is glass hollow microsphere, synthetic resin hollow microsphere, silica hollow microsphere or shirasu hollow microsphere.
Claim 7
Dependent Claim 31 words
A water-in-oil emulsion explosive composition as claimed in claim 1, wherein the chemical foaming agent is a mixture of alkali metal borohydride or sodium nitrite with urea, N,N'-dinitrosopentamethylenetetramine, azodicarbonamide or azobisisobutyronirile.
Claim 8
Dependent Claim 77 words
A water-in-oil emulsion explosive composition as claimed in claim 1, wherein the amount of ammonium nitrate or the mixture of ammonium nitrate and the other inorganic oxidizer salts is 50-90% by weight, that of water is 5-20% by weight, that of the oil and/or wax is 2-7% by weight, that of the emulsifier is 1-5% by weight, that of the hollow miscrosphere is 1-10% by weight and that of the chemical foaming agent is 0.1-2% by weight.

References Cited (Backward Citations)

US3770522A Cited
US4008108A Cited
US4104092A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-15 1985-08-17 1986-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-15 1989-08-17 1990-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-15 1993-08-17 1994-02-16 $7700.00 Window Closed / Lapsed

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