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US4315084A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyphenylene ether molding compositions that include an alkenyl aromatic resin and EPDM rubber

Assignee: General Electric Co
•
Filing: 1980-01-14
•
Granted: 1982-02-09
•
Expires: 2000-01-14
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Abstract

Abstract Novel molding compositions are disclosed which comprise a polyphenylene ether resin, an alkenyl aromatic resin and EPDM rubber.

Inventors

  • 👤 Glenn D. Cooper
  • 👤 Gim F. Lee, Jr.
  • 👤 Rainey A. Shufelt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 03:25
CPC Classifications
C; C08; C08L; C08L25/00; C08L51/00; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L23/00; C08L23/02; C08L23/16; C08L81/00

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 29 words
A thermoplastic molding composition which comprises: (a) a polyphenylene ether resin; (b) an alkenyl aromatic resin; and (c) a rubbery interpolymer of a mixture of mono-olefins and a polyene.
Claim 2
Dependent Claim 29 words
A thermoplastic molding composition which comprises: (a) a polyphenylene ether resin; (b) an alkenyl aromatic resin; and (c) a rubbery interpolymer of a mixture of mono-olefins and a polyene.
Claim 3
Dependent Claim 102 words
A thermoplastic molding composition as defined in claim 1 wherein the polyphenylene ether has units of the formula: ##STR6## wherein Q is selected from the group consisting of hydrogen, hydrocarbon radicals, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, Q' and Q" are the same as Q and in addition halogen with the proviso that Q and Q' are both free of a tertiary carbon atom and n is an integer of at least 50.
Claim 4
Dependent Claim 105 words
A thermoplastic molding composition as defined in claim 2 wherein the alkenyl aromatic resin has at least 25% of its units derived from an alkenyl atomatic monomer of the formula: ##STR7## wherein R 1 and R 2 are selected from the group consisting of hydrogen and lower alkyl or alkenyl groups of from 1 to 6 carbon atoms; R 3 , R 4 and R 5 are selected from the group consisting of chloro, bromo, hydrogen and lower alkyl group of from 1 to 6 carbon atoms; and R 6 and R 7 may be concatenated together with hydrocarbyl groups to form a naphthyl group.
Claim 5
Dependent Claim 45 words
A thermoplastic molding composition as defined in claim 3 wherein the alkenyl aromatic resin is modified by interpolymerization with a rubber selected from the group consisting of polybutadiene rubber, butyl rubber, natural rubber, polysulfide rubber, EPDM rubber, styrene-butadiene rubber, propylene oxide, acrylonitrile rubber and ethylene-propylene.
Claim 6
Dependent Claim 22 words
A thermoplastic molding composition as defined in claim 4 wherein the modified alkenyl aromatic resin is a rubber modified high impact polystyrene.
Claim 7
Dependent Claim 19 words
A thermoplastic molding composition as defined in claim 5 wherein the polyphenylene ether resin is a poly(2,6-dimethyl-1,4-phenylene) ether resin.
Claim 8
Dependent Claim 50 words
A thermoplastic molding composition as defined in claim 6 where the rubbery interpolymer is 10-90 mole percent of ethylene; 10-90 mole percent of an alpha olefin containing 3-16 carbon atoms and 1-15 mole percent of a polyene that is a non-conjugated cyclic or open chain diene of from 5-20 atoms.
Claim 9
Dependent Claim 20 words
A thermoplastic molding composition as defined in claim 7 wherein the rubbery interpolymer is derived from ethylene, propylene and hexadiene.
Claim 10
Dependent Claim 55 words
A thermoplastic molding composition which comprises: (a) from 10 to 90 parts by weight of a polyphenylene ether resin; (b) from 90 to 10 parts by weight of a rubbery modified alkenyl aromatic resin; and (c) from 1 to 15 parts by weight of a rubbery interpolymer of a mixture of mono-olefins and a polyene.
Claim 11
Dependent Claim 55 words
A thermoplastic molding composition which comprises: (a) from 10 to 90 parts by weight of a polyphenylene ether resin; (b) from 90 to 10 parts by weight of a rubbery modified alkenyl aromatic resin; and (c) from 1 to 15 parts by weight of a rubbery interpolymer of a mixture of mono-olefins and a polyene.
Claim 12
Dependent Claim 41 words
A thermoplastic molding composition as defined in claim 9 wherein the polyphenylene ether resin is a poly(2,6-dimethyl-1,4-phenylene) ether resin; the rubber modified alkenyl aromatic resin is polybutadiene high impact polystyrene and the rubbery interpolymer is derived from ethylene, propylene and 1,4-hexadiene.
Claim 13
Dependent Claim 18 words
A thermoplastic molding composition as defined in claim 1 which includes a reinforcing amount of a reinforcing filler.
Claim 14
Dependent Claim 20 words
A thermoplastic molding composition as defined in claim 11 which includes a flame retardant amount of a flame retardant agent.
Claim 15
Dependent Claim 20 words
A thermoplastic molding composition as defined in claim 1 which includes a flame retardant amount of a flame retardant agent.
Claim 16
Dependent Claim 20 words
A thermoplastic molding composition as defined in claim 7 wherein the rubbery interpolymer is derived from ethylene, propylene and 5-ethylidene-2-norbornene.
Claim 17
Dependent Claim 40 words
A thermoplastic molding composition as defined in claim 9 wherein the polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether resin; the rubber modified alkenyl aromatic resin is polybutadiene high impact polystyrene and the rubbery interpolymer is derived from ethylene, propylene and 5-ethylidene-2-norbornene.
Claim 18
Dependent Claim 52 words
A thermoplastic molding composition which comprises: (a) from 40 to 65 parts by weight of poly(2,6-dimethyl-1,4-phenylene) ether resin; (b) from 35 to 60 parts by weight of a rubber modified alkenyl aromatic resin; and (c) from 2 to 10 parts by weight of a rubbery interpolymer derived from ethylene, propylene and 5-ethylene-2-norborene.
Claim 19
Dependent Claim 52 words
A thermoplastic molding composition which comprises: (a) from 40 to 65 parts by weight of poly(2,6-dimethyl-1,4-phenylene) ether resin; (b) from 35 to 60 parts by weight of a rubber modified alkenyl aromatic resin; and (c) from 2 to 10 parts by weight of a rubbery interpolymer derived from ethylene, propylene and 5-ethylene-2-norborene.

References Cited (Backward Citations)

US3383435A Cited
CS165110B1 Cited
US3981341A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-08 1985-08-10 1986-02-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-08 1989-08-10 1990-02-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-08 1993-08-10 1994-02-09 $7700.00 Window Closed / Lapsed

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