US4314875A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Device fabrication by plasma etching
Assignee: AT&T Inc
•
Filing: 1980-05-13
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Granted: 1982-02-09
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Expires: 2000-05-13
Abstract
Abstract Etch rate in plasma-assisted etching is increased by inclusion of an additional oxidant. The oxidant increases consumption of unsaturates in the plasma to increase etchant species lifetime and to suppress polymer formation.
Inventors
- 👤 Daniel L. Flamm
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 10:16
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/28; H10P50/286; H10P50/287; Y; Y10; Y10S; Y10S438/00; Y10S438/963
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
171 words
Process for fabrication of an article comprising at least one operation during which the article undergoing fabrication comprises a surface of material to be etched wherein the said article is etched within a plasma environment contained within an apparatus, the plasma resulting from imposition of an electrical field across gaseous reactant between two electrodes, etching being primarily due to chemical reaction with the said material to be etched, the said gaseous reactant including an effective etchant precursor for yielding a plasma-derived effective etchant primarily responsible for the said chemical reaction and an unsaturate precursor which yields ethylenically unsaturated material or radical which may yield unsaturated material here designated as "unsaturate" which may combine with effective etchant to reduce the amount of available effective etchant, characterized in that the said gaseous reactant includes an oxidant precursor which yields an additional oxidant which combines with unsaturate to result in reduced reaction between unsaturate and effective etchant and thereby increase concentration of effective etchant whereby the rate of the said chemical reaction is increased.
Claim 2
Dependent Claim
171 words
Process for fabrication of an article comprising at least one operation during which the article undergoing fabrication comprises a surface of material to be etched wherein the said article is etched within a plasma environment contained within an apparatus, the plasma resulting from imposition of an electrical field across gaseous reactant between two electrodes, etching being primarily due to chemical reaction with the said material to be etched, the said gaseous reactant including an effective etchant precursor for yielding a plasma-derived effective etchant primarily responsible for the said chemical reaction and an unsaturate precursor which yields ethylenically unsaturated material or radical which may yield unsaturated material here designated as "unsaturate" which may combine with effective etchant to reduce the amount of available effective etchant, characterized in that the said gaseous reactant includes an oxidant precursor which yields an additional oxidant which combines with unsaturate to result in reduced reaction between unsaturate and effective etchant and thereby increase concentration of effective etchant whereby the rate of the said chemical reaction is increased.
Claim 3
Dependent Claim
15 words
Process of claim 1 in which etchant precursor and unsaturate precursor are a single compound.
Claim 4
Dependent Claim
14 words
Process of claim 1 in which polymerization of unsaturate is inhibited by additional oxidant.
Claim 5
Dependent Claim
26 words
Process of claim 1 in which the additional oxidant is a stronger oxidizing agent with respect to the said unsaturate than is the said effective etchant.
Claim 6
Dependent Claim
15 words
Process of claim 4 in which the said unsaturate contains fluorine and ethylenically bonded carbon.
Claim 7
Dependent Claim
24 words
Process of claim 1 in which the effective etchant precursor includes at least one element selected from the group consisting of chlorine and bromine.
Claim 8
Dependent Claim
58 words
Process of claim 6 in which the added oxidant precursor includes at least one element selected from the group consisting of fluorine and oxygen, when the effective etchant precursor includes chlorine, and in which the added oxidant precursor includes an element selected from the group consisting of chlorine, fluorine, and oxygen when the effective etchant precursor includes bromine.
Claim 9
Dependent Claim
41 words
Process of claim 1 in which the added oxidant precursor is at least one molecular species selected from the group consisting of NF 3 , ClF 3 , BrF 3 , F 2 , O 2 , and Cl 2 .
Claim 10
Dependent Claim
12 words
Process of claim 1 in which the said precursors include a halocarbon.
Claim 11
Dependent Claim
36 words
Process of claim 1 in which the said additional oxidant precursor has an atom content of additional oxidant at least equal to 10 percent of the atom content of etchant species in the said etchant precursor.
References Cited (Backward Citations)
US4162185A
Cited
US4211601A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-02-08 | 1985-08-10 | 1986-02-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-02-08 | 1989-08-10 | 1990-02-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-02-08 | 1993-08-10 | 1994-02-09 | $7700.00 | Window Closed / Lapsed |