US4313996A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Formable metal-plastic-metal structural laminates
Assignee: Dow Chemical Co
•
Filing: 1979-05-21
•
Granted: 1982-02-02
•
Expires: 1999-05-21
Abstract
Abstract A metal-plastic-metal structural laminate which can be formed into various useful articles having compound curves using conventional metal forming techniques. The laminate comprises two metal skin layers and a centrally disposed polymer layer comprising a core layer, and optionally first and second adhesive layers. Each metal skin layer is 2 to 20 mils, the ratio of the core thickness to skin thickness is less than 9:1 and the total laminate thickness is 5 to 65 mils. The laminate can be bent to 90° to a critical radius, the distance between the pivot point and the inner skin surface of the laminate, without metal rupture.
Inventors
- 👤 Ritchey O. Newman
- 👤 James K. Rieke
- 👤 Donald R. Wright
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 12:02
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; Y; Y10; Y10T; Y10T156/00; Y10T156/10; Y10T156/1002; Y10T156/1007; Y10T428/00; Y10T428/12; Y10T428/12493; Y10T428/12535; Y10T428/12542; Y10T428/12549; Y10T428/12556; Y10T428/12569; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/24992; Y10T428/26; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31696
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
249 words
A metal-polymer-metal structural laminate comprising a core of polymeric resinous material having tightly adhered to each side thereof a metal skin layer wherein each metal skin layer is from about 2 to about 20 mils thick, said laminate further having a ratio of core thickness to skin thickness of less than 9:1, and a total thickness of from about 5 to about 65 mils; the materials of construction of said polymeric core and metal skins and the geometry of the laminate being such that the laminate has a flexural stiffness at least 40% that of the solid metal of the same thickness as measured by ASTM D790 on a one inch wide sample having four inch span under three point loading conditions, a density from about 25% to 90% that of the average of two solid metal skin layers, a limiting dome height of at least about 60 percent of the limiting dome height of the solid metal of the skin layer of the lower ultimate elongation having the same thickness, the capability of being subjected to a no load oven test, subsequent to forming of said laminate, at a temperature of at least 190° F. for a period of 30 minutes without delaminating, and the capability of being bent at room temperature to 90° to a critical radius without metal rupture, the critical radius defined as the distance from the pivot point to the inner skin surface of the laminate, being about equal to the total laminate thickness.
Claim 2
Dependent Claim
249 words
A metal-polymer-metal structural laminate comprising a core of polymeric resinous material having tightly adhered to each side thereof a metal skin layer wherein each metal skin layer is from about 2 to about 20 mils thick, said laminate further having a ratio of core thickness to skin thickness of less than 9:1, and a total thickness of from about 5 to about 65 mils; the materials of construction of said polymeric core and metal skins and the geometry of the laminate being such that the laminate has a flexural stiffness at least 40% that of the solid metal of the same thickness as measured by ASTM D790 on a one inch wide sample having four inch span under three point loading conditions, a density from about 25% to 90% that of the average of two solid metal skin layers, a limiting dome height of at least about 60 percent of the limiting dome height of the solid metal of the skin layer of the lower ultimate elongation having the same thickness, the capability of being subjected to a no load oven test, subsequent to forming of said laminate, at a temperature of at least 190° F. for a period of 30 minutes without delaminating, and the capability of being bent at room temperature to 90° to a critical radius without metal rupture, the critical radius defined as the distance from the pivot point to the inner skin surface of the laminate, being about equal to the total laminate thickness.
Claim 3
Dependent Claim
20 words
The structural laminate of claim 1 wherein the metal skin layers on each side of the core are different thicknesses.
Claim 4
Dependent Claim
21 words
The structural laminate of claim 1 wherein the metal skin layers on each side of the core are of different metals.
Claim 5
Dependent Claim
49 words
The structural laminate of claim 1 wherein the core of polymeric resinous material is selected from a group consisting of homopolymers and copolymers of ethylene or propylene and having a brittle temperature of less than about 30° F. and a Vicat softening point of greater than about 170° F.
Claim 6
Dependent Claim
23 words
The structural laminate of claim 1 wherein the core of polymeric resinous material has been irradiated for improved creep properties and thermal stability.
Claim 7
Dependent Claim
15 words
The structural laminate of claim 1 wherein the core of polymeric resinous material is electroconductive.
Claim 8
Dependent Claim
16 words
The structural laminate of claim 1 having a core thickness from about 10 to 45 mils.
Claim 9
Dependent Claim
21 words
The structural laminate of claim 1 wherein the metal skin layer has a thickness of from about 5 to 15 mils.
Claim 10
Dependent Claim
16 words
The structural laminate of claim 1 wherein the polymer core does not incorporate a solid filler.
Claim 11
Dependent Claim
21 words
The structural laminate of claim 1 wherein the core of polymeric resinous material contains at least one reinforcing element embedded therein.
Claim 12
Dependent Claim
15 words
The structural laminate of claim 10 wherein the reinforcing element is an expanded metallic sheet.
Claim 13
Dependent Claim
87 words
The structural laminate of claim 1 wherein the polymeric resinous material of the core is selected from homopolymers and copolymers of propylene or ethylene having a brittle temperature of less than about 30° F. and a Vicat softening point of greater than about 170° F. and the metal skin layers are steel or steel alloys, the thickness of each skin being within the range of from about 5 to 10 mils and the total laminate thickness being within the range of from about 23 to 48 mils.
Claim 14
Dependent Claim
15 words
The structure laminate of claim 12 wherein the polymeric resinous material is high density polyethylene.
Claim 15
Dependent Claim
86 words
The structural laminate of claim 1 wherein the polymeric resinous material of the core is selected from homopolymers and copolymers of propylene or ethylene having a brittle temperature of less than about 30° F. and a Vicat softening point of greater than about 170° F. and the metal skin layers are aluminum or aluminum alloys, the thickness of each skin being within the range of from 6 to 12 mils and the total laminate thickness being within the range of from about 30 to 60 mils.
Claim 16
Dependent Claim
15 words
The structural laminate of claim 14 wherein the polymeric resinous material is high density polyethylene.
Claim 17
Dependent Claim
29 words
The structural laminate of claims 1, 10 or 12 wherein the core is tightly adhered to the metal skin layers by the use of an intermediate adhesive layer therebetween.
Claim 18
Dependent Claim
20 words
The structural laminate of claim 16 wherein the intermediate adhesive comprises a copolymer of ethylene and ethylenically unsaturated carboxylic acid.
Claim 19
Dependent Claim
13 words
The structural laminate of claim 17 wherein the carboxylic acid is acrylic acid.
References Cited (Backward Citations)
US3382136A
Cited
US3298559A
Cited
US3340714A
Cited
US3348995A
Cited
US3594249A
Cited
US3616019A
Cited
US3542605A
Cited
US3721597A
Cited
US3711365A
Cited
US3826628A
Cited
US4115619A
Cited
US4229504A
Cited
GB2038239A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-02-01 | 1985-08-03 | 1986-02-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-02-01 | 1989-08-03 | 1990-02-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-02-01 | 1993-08-03 | 1994-02-02 | $7700.00 | Window Closed / Lapsed |