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US4313840A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat transfer oil and method for driving a Freon turbine

Assignee: National Institute of Advanced Industrial Science and Technology
•
Filing: 1980-03-07
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Granted: 1982-02-02
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Expires: 2000-03-07
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Abstract

Abstract Freon stable heat transfer oil comprising polyol ester containing tris-(alkylphenyl) phosphite and benzotriazole <IMAGE> or benzotriazole derivative <IMAGE> in which R1 and R2 each represents a hydrogen atom or an alkyl group. It is desirable to add tris-(alkylphenyl) phosphite or tris-(phenyl) phosphite in an amount in the range between 0.02-5% by weight and to add benzotriazole or its derivative in an amount in the range between 0.02-1% by weight to the heat transfer oil.

Inventors

  • 👤 Shigeki Komatsuzaki
  • 👤 Moriichi Sato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 20:03
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/08; C10; C10M; C10M2207/00; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2215/00; C10M2215/22; C10M2215/221; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/30; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10N; C10N2040/00; C10N2040/135; C10N2040/30; C10N2040/32; C10N2040/34; C10N2040/36; C10N2040/38; C10N2040/40; C10N2040/42; C10N2040/44; C10N2040/50

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 169 words
A heat transfer method for driving a Freon turbine comprising the steps of: (a) transferring heat of a heat source through a heat exchanger of the indirect contact type to an intermediate heat transfer oil, consisting essentially of: (1) a major amount of a polyolester of a reaction product of a polyhydric alcohol selected from the group consisting of neopentylglycol, trimethylolethane, trimethylolpropane and pentaerythritol with a saturated monocarboxylic acid having 7-16 carbon atoms per molecule; (2) at least one member selected from the groups consisting of tris-(alkylphenyl)phosphite and tris-(phenyl)phosphite, and (3) at least one member selected from the group consisting of benzotriazole and benzotriazole derivatives having the formula ##STR30## wherein R 1 and R 2 each represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; whereby said heated intermediate transfer oil gasifies said Freon by contact therewith, said components (2) and (3) being present in an amount sufficient to reduce the generation of chlorine ion; and (b) driving said turbine with said gasified Freon.
Claim 2
Dependent Claim 169 words
A heat transfer method for driving a Freon turbine comprising the steps of: (a) transferring heat of a heat source through a heat exchanger of the indirect contact type to an intermediate heat transfer oil, consisting essentially of: (1) a major amount of a polyolester of a reaction product of a polyhydric alcohol selected from the group consisting of neopentylglycol, trimethylolethane, trimethylolpropane and pentaerythritol with a saturated monocarboxylic acid having 7-16 carbon atoms per molecule; (2) at least one member selected from the groups consisting of tris-(alkylphenyl)phosphite and tris-(phenyl)phosphite, and (3) at least one member selected from the group consisting of benzotriazole and benzotriazole derivatives having the formula ##STR30## wherein R 1 and R 2 each represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; whereby said heated intermediate transfer oil gasifies said Freon by contact therewith, said components (2) and (3) being present in an amount sufficient to reduce the generation of chlorine ion; and (b) driving said turbine with said gasified Freon.
Claim 3
Dependent Claim 41 words
A heat transfer method according to claim 1, wherein tris-(alkylphenyl)phosphite and tris-(phenyl)phosphite are present in an amount of at least 0.02% by weight and wherein benzotriazole or said benzotriazole derivatives are present in an amount of at least 0.02% by weight.
Claim 4
Dependent Claim 23 words
A heat transfer method according to claim 2, wherein tris-(alkylphenyl)phosphite and tris-(phenyl)phosphite are present in an amount of 0.02 to 5% by weight.
Claim 5
Dependent Claim 25 words
A heat transfer method according to claim 2, wherein benzotriazole or said benzotriazole derivative is present in an amount of 0.02 to 1% by weight.
Claim 6
Dependent Claim 17 words
A heat transfer method according to claim 1, wherein said polyolester is trimethylolpropane tricaprylate or pentaerythritol tetracaprylate.
Claim 7
Dependent Claim 15 words
A heat transfer method according to claim 1, wherein said turbine rotates an electric generator.

References Cited (Backward Citations)

CA522450A Cited
GB823295A Cited
US3914179A Cited
US3640873A Cited
US3630915A Cited
US3790481A Cited
US3926823A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-01 1985-08-03 1986-02-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-01 1989-08-03 1990-02-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-01 1993-08-03 1994-02-02 $7700.00 Window Closed / Lapsed

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