US4313816A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Staged temperature coal conversion process
Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1980-08-25
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Granted: 1982-02-02
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Expires: 2000-08-25
Abstract
Abstract Coal or similar liquefiable carbonaceous solids are converted into lower molecular weight liquids by contacting the feed solids with molecular hydrogen in the absence of externally added hydrocarbon liquids under liquefaction conditions during sequential residence in two or more liquefaction zones arranged in series and operated such that the temperature in each zone increases from the first to the final zone. The effluent from each liquefaction zone is passed to the next succeeding higher temperature zone in the series. No hydrocarbon liquids are added to the first zone in the series and the only liquids present in each succeeding zone of the series are the liquids in the effluent from the preceding zone. Liquid hydrocarbonaceous products are recovered from the effluent withdrawn from the last zone.
Inventors
- 👤 Lavanga R. Veluswamy
- 👤 Peter S. Maa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 15:36
CPC Classifications
C; C10; C10G; C10G1/00; C10G1/06; C10G1/006; C10G1/08
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
154 words
A process for converting coal or similar liquefiable carbonaceous solids into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said carbonaceous solids with molecular hydrogen in the absence of externally added hydrocarbon liquids under liquefaction conditions during sequential residence in two or more liquefaction zones arranged in series and operated such that (i) the temperature in each zone increases from the first to the final zone of the series and (ii) the total of the solids residence times in all except the final zone of the series is greater than about 40 minutes, wherein said carbonaceous solids are partially converted into lower molecular weight liquid hydrocarbons in each of said liquefaction zones and the only hydrocarbon liquids added to each liquefaction zone subsequent to said first liquefaction zone are the liquids in the effluent from the preceding liquefaction zone; and (b) recovering liquid hydrocarbonaceous product from the effluent of said final liquefaction zone.
Claim 2
Dependent Claim
154 words
A process for converting coal or similar liquefiable carbonaceous solids into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said carbonaceous solids with molecular hydrogen in the absence of externally added hydrocarbon liquids under liquefaction conditions during sequential residence in two or more liquefaction zones arranged in series and operated such that (i) the temperature in each zone increases from the first to the final zone of the series and (ii) the total of the solids residence times in all except the final zone of the series is greater than about 40 minutes, wherein said carbonaceous solids are partially converted into lower molecular weight liquid hydrocarbons in each of said liquefaction zones and the only hydrocarbon liquids added to each liquefaction zone subsequent to said first liquefaction zone are the liquids in the effluent from the preceding liquefaction zone; and (b) recovering liquid hydrocarbonaceous product from the effluent of said final liquefaction zone.
Claim 3
Dependent Claim
25 words
A process as defined in claim 1 wherein said first liquefaction zone is operated at a temperature between about 680° F. and about 750° F.
Claim 4
Dependent Claim
14 words
A process as defined in claim 1 wherein said carbonaceous solids comprise bituminous coal.
Claim 5
Dependent Claim
49 words
A process as defined in claim 1 wherein said first liquefaction zone is operated at a temperature in the range between about 690° F. and about 720° F. and said final liquefaction zone is operated at a temperature in the range between about 820° F. and about 860° F.
Claim 6
Dependent Claim
16 words
A process as defined in claim 1 wherein two liquefaction zones are employed in step (a).
Claim 7
Dependent Claim
42 words
A process as defined in claim 1 wherein said carbonaceous solids comprise a bituminous coal and are contacted in said liquefaction zones in the presence of an added hydrogenation catalyst selected from the group consisting of compounds containing nickel, molybdenum, and cobalt.
Claim 8
Dependent Claim
156 words
A process for converting coal or similar liquefiable carbonaceous solids into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said carbonaceous solids with molecular hydrogen under liquefaction conditions in the absence of externally added hydrocarbon liquids in a first liquefaction zone wherein the solids residence time is greater than about 40 minutes to at least partially convert said solids into lower molecular weight liquid hydrocarbons thereby producing a liquefaction effluent; (b) subjecting said liquefaction effluent from said first liquefaction zone to liquefaction conditions in the presence of molecular hydrogen in a second liquefaction zone maintained at a temperature greater than the temperature in said first liquefaction zone thereby further converting said carbonaceous solids into lower molecular weight hydrocarbons, wherein the only hydrocarbon liquids added to said second liquefaction zone are the liquids in said liquefaction effluent from said first liquefaction zone; and (c) recovering liquid hydrocarbonaceous products from the effluent of said second liquefaction zone.
Claim 9
Dependent Claim
156 words
A process for converting coal or similar liquefiable carbonaceous solids into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said carbonaceous solids with molecular hydrogen under liquefaction conditions in the absence of externally added hydrocarbon liquids in a first liquefaction zone wherein the solids residence time is greater than about 40 minutes to at least partially convert said solids into lower molecular weight liquid hydrocarbons thereby producing a liquefaction effluent; (b) subjecting said liquefaction effluent from said first liquefaction zone to liquefaction conditions in the presence of molecular hydrogen in a second liquefaction zone maintained at a temperature greater than the temperature in said first liquefaction zone thereby further converting said carbonaceous solids into lower molecular weight hydrocarbons, wherein the only hydrocarbon liquids added to said second liquefaction zone are the liquids in said liquefaction effluent from said first liquefaction zone; and (c) recovering liquid hydrocarbonaceous products from the effluent of said second liquefaction zone.
Claim 10
Dependent Claim
14 words
A process as defined in claim 7 wherein said carbonaceous solids comprise bituminous coal.
Claim 11
Dependent Claim
43 words
A process as defined in claim 7 wherein said solids residence time in said first liquefaction zone is between about 60 and about 200 minutes and said solids residence time in said second liquefaction zone is between about 20 and about 120 minutes.
Claim 12
Dependent Claim
41 words
A process as defined in claim 7 wherein the temperature in said first liquefaction zone is between about 680° F. and about 750° F. and the temperature in said second liquefaction zone is between about 790° F. and about 900° F.
Claim 13
Dependent Claim
40 words
A process as defined in claim 7 wherein the pressure in said first liquefaction zone is between about 1500 psig and about 1500 psig and the pressure in said second liquefaction zone is between about 1500 psig about 2500 psig.
Claim 14
Dependent Claim
51 words
A process as defined in claim 7 wherein said carbonaceous solids comprise coal containing a total sulfur content greater than about 1.0 weight percent based on dry coal and a hydrogenation catalyst selected from the group consisting of compounds containing nickel, cobalt, and molybdenum is present in each of said zones.
Claim 15
Dependent Claim
14 words
A process as defined in claim 12 wherein said hydrogenation catalyst comprises ammonium heptamolybdate.
Claim 16
Dependent Claim
28 words
A process as defined in claim 7 wherein said carbonaceous solids comprise coal having a total sulfur content greater than about 1.0 weight percent based on dry coal.
Claim 17
Dependent Claim
29 words
A process as defined in claim 7 wherein the solids residence time in said first liquefaction zone is greater than the solids residence time in said second liquefaction zone.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-02-01 | 1985-08-03 | 1986-02-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-02-01 | 1989-08-03 | 1990-02-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-02-01 | 1993-08-03 | 1994-02-02 | $7700.00 | Window Closed / Lapsed |