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US4313806A Expired / Lapsed US ⏱️ 0.0 years remaining

Cathodic protection of catalysts in a corrosive environment

Assignee: Air Products and Chemicals Inc
•
Filing: 1980-10-10
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Granted: 1982-02-02
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Expires: 2000-10-10
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Abstract

Abstract Dissolution of Group VIII supported metal catalysts from semi-conductive or conductive carriers in liquid media containing a strong inorganic acid is stopped by making the Group VIII noble metal cathodic with respect to an anode placed in the reactor. A representative embodiment is in processes for synthesis of hydrogen peroxide from its elements.

Inventors

  • 👤 Augustine I. Dalton, Jr.
  • 👤 Ronald W. Skinner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 15:33
CPC Classifications
C; C23; C23F; C23F13/00; C23F13/02

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 69 words
A process for preventing dissolution of a Group VIII noble metal catalyst from a conductive or semiconductive carrier in a corrosive or oxidatively active liquid environment, comprising polarizing the Group VIII noble metal surface on the conductive or semiconductive carrier so as to render the polarized Group VIII noble metal surface cathodic with respect to an anode placed in a reactor containing the corrosive or oxidatively active liquid environment.
Claim 2
Dependent Claim 69 words
A process for preventing dissolution of a Group VIII noble metal catalyst from a conductive or semiconductive carrier in a corrosive or oxidatively active liquid environment, comprising polarizing the Group VIII noble metal surface on the conductive or semiconductive carrier so as to render the polarized Group VIII noble metal surface cathodic with respect to an anode placed in a reactor containing the corrosive or oxidatively active liquid environment.
Claim 3
Dependent Claim 50 words
The process of claim 1, wherein the corrosive environment is that used in the liquid phase catalytic reaction of hydrogen and oxygen to form hydrogen peroxide in a liquid capable of stabilizing the hydrogen peroxide thus produced against decomposition, the liquid containing water and at least one strong inorganic acid.
Claim 4
Dependent Claim 14 words
The process of claim 2, wherein the Group VIII noble metal catalyst is palladium.
Claim 5
Dependent Claim 11 words
The process of claim 2, wherein the conductive carrier is carbon.
Claim 6
Dependent Claim 12 words
The process of claim 2, wherein the corrosive environment is aqueous acetone.
Claim 7
Dependent Claim 16 words
The process of claim 2, wherein the strong inorganic acid is hydrochloric acid or sulfuric acid.
Claim 8
Dependent Claim 15 words
The process of claim 2, wherein the corrosive environment contains hydrochloric acid and sulfuric acid.
Claim 9
Dependent Claim 26 words
The process of claim 2, wherein the catalyst is palladium supported on carbon and the corrosive environment is aqueous acetone containing hydrochloric acid and sulfuric acid.

References Cited (Backward Citations)

US1779436A Cited
US3201335A Cited
US3361533A Cited
US3336112A Cited
US3972796A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-01 1985-08-03 1986-02-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-01 1989-08-03 1990-02-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-01 1993-08-03 1994-02-02 $7700.00 Window Closed / Lapsed

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