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US4312957A Expired / Lapsed US ⏱️ 0.0 years remaining

Fast-cooling styrene polymer foams

Assignee: Lyondell Chemical Technology LP
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Filing: 1980-10-01
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Granted: 1982-01-26
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Expires: 2000-10-01
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Abstract

Abstract Expandable styrene polymer particles which have fast cooling rates during molding are produuced by suspending styrene polymer particles in an aqueous medium and impregnating a blowing agent into the particles in the presence of 0.1 to 0.6 parts of a synergistic mixture of surfactants per 100 parts of polymer particles.

Inventors

  • 👤 John P. Spicuzza, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 04:45
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/16; C08J9/18; C08J2325/00; C08J2325/02

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 198 words
Method of making foamable styrene polymer particles which yield a fast cooling foamed molding comprising the steps of: (a) suspending styrene polymer particles in water with the aid of a suspending agent system; (b) adding 3 to 20 weight percent of a blowing agent and 0.1 to 0.6 weight percent of a synergistic mixture of (1) a first surfactant selected from the group consisting of polyoxyethylene sorbitan monoesters of fatty acids, polyoxyethylene monoesters of fatty acids, and polyoxyethylene monoethers of long-chain fatty alcohols and (2) a second surfactant selected from the polyoxyethylene monoethers of alkylphenols, wherein the polyoxyethylene moieties contain from 10 to 50 moles of ethylene oxide per molecule, the fatty acids and alcohols contain from 10 to 18 carbon atoms per molecule, and the alkyl portion of the alkylphenols contains from 8 to 12 carbon atoms wherein said synergistic mixture consists of a ratio of said first surfactant to said second surfactant of between 3 to 1 and 1 to 1; (c) heating the suspension at a temperature of from 80° to 150° C. to impregnate the polymer particles with blowing agent and the mixed surfactants; and (d) separating the impregnated particles from the aqueous system.
Claim 2
Dependent Claim 198 words
Method of making foamable styrene polymer particles which yield a fast cooling foamed molding comprising the steps of: (a) suspending styrene polymer particles in water with the aid of a suspending agent system; (b) adding 3 to 20 weight percent of a blowing agent and 0.1 to 0.6 weight percent of a synergistic mixture of (1) a first surfactant selected from the group consisting of polyoxyethylene sorbitan monoesters of fatty acids, polyoxyethylene monoesters of fatty acids, and polyoxyethylene monoethers of long-chain fatty alcohols and (2) a second surfactant selected from the polyoxyethylene monoethers of alkylphenols, wherein the polyoxyethylene moieties contain from 10 to 50 moles of ethylene oxide per molecule, the fatty acids and alcohols contain from 10 to 18 carbon atoms per molecule, and the alkyl portion of the alkylphenols contains from 8 to 12 carbon atoms wherein said synergistic mixture consists of a ratio of said first surfactant to said second surfactant of between 3 to 1 and 1 to 1; (c) heating the suspension at a temperature of from 80° to 150° C. to impregnate the polymer particles with blowing agent and the mixed surfactants; and (d) separating the impregnated particles from the aqueous system.
Claim 3
Dependent Claim 12 words
The method of claim 1 wherein said styrene polymer particles are polystyrene.
Claim 4
Dependent Claim 21 words
The method of claim 1 wherein said styrene polymer particles are a copolymer of styrene with minor amounts of maleic anhydride.
Claim 5
Dependent Claim 20 words
The method of claim 1 wherein said styrene polymer particles are a copolymer of styrene with minor amounts of acrylonitrile.
Claim 6
Dependent Claim 22 words
The method of claim 1 wherein said styrene polymer particles are a copolymer of styrene with minor amounts of methyl acid maleate.
Claim 7
Dependent Claim 137 words
A composition comprising a styrene polymer containing dispersed throughout 3 to 20 weight percent of a blowing agent and 0.1 and 0.6 weight percent of a synergistic mixture of (1) a first surfactant selected from the group consisting of polyoxyethylene sorbitan monoesters of fatty acids, polyoxyethylene monoesters of fatty acids, and polyoxyethylene monoethers of long-chain fatty alcohols and (2) a second surfactant selected from the polyoxyethylene monoethers of alkylphenols, wherein the polyoxyethylene moieties contain from 10 to 50 moles of ethylene oxide per molecule, the fatty acids and alcohols contain from 10 to 18 carbon atoms per molecule, and the alkyl portion of the alkylphenols contains from 8 to 12 carbon atoms wherein said synergistic mixture consists of a ratio of said first surfactant to said second surfactant of between 3 to 1 and 1 to 1.
Claim 8
Dependent Claim 137 words
A composition comprising a styrene polymer containing dispersed throughout 3 to 20 weight percent of a blowing agent and 0.1 and 0.6 weight percent of a synergistic mixture of (1) a first surfactant selected from the group consisting of polyoxyethylene sorbitan monoesters of fatty acids, polyoxyethylene monoesters of fatty acids, and polyoxyethylene monoethers of long-chain fatty alcohols and (2) a second surfactant selected from the polyoxyethylene monoethers of alkylphenols, wherein the polyoxyethylene moieties contain from 10 to 50 moles of ethylene oxide per molecule, the fatty acids and alcohols contain from 10 to 18 carbon atoms per molecule, and the alkyl portion of the alkylphenols contains from 8 to 12 carbon atoms wherein said synergistic mixture consists of a ratio of said first surfactant to said second surfactant of between 3 to 1 and 1 to 1.
Claim 9
Dependent Claim 11 words
The composition of claim 6 wherein the styrene polymer is polystyrene.
Claim 10
Dependent Claim 19 words
The composition of claim 6 wherein the styrene polymer is a copolymer of styrene with minor amounts of acrylonitrile.
Claim 11
Dependent Claim 20 words
The composition of claim 6 wherein the styrene polymer is a copolymer of styrene with minor amounts of maleic anhydride.
Claim 12
Dependent Claim 21 words
The composition of claim 6 wherein the styrene polymer is a copolymer of styrene with minor amounts of methyl acid maleate.

References Cited (Backward Citations)

US3480570A Cited
US3503908A Cited
US3789028A Cited
US3817879A Cited
US3827990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-25 1985-07-27 1986-01-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-25 1989-07-27 1990-01-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-25 1993-07-27 1994-01-26 $7700.00 Window Closed / Lapsed

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