US4312940A
Expired / Lapsed
US
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Photographic material containing a novel polymer mordant
Assignee: Fujifilm Holdings Corp
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Filing: 1980-07-07
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Granted: 1982-01-26
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Expires: 2000-07-07
Abstract
Abstract A photographic light-sensitive material comprising at least one layer containing a polymer dispersion of the following formula (I) or (II) as a mordant ##STR1## wherein A represents a monomer unit obtained from at least one monomer having at least two copolymerizable ethylenically unsaturated groups at least one of which is in the side chain; B represents a monomer unit obtained from at least one copolymerizable monoethylenically unsaturated monomer; D.sup.⊕ represents a 5- or 6-membered heterocyclic group containing one or two nitrogen atoms one of which is positively charged and D may contain one or more substituents; R 1 represents a hydrogen atom or a lower alkyl group; R 2 and R 3 , which may be the same or different, each represents an alkyl group or an aralkyl group, or R 2 and R 3 may combine together with the nitrogen atom to which they are attached and form a 5- or 6-membered ring; X.sup.⊖ represents an anion; Q represents an alkylene group, a phenylene group, an aralkylene group or a group of the formula ##STR2## wherein Y represents an alkylene group or an aralkylene group and R represents an alkyl group; and x, y and z represent the molar percentage of the respective units in the polymer and x is about 0.5 to 10%, y is about 0 to 60% and z is about 30 to 99.5%.
Inventors
- 👤 Taku Nakamura
- 👤 Shigeru Nagatomo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 19:39
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/825; G03C1/835; Y; Y10; Y10S; Y10S430/00; Y10S430/142
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
254 words
A silver halide photographic light-sensitive material comprising at least one gelatino layer containing a polymer dispersion of the following formula (I) or (II) as a mordant capable of mordanting an acid dye, which material is subjected to alkali processing to remove mordanted acid dye ##STR24## where A represents a monomer unit obtained from at least one monomer having at least two copolymerizable ethylenically unsaturated groups at least one of which is in the side chain: B represents a monomer unit obtained from at least one copolymerizable monoethylenically unsaturated monomer; D.sup.⊕ represents a 5- or 6-membered heterocyclic ring containing one or two nitrogen atoms one of which is positively charged to form a tertiary ammonium group and D may contain one or more substituents; R 1 represents a hydrogen atom or a lower alkyl group; R 2 and R 3 , which may be the same or different, each represents an alkyl group or an aralkyl group, or R 2 and R 3 combine together with the nitrogen atom to which they are attached and form a 5- or 6-membered ring; X.sup.⊖ represents an anion; Q represents an alkylene group, a phenylene group, an aralkylene group or a group of the formula ##STR25## wherein Y represents the alkylene group or an aralkylene group and R represents an alkyl group; and x, y and z represent the molar percentage of the respective units in the polymer and x is about 0.5 to 10%, y is about 0 to 60% and z is about 30 to 99.5%.
Claim 2
Dependent Claim
254 words
A silver halide photographic light-sensitive material comprising at least one gelatino layer containing a polymer dispersion of the following formula (I) or (II) as a mordant capable of mordanting an acid dye, which material is subjected to alkali processing to remove mordanted acid dye ##STR24## where A represents a monomer unit obtained from at least one monomer having at least two copolymerizable ethylenically unsaturated groups at least one of which is in the side chain: B represents a monomer unit obtained from at least one copolymerizable monoethylenically unsaturated monomer; D.sup.⊕ represents a 5- or 6-membered heterocyclic ring containing one or two nitrogen atoms one of which is positively charged to form a tertiary ammonium group and D may contain one or more substituents; R 1 represents a hydrogen atom or a lower alkyl group; R 2 and R 3 , which may be the same or different, each represents an alkyl group or an aralkyl group, or R 2 and R 3 combine together with the nitrogen atom to which they are attached and form a 5- or 6-membered ring; X.sup.⊖ represents an anion; Q represents an alkylene group, a phenylene group, an aralkylene group or a group of the formula ##STR25## wherein Y represents the alkylene group or an aralkylene group and R represents an alkyl group; and x, y and z represent the molar percentage of the respective units in the polymer and x is about 0.5 to 10%, y is about 0 to 60% and z is about 30 to 99.5%.
Claim 3
Dependent Claim
22 words
The photographic light-sensitive material of claim 1, wherein A represents a monomer unit obtained from a dimethacrylate, a diacrylate or divinyl benzene.
Claim 4
Dependent Claim
60 words
The photographic light-sensitive material of claim 1, wherein monomer B is obtained from an α-olefin having 3 to 6 carbon atoms, styrene, α-methylstyrene, vinyltoluene, monoethylenically unsaturated esters of aliphatic acids having 2 to 6 carbon atoms, esters of monoethylenically unsaturated carboxylic acids or dicarboxylic acids having 3 to 20 carbon atoms, styrene or a derivatives thereof, acrylonitrile, and allyl cyanide.
Claim 5
Dependent Claim
20 words
The photographic light-sensitive material of claim 2, wherein the unit A is obtained from divinyl benzene or ethylene glycol dimethacrylate.
Claim 6
Dependent Claim
17 words
The photographic light-sensitive material of claim 3, wherein unit B is obtained from styrene, n-butylmethacrylate, cyclohexyl methacrylate.
Claim 7
Dependent Claim
17 words
The photographic light-sensitive material of claim 1, wherein D represents a ring selected from the following: ##STR26##
Claim 8
Dependent Claim
30 words
The photographic light-sensitive material of claim 1, wherein x is about 3 to 10 mol%, y is about 0 to 55 mol%, and z is about 40 to 97 mol%.
Claim 9
Dependent Claim
36 words
The photographic light-sensitive material of claim 1, wherein said polymer of the formula (I) or (II) is present in said layer in an amount of about 2 to 10 g per 100 g of dry gelatin.
Claim 10
Dependent Claim
14 words
The photographic light-sensitive material of claim 1, wherein said layer is an antihalation layer.
Claim 11
Dependent Claim
14 words
The photographic light-sensitive material of claim 1, wherein said layer is a filter layer.
Claim 12
Dependent Claim
14 words
The photographic light-sensitive material of claim 1, wherein said mordant has general formula (II).
Claim 13
Dependent Claim
14 words
The photographic light-sensitive material of claim 1, wherein said mordant has general formula (I).
Claim 14
Dependent Claim
111 words
The photographic light-sensitive material of claim 12, wherein monomer A contains 4 to 20 carbon atoms, monomer B contains 3 to 20 carbon atoms, Q is a divalent alkylene group having 1 to 12 carbon atoms, a phenylene group or an aralkylene group having 7 to 12 carbon atoms, R 1 is a hydrogen atom or a lower straight chain alkyl group having 1 to 6 carbon atoms and wherein R 2 and R 3 , which may be the same or different, each represents a straight, branched or cyclic alkyl group having 1 to 20 carbon atoms or a mono- or bicyclic aralkyl group having 7 to 20 carbon atoms.
Claim 15
Dependent Claim
37 words
The photographic light-sensitive material of claim 13, wherein X.sup.⊖ is selected from the group consisting of a halogen atom, an alkyl- or aryl-sulfonate ion, an acetate ion, a nitrate ion, a sulfate ion or a phosphate ion.
Claim 16
Dependent Claim
29 words
The photographic light-sensitive material of claim 14, wherein said mordant is utilized in an amount of about 2 to 100 g of mordant per 100 g of dry gelatin.
Claim 17
Dependent Claim
19 words
The photographic light-sensitive material of claim 15, wherein said mordant is in a filter layer or an anti-halation layer.
Claim 18
Dependent Claim
31 words
The photographic light-sensitive material of claim 1, wherein said acid dye is selected from acid dyes comprising a sulfonyl group, a carboxyl group, a sulfonamido group or a phenolic hydroxyl group.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-01-25 | 1985-07-27 | 1986-01-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-01-25 | 1989-07-27 | 1990-01-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-01-25 | 1993-07-27 | 1994-01-26 | $7700.00 | Window Closed / Lapsed |