Process and apparatus for the continuous production of foamed plastics material having improved fire resistance

Claim 1

A process for the continuous production of a flame-resistant foamed plastics material which comprises condensing an aqueous solution of a water-soluble aminoplast precondensate or a precursor thereof with an organic isocyanate which is at least bifunctional in the presence of an acidic curing catalyst to cure the aminoplast precondensate and in the presence of an organic amine as basic catalyst and, optionally, additionally an organic metal compound, the said water-soluble aminoplast precondensate or the precursor thereof being added, simultaneously with but separately from the acid curing catalysts, to the isocyanate to which the amine and, where relevant, the organic metal compound has been added previously, and the isocyanate being present in an amount, relative to the water, which permits a cross-linking reaction with the methylol groups of the aminoplast precondensate or of the precursor thereof, the said basic catalyst and, where relevant, the organic metal compound, being added in a first mixing stage to the isocyanate in an amount of 4 to 14% by weight, relative to the amount of isocyanate, the residence time of the pre-adduct formed from the catalyst and the organic isocyanate being from 1 to 8 seconds in the first mixing stage at a reaction temperature within the range of 40° to 130° C., after which the pre-adduct is immediately transferred to a subsequent second mixing stage into which the aminoplast precondensate and acid catalyst are introduced, following which the foamable reaction mixture is discharged continuously.