US4311683A
Expired / Lapsed
US
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Process for removal of hydrogen sulfide from gas streams
Assignee: Honeywell UOP LLC
•
Filing: 1980-06-23
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Granted: 1982-01-19
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Expires: 2000-06-23
Abstract
Abstract A process for the removal of H 2 S from a feed gas, and the production of sulfur therefrom, is effected by oxidation with oxygen and/or SO 2 at temperatures between 250° and 450° F. The oxidation is conducted in the presence of an extremely stable oxidation catalyst comprising an oxide and/or sulfide of vanadium supported on a non-alkaline porous refractory oxide. Sulfur deposition and consequent catalyst deactivation are prevented by maintaining the partial pressure of free sulfur in the oxidation reactor below that necessary for condensation. H 2 , CO, and light hydrocarbons present in the feed gas are not oxidized. Typical uses of the process include the removal of H 2 S and the production of sulfur from sour natural gases or gases obtained from the gasification of coal. Feed gases which contain SO 2 and H 2 S in mole ratios greater than 0.5, or which contain other gaseous sulfur compounds such as COS, CS 2 , SO 3 and mercaptans, can be desulfurized by hydrogenating all of such sulfur components to H 2 S and subsequently removing the H 2 S from the hydrogenated feed gas by the oxidation process of the invention. This hydrogenation-oxidation combination is especially contemplated for the desulfurization of Claus tail gases and stack gas effluents.
Inventors
- 👤 Robert H. Hass
- 👤 Rowland C. Hansford
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 22:39
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/0404; C01B17/046; C01B17/0465
Claims Analysis
Total Claims: 57
Claim 1
Independent Claim
71 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises contacting hydrogen sulfide and elemental oxygen with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a non-alkaline, porous refractory oxide support under conditions, including a temperature between about 250° and 450° F., such that said hydrogen sulfide reacts with said oxygen to produce elemental sulfur.
Claim 2
Dependent Claim
71 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises contacting hydrogen sulfide and elemental oxygen with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a non-alkaline, porous refractory oxide support under conditions, including a temperature between about 250° and 450° F., such that said hydrogen sulfide reacts with said oxygen to produce elemental sulfur.
Claim 3
Dependent Claim
102 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises contacting, at a temperature between about 250° and 450° F., hydrogen sulfide and oxygen with a solid catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxide and sulfides supported on a non-alkaline, porous refractory oxide, said contacting being such that a substantial proportion of said hydrogen sulfide is converted to elemental sulfur and said catalyst is utilized for at least 30 days with essentially no deactivation for the conversion of said hydrogen sulfide to elemental sulfur by reaction with oxygen.
Claim 4
Dependent Claim
102 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises contacting, at a temperature between about 250° and 450° F., hydrogen sulfide and oxygen with a solid catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxide and sulfides supported on a non-alkaline, porous refractory oxide, said contacting being such that a substantial proportion of said hydrogen sulfide is converted to elemental sulfur and said catalyst is utilized for at least 30 days with essentially no deactivation for the conversion of said hydrogen sulfide to elemental sulfur by reaction with oxygen.
Claim 5
Dependent Claim
134 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises contacting hydrogen sulfide with a solid catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium sulfides and oxides supported on a porous refractory oxide containing less than about 4 percent by weight of alkali metal and alkaline earth metal compounds, calculated as the oxides, said contacting being under conditions, including the presence of sufficient elemental oxygen and a temperature between about 250° and about 450° F., such that at least 80 percent of said hydrogen sulfide is converted to elemental sulfur by reaction with said oxygen, said contacting being carried out for at least 30 days with said catalyst maintaining substantially undiminished activity for reacting hydrogen sulfide with oxygen to produce elemental sulfur.
Claim 6
Dependent Claim
134 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises contacting hydrogen sulfide with a solid catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium sulfides and oxides supported on a porous refractory oxide containing less than about 4 percent by weight of alkali metal and alkaline earth metal compounds, calculated as the oxides, said contacting being under conditions, including the presence of sufficient elemental oxygen and a temperature between about 250° and about 450° F., such that at least 80 percent of said hydrogen sulfide is converted to elemental sulfur by reaction with said oxygen, said contacting being carried out for at least 30 days with said catalyst maintaining substantially undiminished activity for reacting hydrogen sulfide with oxygen to produce elemental sulfur.
Claim 7
Dependent Claim
114 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises the contacting of flowing gases containing hydrogen sulfide and elemental oxygen with a catalyst for at least 30 days under conditions, including a temperature between about 250° and 450° F., such that at least some of said hydrogen sulfide reacts with said elemental oxygen to produce elemental sulfur vapor, said catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxide and sulfides supported on a non-alkaline, porous refractory oxide, and said catalyst remaining highly active for catalyzing the reaction between hydrogen sulfide and oxygen to produce elemental sulfur during said 30 days of said contacting.
Claim 8
Dependent Claim
114 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises the contacting of flowing gases containing hydrogen sulfide and elemental oxygen with a catalyst for at least 30 days under conditions, including a temperature between about 250° and 450° F., such that at least some of said hydrogen sulfide reacts with said elemental oxygen to produce elemental sulfur vapor, said catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxide and sulfides supported on a non-alkaline, porous refractory oxide, and said catalyst remaining highly active for catalyzing the reaction between hydrogen sulfide and oxygen to produce elemental sulfur during said 30 days of said contacting.
Claim 9
Dependent Claim
92 words
A process as defined in claims 1, 2, 3, or 4 wherein elemental oxygen is present in essentially the stoichiometric proportion necessary to effect the full conversion of hydrogen sulfide to sulfur, and wherein at least 80% of said hydrogen sulfide is converted to sulfur, and wherein said catalyst consists essentially of between about 2 and 20 percent by weight of vanadium promoters on a support selected from the group consisting of alumina, silica, silica-alumina, and mixtures thereof, and wherein said conditions are such that essentially no sulfur deposits on the catalyst.
Claim 10
Dependent Claim
137 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) contacting at a temperature between about 250° and 450° F., a feed gas comprising hydrogen sulfide and elemental oxygen with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a support material selected from the group consisting of alumina, silica-alumina, silica, acidic metal phosphates, acidic metal arsenates, the natural and synthetic amorphous and crystalline aluminosilicate zeolites in their hydrogen forms, silica-magnesia, zirconia, silica-zirconia, titania, silica-titania, silica-zirconia-titania, and combinations thereof, said contacting being under conditions such that hydrogen sulfide and oxygen in the feed gas react to produce elemental sulfur without depositing essentially any of said elemental sulfur on said catalyst, and (2) recovering a product gas stream containing elemental sulfur vapor.
Claim 11
Dependent Claim
137 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) contacting at a temperature between about 250° and 450° F., a feed gas comprising hydrogen sulfide and elemental oxygen with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a support material selected from the group consisting of alumina, silica-alumina, silica, acidic metal phosphates, acidic metal arsenates, the natural and synthetic amorphous and crystalline aluminosilicate zeolites in their hydrogen forms, silica-magnesia, zirconia, silica-zirconia, titania, silica-titania, silica-zirconia-titania, and combinations thereof, said contacting being under conditions such that hydrogen sulfide and oxygen in the feed gas react to produce elemental sulfur without depositing essentially any of said elemental sulfur on said catalyst, and (2) recovering a product gas stream containing elemental sulfur vapor.
Claim 12
Dependent Claim
110 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) passing a feed gas stream containing hydrogen sulfide and oxygen through a catalyst bed under conditions, including an inlet temperature into said bed between about 250° and 450° F., such that hydrogen sulfide and oxygen in said feed gas stream react to produce elemental sulfur vapor, said catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support selected from the group consisting of alumina, silica-alumina, silica, and combinations thereof, and (2) recovering a product gas stream containing elemental sulfur vapor.
Claim 13
Dependent Claim
110 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) passing a feed gas stream containing hydrogen sulfide and oxygen through a catalyst bed under conditions, including an inlet temperature into said bed between about 250° and 450° F., such that hydrogen sulfide and oxygen in said feed gas stream react to produce elemental sulfur vapor, said catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support selected from the group consisting of alumina, silica-alumina, silica, and combinations thereof, and (2) recovering a product gas stream containing elemental sulfur vapor.
Claim 14
Dependent Claim
129 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) passing a feed gas stream containing hydrogen sulfide and oxygen through a catalyst bed under conditions, including an inlet temperature into said bed between 250° and 450° F., such that hydrogen sulfide and oxygen react to produce elemental sulfur vapor, said catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support selected from the group consisting of alumina, silica-alumina, silica, acidic metal phosphates, acidic metal arsenates, the natural and synthetic amorphous and crystalline aluminosilicate zeolites in their hydrogen forms, silica-magnesia,a zirconia, silica-zirconia, titania, silica-titania, silica-zirconia-titania, and combinations thereof, and (2) recovering a product gas stream containing elemental sulfur vapor.
Claim 15
Dependent Claim
129 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) passing a feed gas stream containing hydrogen sulfide and oxygen through a catalyst bed under conditions, including an inlet temperature into said bed between 250° and 450° F., such that hydrogen sulfide and oxygen react to produce elemental sulfur vapor, said catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support selected from the group consisting of alumina, silica-alumina, silica, acidic metal phosphates, acidic metal arsenates, the natural and synthetic amorphous and crystalline aluminosilicate zeolites in their hydrogen forms, silica-magnesia,a zirconia, silica-zirconia, titania, silica-titania, silica-zirconia-titania, and combinations thereof, and (2) recovering a product gas stream containing elemental sulfur vapor.
Claim 16
Dependent Claim
109 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) contacting flowing gases containing hydrogen sulfide and oxygen with a solid catalyst for at least 30 days under conditions, including a temperature between about 250° and 450° F., sufficient to react at least 80% of said hydrogen sulfide with said oxygen to produce elemental sulfur essentially completely in the vapor state, said catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support selected from the group consisting of alumina and silica-alumina, and (2) recovering a product gas containing elemental sulfur vapor.
Claim 17
Dependent Claim
109 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) contacting flowing gases containing hydrogen sulfide and oxygen with a solid catalyst for at least 30 days under conditions, including a temperature between about 250° and 450° F., sufficient to react at least 80% of said hydrogen sulfide with said oxygen to produce elemental sulfur essentially completely in the vapor state, said catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support selected from the group consisting of alumina and silica-alumina, and (2) recovering a product gas containing elemental sulfur vapor.
Claim 18
Dependent Claim
118 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) contacting hydrogen sulfide and elemental oxygen with a solid catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a support material selected from the group consisting of alumina, silica-alumina, silica, and combinations thereof, said contacting being under conditions, including a temperature between about 250° and 450° F. and the presence of sufficient elemental oxygen, such that a substantial proportion of said hydrogen sulfide reacts with said oxygen to produce elemental sulfur with essentially none of said elemental sulfur depositing upon the catalyst and (2) recovering a product gas containing elemental sulfur vapor.
Claim 19
Dependent Claim
118 words
A process for the conversion of hydrogen sulfide to elemental sulfur, which process comprises (1) contacting hydrogen sulfide and elemental oxygen with a solid catalyst consisting essentially of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a support material selected from the group consisting of alumina, silica-alumina, silica, and combinations thereof, said contacting being under conditions, including a temperature between about 250° and 450° F. and the presence of sufficient elemental oxygen, such that a substantial proportion of said hydrogen sulfide reacts with said oxygen to produce elemental sulfur with essentially none of said elemental sulfur depositing upon the catalyst and (2) recovering a product gas containing elemental sulfur vapor.
Claim 20
Dependent Claim
94 words
A process as defined in claims 6, 7, 8, 9, or 10 wherein elemental oxygen is present in step (1) in essentially the stoichiometric proportion necessary to effect the full conversion of hydrogen sulfide to elemental sulfur, and wherein at least 80% of said hydrogen sulfide is oxidized to elemental sulfur in step (1), and wherein said catalyst contains between about 2 and 20 percent by weight of vanadium promoters, calculated as V 2 O 5 , and wherein said conditions in step (1) are such that essentially no sulfur deposits on said catalyst.
Claim 21
Dependent Claim
32 words
A process as defined in claim 11 wherein elemental sulfur is separated from said product gas obtained in step (2) and a portion of the resulting off-gas is recycled to step (1).
Claim 22
Dependent Claim
71 words
A process as defined in claim 12 wherein the remaining portion of said off gas is contacted with a catalyst comprising a combination of a Group VIB metal oxide and/or sulfide and an iron group metal oxide and/or sulfide under conditions, including the presence of hydrogen and an elevated temperature, such that essentially all of the residual sulfur vapor and SO 2 in said off gas is converted to hydrogen sulfide.
Claim 23
Dependent Claim
15 words
A process as defined in claim 11 wherein said catalyst is in the reduced state.
Claim 24
Dependent Claim
24 words
A process as defined in claim 11 wherein said catalyst contains vanadium promoters essentially completely in the form of V 2 O 5 .
Claim 25
Dependent Claim
36 words
A process as defined in claims 6, 7, 8, or 10 wherein said catalyst experiences substantially no deactivation for the oxidation of hydrogen sulfide to sulfur for at least 30 days of contacting in step (1).
Claim 26
Dependent Claim
32 words
A process as defined in claim 11 wherein said catalyst experiences substantially no deactivation for the oxidation of hydrogen sulfide to sulfur for at least 90 days of contacting in step (1).
Claim 27
Dependent Claim
51 words
A process as defined in claim 9 wherein said flowing gas is contacted with said catalyst at a space velocity between about 250 and 2000 v/v/hr for at least 90 days, and wherein said catalyst experiences substantially no deactivation for the oxidation of hydrogen sulfide to sulfur during said 90 days.
Claim 28
Dependent Claim
153 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending a feed gas stream containing hydrogen sulfide with air such that the resulting mixed gas stream contains a substantial proportion of oxygen; (2) contacting said mixed gas stream with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support containing less than about 2% by weight of alkali metal and alkaline earth metal compounds, calculated as the oxides, said contacting being under conditions, including a temperature in the range of 250° to 450° F., such that a substantial proportion of the oxygen blended in step (1) in the form of air reacts with said hydrogen sulfide to produce elemental sulfur vapor; and (3) recovering a gaseous effluent from step (2) containing elemental sulfur vapor and separating elemental sulfur therefrom.
Claim 29
Dependent Claim
153 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending a feed gas stream containing hydrogen sulfide with air such that the resulting mixed gas stream contains a substantial proportion of oxygen; (2) contacting said mixed gas stream with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support containing less than about 2% by weight of alkali metal and alkaline earth metal compounds, calculated as the oxides, said contacting being under conditions, including a temperature in the range of 250° to 450° F., such that a substantial proportion of the oxygen blended in step (1) in the form of air reacts with said hydrogen sulfide to produce elemental sulfur vapor; and (3) recovering a gaseous effluent from step (2) containing elemental sulfur vapor and separating elemental sulfur therefrom.
Claim 30
Dependent Claim
150 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending with a feed gas stream containing hydrogen sulfide a stream of air sufficient to convert in step (2) hereinafter at least 80% of said hydrogen sulfide to elemental sulfur by reaction with the oxygen provided in said air stream; (2) contacting the mixed gas stream produced in step (1) with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a non-alkaline, porous refractory oxide support under conditions, including a temperature of initial contacting of said catalyst and mixed gas stream of between about 250° and 450° F., such that at least 80% of said hydrogen sulfide is converted to elemental sulfur vapor; and (3) recovering a gaseous effluent from step (2) containing elemental sulfur vapor and separating elemental sulfur therefrom.
Claim 31
Dependent Claim
150 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending with a feed gas stream containing hydrogen sulfide a stream of air sufficient to convert in step (2) hereinafter at least 80% of said hydrogen sulfide to elemental sulfur by reaction with the oxygen provided in said air stream; (2) contacting the mixed gas stream produced in step (1) with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a non-alkaline, porous refractory oxide support under conditions, including a temperature of initial contacting of said catalyst and mixed gas stream of between about 250° and 450° F., such that at least 80% of said hydrogen sulfide is converted to elemental sulfur vapor; and (3) recovering a gaseous effluent from step (2) containing elemental sulfur vapor and separating elemental sulfur therefrom.
Claim 32
Dependent Claim
220 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending a feed gas stream containing between about 100 ppmv and 10 mole percent hydrogen sulfide with air such that the resulting mixed gas stream contains hydrogen sulfide, oxygen, and any SO 2 from said feed gas stream in a proportion such that the molar ratio of (SO 2 +O 2 )/H 2 S is about 0.5; (2) contacting said mixed gas stream with a solid catalyst consisting essentially of between about 2 and 20% by weight of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a support material selected from the group consisting of alumina, silica, silica-alumina, zirconia, silica-zirconia, titania, silica-titania, silica-zirconia-titania, natural and synthetic crystalline and amorphous alumino-silicate zeolites in their hydrogen forms, acidic metal phosphates, acid metal arsenates, and combinations thereof, said contacting being under conditions, including a temperature in the range of 250° to 450° F., such that a substantial proportion of the oxygen supplied in step (1) with air reacts with hydrogen sulfide to produce elemental sulfur vapor and at least 80% of said hydrogen sulfide is converted to elemental sulfur vapor; and (3) recovering a gaseous effluent from step (2) containing elemental sulfur and separating elemental sulfur therefrom.
Claim 33
Dependent Claim
220 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending a feed gas stream containing between about 100 ppmv and 10 mole percent hydrogen sulfide with air such that the resulting mixed gas stream contains hydrogen sulfide, oxygen, and any SO 2 from said feed gas stream in a proportion such that the molar ratio of (SO 2 +O 2 )/H 2 S is about 0.5; (2) contacting said mixed gas stream with a solid catalyst consisting essentially of between about 2 and 20% by weight of one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a support material selected from the group consisting of alumina, silica, silica-alumina, zirconia, silica-zirconia, titania, silica-titania, silica-zirconia-titania, natural and synthetic crystalline and amorphous alumino-silicate zeolites in their hydrogen forms, acidic metal phosphates, acid metal arsenates, and combinations thereof, said contacting being under conditions, including a temperature in the range of 250° to 450° F., such that a substantial proportion of the oxygen supplied in step (1) with air reacts with hydrogen sulfide to produce elemental sulfur vapor and at least 80% of said hydrogen sulfide is converted to elemental sulfur vapor; and (3) recovering a gaseous effluent from step (2) containing elemental sulfur and separating elemental sulfur therefrom.
Claim 34
Dependent Claim
63 words
A process as defined in claims 19, 20, or 21 wherein said contacting in step (2) is conducted for at least 30 days without the catalyst experiencing substantially any deactivation for the oxidation of hydrogen sulfide to elemental sulfur, and wherein an off-gas is recovered in step (3) from the separation of sulfur, a portion of which off-gas is recycled to step (1).
Claim 35
Dependent Claim
18 words
A process as defined in claims 19, 20, or 21 wherein said catalyst is in the reduced state.
Claim 36
Dependent Claim
30 words
A process as defined in claim 22 wherein said mixed gas stream is contacted with said catalyst in step (2) at a space velocity between about 250 and 2000 v/v/hr.
Claim 37
Dependent Claim
210 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending a feed gas stream containing hydrogen sulfide in a proportion between about 500 ppmv and 10 mole percent with air such that the resulting mixed gas stream contains oxygen in essentially the stoichiometric proportion necessary to oxidize said hydrogen sulfide to sulfur; (2) contacting said mixed gas stream with a solid catalyst consisting essentially of between about 2 and 20 weight percent of one or more vanadium oxides on silica-alumina, said contacting being under conditions, including a temperature between about 250° and about 450° F. and a gas hourly space velocity between about 250 and 2000 v/v/hr and the presence of sufficient oxygen in said mixed gas stream, such that at least about 80% of said hydrogen sulfide reacts with said oxygen and at least 80% of said hydrogen sulfide is converted to elemental sulfur vapor without depositing substantially any elemental sulfur upon the catalyst, which catalyst maintains substantially undiminished activity for reacting hydrogen sulfide with oxygen for at least 30 days of contacting; (3) recovering a gaseous effluent from step (2) containing elemental sulfur vapor; and (4) separating elemental sulfur from the other gases in said gaseous effluent by condensation.
Claim 38
Dependent Claim
210 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) blending a feed gas stream containing hydrogen sulfide in a proportion between about 500 ppmv and 10 mole percent with air such that the resulting mixed gas stream contains oxygen in essentially the stoichiometric proportion necessary to oxidize said hydrogen sulfide to sulfur; (2) contacting said mixed gas stream with a solid catalyst consisting essentially of between about 2 and 20 weight percent of one or more vanadium oxides on silica-alumina, said contacting being under conditions, including a temperature between about 250° and about 450° F. and a gas hourly space velocity between about 250 and 2000 v/v/hr and the presence of sufficient oxygen in said mixed gas stream, such that at least about 80% of said hydrogen sulfide reacts with said oxygen and at least 80% of said hydrogen sulfide is converted to elemental sulfur vapor without depositing substantially any elemental sulfur upon the catalyst, which catalyst maintains substantially undiminished activity for reacting hydrogen sulfide with oxygen for at least 30 days of contacting; (3) recovering a gaseous effluent from step (2) containing elemental sulfur vapor; and (4) separating elemental sulfur from the other gases in said gaseous effluent by condensation.
Claim 39
Dependent Claim
37 words
A process as defined in claim 1, 2, 3, or 4 wherein a product gas is produced from said contacting containing elemental sulfur vapor and having a water vapor dew point between about 50° and 100° F.
Claim 40
Dependent Claim
41 words
A process as defined in claim 6, 7, 8, 9, or 10 wherein said conditions in step (1) are controlled such that said product gas recovered in step (2) has a water vapor dew point between about 50° and 100° F.
Claim 41
Dependent Claim
27 words
A process as defined in claim 11 wherein said product gas recovered in step (2) has a water vapor dew point between about 50° and 90° F.
Claim 42
Dependent Claim
23 words
A process as defined in claim 6, 7, or 8 wherein said feed gas contains less than about 10 volume percent water vapor.
Claim 43
Dependent Claim
31 words
A process as defined in claim 19, 20, 21, or 25 wherein said gaseous effluent recovered in step (3) has a water vapor dew point between about 50° and 100° F.
Claim 44
Dependent Claim
28 words
A process as defined in claim 30 wherein said catalyst contains a support consisting essentially of silica-alumina having an alumina content between about 20 and 30 weight percent.
Claim 45
Dependent Claim
165 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) contacting a feed gas stream containing hydrogen sulfide and containing less than about 10 volume percent water vapor blended with a gaseous oxidant comprising elemental oxygen in a reaction zone with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support containing less than about 2% by weight of alkali metal and alkaline earth metal compounds, said reaction zone being maintained at between about 250° and 450° F. and at a water vapor dew point between about 50° and 100° F. such that a substantial proportion of the oxygen blended with said feed gas stream reacts with said hydrogen sulfide to produce elemental sulfur vapor; and (2) recovering a gaseous effluent from said reaction zone containing elemental sulfur vapor and having a water vapor dew point between about 50° and 100° F.
Claim 46
Dependent Claim
165 words
A process for the oxidation of hydrogen sulfide and the recovery of elemental sulfur, which process comprises: (1) contacting a feed gas stream containing hydrogen sulfide and containing less than about 10 volume percent water vapor blended with a gaseous oxidant comprising elemental oxygen in a reaction zone with a solid catalyst comprising one or more vanadium promoters selected from the group consisting of vanadium oxides and sulfides on a porous refractory oxide support containing less than about 2% by weight of alkali metal and alkaline earth metal compounds, said reaction zone being maintained at between about 250° and 450° F. and at a water vapor dew point between about 50° and 100° F. such that a substantial proportion of the oxygen blended with said feed gas stream reacts with said hydrogen sulfide to produce elemental sulfur vapor; and (2) recovering a gaseous effluent from said reaction zone containing elemental sulfur vapor and having a water vapor dew point between about 50° and 100° F.
Claim 47
Dependent Claim
119 words
A process as defined in claim 32 wherein said catalyst consists essentially of between about 2 and 20% by weight of said vanadium promoters on a support selected from the group consisting of silica, silica-alumina, alumina, and mixtures thereof, and wherein the amount of elemental oxygen blended from said gaseous oxidant into said feed gas stream is essentially the stoichiometric amount necessary for the full conversion of said hydrogen sulfide to elemental sulfur, and wherein the conditions in said reaction zone are such that at least 80% of said hydrogen sulfide is converted to elemental sulfur and essentially no sulfur deposits on the catalyst, and wherein the elemental sulfur vapor in said gaseous effluent is removed therefrom by condensation.
Claim 48
Dependent Claim
35 words
A process as defined in claim 32 or 33 wherein said catalyst experiences essentially no deactivation for the oxidation of hydrogen sulfide to elemental sulfur for at least 90 days of contacting in step (1).
Claim 49
Dependent Claim
50 words
A process as defined in claim 32 or 33 wherein conditions are maintained in said reaction zone such that the water vapor dew point is between about 50° and 80° F. and wherein said gaseous effluent is recovered having a water vapor dew point between about 50° and 80° F.
Claim 50
Dependent Claim
49 words
A process as defined in claim 32 or 33 wherein conditions are maintained in said reaction zone such that the water vapor dew point is between about 50° and 90° F. wherein said gaseous effluent is recovered having a water vapor dew point between about 50° and 90° F.
Claim 51
Dependent Claim
26 words
A process as defined in claim 36 wherein said catalyst support consists essentially of silica-alumina having an alumina content between about 20% and 30% by weight.
Claim 52
Dependent Claim
34 words
A process as defined in claim 36 wherein said contacting of said feed gas stream blended with said gaseous oxidant and said catalyst is at a space velocity between about 250 and 2000 v/v/hr.
Claim 53
Dependent Claim
26 words
A process as defined in claim 38 wherein said catalyst support consists essentially of silica-alumina having an alumina content between about 20% and 30% by weight.
Claim 54
Dependent Claim
47 words
A process as defined in claim 34 wherein conditions are maintained in said reaction zone such that the water vapor dew point is between about 50° and 90° F. and wherein said gaseous effluent is recovered having a water vapor dew point between 50° and 90° F.
Claim 55
Dependent Claim
26 words
A process as defined in claim 40 wherein said catalyst support consists essentially of silica-alumina having an alumina content between about 20% and 30% by weight.
Claim 56
Dependent Claim
34 words
A process as defined in claim 41 wherein said contacting of said feed gas stream blended with said gaseous oxidant and said catalyst is at a space velocity between about 250 and 2000 v/v/hr.
Claim 57
Dependent Claim
26 words
A process as defined in claim 42 wherein said catalyst support consists essentially of silica-alumina having an alumina content between about 20% and 30% by weight.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1985-01-18 | 1985-07-20 | 1986-01-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-01-18 | 1989-07-20 | 1990-01-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-01-18 | 1993-07-20 | 1994-01-19 | $7700.00 | Window Closed / Lapsed |