US4310642A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Graft polycarbonates, their preparation and their use as moldings
Assignee: Bayer AG
•
Filing: 1979-09-24
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Granted: 1982-01-12
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Expires: 1999-09-24
Abstract
Abstract The subject disclosure is concerned with a process for synthesizing soluble thermoplastic graft polymers of polycarbonate and ethylenically unsaturated monomers by polymerizing these monomers and aromatic polycarbonates carrying addition polymerizable end groups in a dilute solution of no more than 30 wt. % of reactants based on the weight of solution. The graft polymers so obtained are also encompassed by the inventive concept.
Inventors
- 👤 Dieter Margotte
- 👤 Werner Nouvertne
- 👤 Dieter Neuray
- 👤 Hugo Vernaleken
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 02:12
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/04; C08G64/045; C08F; C08F283/00; C08F283/02; C08F290/00; C08F290/02; C08F290/06; C08F290/061
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
207 words
A process for the production of soluble thermoplastic graft polycarbonate with a molecular weight (weight average Mw) of about 30,000 to 400,000, in which an aromatic polycarbonate with on average at least one unsaturated end group per polycarbonate molecule, having the formula II ##STR6## in which Z=a radical of a diphenol, n=an integer from 30 to 100, and E represents a saturated end group of the formula IIIb or an unsaturated end group of the formula IIIa ##STR7## in which for IIIa, m denotes zero and R denotes ##STR8## and in which for IIIb, m is zero and R is C 1 -C 18 -alkyl or m is 1 and R is H, alkyl or halogen, is polymerized by means of solution polymerization in the presence of monomers which can be polymerized under free radical conditions, selected from vinyl monomers and acrylic monomers, during which the weight ratio of the starting polycarbonate to the monomers which can be polymerized under free radical conditions is about 70:30 to 10:90, and during which the concentration of the reaction solution does not exceed about 30% by weight, relative to the total weight of polycarbonate with unsaturated end groups, monomers which can be polymerized under free radical conditions and reaction medium.
Claim 2
Dependent Claim
207 words
A process for the production of soluble thermoplastic graft polycarbonate with a molecular weight (weight average Mw) of about 30,000 to 400,000, in which an aromatic polycarbonate with on average at least one unsaturated end group per polycarbonate molecule, having the formula II ##STR6## in which Z=a radical of a diphenol, n=an integer from 30 to 100, and E represents a saturated end group of the formula IIIb or an unsaturated end group of the formula IIIa ##STR7## in which for IIIa, m denotes zero and R denotes ##STR8## and in which for IIIb, m is zero and R is C 1 -C 18 -alkyl or m is 1 and R is H, alkyl or halogen, is polymerized by means of solution polymerization in the presence of monomers which can be polymerized under free radical conditions, selected from vinyl monomers and acrylic monomers, during which the weight ratio of the starting polycarbonate to the monomers which can be polymerized under free radical conditions is about 70:30 to 10:90, and during which the concentration of the reaction solution does not exceed about 30% by weight, relative to the total weight of polycarbonate with unsaturated end groups, monomers which can be polymerized under free radical conditions and reaction medium.
Claim 3
Dependent Claim
24 words
A process according to claim 1, in which an aromatic polycarbonate with on average only one unsaturated end group per polycarbonate molecule is polymerized.
Claim 4
Dependent Claim
33 words
A process according to claims 1 or 2, in which the weight ratio of the starting polycarbonate to the monomer which can be polymerized under free radical conditions is about 70:30 to 40:60.
Claim 5
Dependent Claim
31 words
A process according to claim 3, in which the weight ratio of the starting polycarbonate to the monomer which can be polymerized under free radical conditions is about 65:35 to 45:55.
Claim 6
Dependent Claim
13 words
A thermoplastic graft polycarbonate produced by the process of claims 1 or 2.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-01-11 | 1985-07-13 | 1986-01-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-01-11 | 1989-07-13 | 1990-01-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-01-11 | 1993-07-13 | 1994-01-12 | $7700.00 | Window Closed / Lapsed |